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## Full-Text Articles in Physics

Magnetic Resonance Spectroscopy Of Fullerenes And [Pi]-Conjugated Polymers , Paul Andrew Lane

#### Magnetic Resonance Spectroscopy Of Fullerenes And [Pi]-Conjugated Polymers , Paul Andrew Lane

*Retrospective Theses and Dissertations*

The photophysics of two novel [pi]-conjugated systems, buckminsterfullerene and [pi]-conjugated polymers, are studied by the technique of Photoluminescence-Detected Magnetic Resonance (PLDMR);The PLDMR of C60 and C70 dissolved in toluene/polystyrene glasses and of fullerene films is described. The PLDMR of the glasses is due to a triplet exciton delocalized over the entire molecule. That of 3C70 strikingly differs from 3C60 in both lineshape and dynamics, due to the much longer triplet lifetime of 3C70. The PLDMR of films indicates that the delocalized triplet is distorted by intermolecular interactions and reveals a half-field resonance due to triplet-triplet fusion ...

Nmr And Nqr Study Of The Thermodynamically Stable Quasicrystals , Ananda Shastri

#### Nmr And Nqr Study Of The Thermodynamically Stable Quasicrystals , Ananda Shastri

*Retrospective Theses and Dissertations*

[superscript]27Al and [superscript]63,65Cu NMR measurements are reported for powder samples of stable AlCuFe and AlCuRu icosahedral quasicrystals and their crystalline approximants, and for a AlPdMn single grain quasicrystal. Furthermore, [superscript]27Al NQR spectra at 4.2 K have been observed in the AlCuFe and AlCuRu samples. From the quadrupole perturbed NMR spectra at different magnetic fields, and from the zero field NQR spectra, a wide distribution of local electric field gradient (EFG) tensor components and principal axis system orientations was found at the Al site. A model EFG calculation based on a 1/1 AlCuFe approximant was ...

Optical Anisotropy Of (110) Surfaces Of Ag And Cu , Zai Chen

#### Optical Anisotropy Of (110) Surfaces Of Ag And Cu , Zai Chen

*Retrospective Theses and Dissertations*

A reflectance-difference spectroscopy (RD) system was designed and built. Automatically controlled by a computer (PC), the system was used to study the anisotropic optical response of the (110) surfaces of Ag and Cu. Four Ag(110) surfaces were prepared, one epitaxially-grown single-crystalline thin film surface and three chemically etched single crystal surfaces. The RD spectra show all surfaces have very similar anisotropic peaks around 3.8 eV and 3.9 eV. This anisotropy is produced by the surface layer of atoms and is sensitive to the details of the electronic band structure. The peak structures can be attributed to transitions ...

Theory Of Magneto-Optics And Circular Magnetic X-Ray Dichroism , Xindong Wang

#### Theory Of Magneto-Optics And Circular Magnetic X-Ray Dichroism , Xindong Wang

*Retrospective Theses and Dissertations*

This thesis contains three parts. In the first part, before getting into the discussion of magneto-optical properties for the systems under study, the author reviews some background subjects, such as the energy-band theory within the framework of density functional theory, the multiple scattering approach to the solution of band problem and its relation with the LMTO method, an account of the tight-binding LMTO method which we use exclusively in our calculations, the linear response theory and its application to the quantum theory of dielectric constants. In the second part, circular magnetic x-ray dichroism, as a powerful and newly developed experimental ...

A Closed-Form Integration Method For State-Space Time-Domain Analysis Of Electronic Circuits And Systems , Bruce Alan Alspaugh

#### A Closed-Form Integration Method For State-Space Time-Domain Analysis Of Electronic Circuits And Systems , Bruce Alan Alspaugh

*Retrospective Theses and Dissertations*

While most traditional circuit simulation programs such as SPICE rely upon numerical integration techniques to perform transient analysis, this dissertation presents an alternative approach that relies on closed-form integration. Traditional numerical approaches offer no hope of finding an analytical solution, even if it is known that the solutions will be in a simple functional form. By using closed-form methods, the computer can find the exact analytical solution to the network and completely avoid problems associated with numerical approximations, determining appropriate integration step sizes, stiff systems of differential equations, or accumulated global error. Computer run time is independent of the amount ...

Characterization And Analysis Of Viscoelastically Loaded Thin Film Piezoelectric Resonators Incorporated In An Oscillator Microsensing System , Ronald Patrick O'Toole

#### Characterization And Analysis Of Viscoelastically Loaded Thin Film Piezoelectric Resonators Incorporated In An Oscillator Microsensing System , Ronald Patrick O'Toole

*Retrospective Theses and Dissertations*

In the recent advancement of piezoelectric resonator technology, there has been a large growth in the application of these devices for chemical sensing. These sensors operate by detecting changes in their environment which perturb the electrical - acoustic operation and in turn can be harnessed by means of supporting electronics and signal processing to monitor various processes. Examples include remote environmental monitoring, chemical process control, and commercial gas phase detectors. In this dissertation, the chemical sensing theory and properties of piezoelectric resonators such as the bulk-acoustic wave thin-film resonator (TFR) and the quartz crystal microbalance (QCM) are developed. This analysis concentrates ...

#### Fabrication And Characterization Of Hydrogenated Amorphous Silicon Films, Cvd Diamond Films, And Their Devices , Hao Jia

*Retrospective Theses and Dissertations*

Hydrogenated amorphous silicon (a-Si:H) films have been prepared by radio frequency (rf) sputtering technique, and studied by infrared (IR) absorption, small angle x-ray scattering (SAXS), electron spin resonance (ESR), and secondary ion mass spectrometry (SIMS). The optoelectronic properties of a-Si:H films were improved dramatically by annealing at 250-330°C; strong correlation between hydrogen content and SAXS determined microvoid was found in a-Si:H film; and contradictory evidences to the widely invoked "multiple trapping" model for hydrogen diffusion in a-Si:H were also found for the first time and discussed in this work;As the second part of this ...

Classical Wave Propagation In Periodic And Random Media , Sreela Datta

#### Classical Wave Propagation In Periodic And Random Media , Sreela Datta

*Retrospective Theses and Dissertations*

This thesis presents the results of numerical studies of scalar and electromagnetic wave propagation in periodic and random dielectric media. The photonic energy band structure of periodic composite materials, consisting of regular spherical arrays or scaffoldings of one kind of dielectric material in a different background material, are studied using the plane wave expansion method in order to determine, among other things, the optimum conditions (crystal structure, dielectric constant ratio, filling ratio etc.) for the existence of photonic band gaps. The significance of these numerical studies lies in the potential for important applications of photonic band gap materials and also ...

Sub-Micron Scale Conduction Processes On Clean Surfaces , Kevin R. Kimberlin

#### Sub-Micron Scale Conduction Processes On Clean Surfaces , Kevin R. Kimberlin

*Retrospective Theses and Dissertations*

Fundamental electrical conductance measurement has been studied in-situ in two dimensions in the Ag/Si(111) system as a function of the incident adatom flux rate with a four probe technique. A conductance study in a three dimensional conical structure was also carried out with field emission techniques. Field emission is now well established and has been used in this case to characterize a novel geometry for use in flat panel displays to replace cathode ray tube monitors. For the two dimensional study on Ag/Si(111), the origin of conduction is still unclear, as both transport by means of ...

Search For Top In Pp̄ Collisions At [Square Root Of S] = 1.8 Tev By Constrained Kinematic Fitting , Myungyun Pang

#### Search For Top In Pp̄ Collisions At [Square Root Of S] = 1.8 Tev By Constrained Kinematic Fitting , Myungyun Pang

*Retrospective Theses and Dissertations*

A search for the top quark has been pursued in pp collision at √s = 1.8 TeV with the DO detector. This documentation describes a method introduced to extract the mass of the top quark and the cross section limits on tt production. Also a preliminary result from the DO experiment is described.

Optical And Magnetic Resonance Studies Of Novel Pristine And Photo-Oxidized Conjugated Polymers , Andrew Vernon Smith

#### Optical And Magnetic Resonance Studies Of Novel Pristine And Photo-Oxidized Conjugated Polymers , Andrew Vernon Smith

*Retrospective Theses and Dissertations*

Optical and magnetic resonance properties of several [pi]-conjugated polymers were studied and the results consolidated in this thesis. Photoluminescence (PL), electron spin resonance (ESR), and the novel Ultraviolet Optically Detected Magnetic Resonance (UV-ODMR) results on poly(p-phenyleneethynyleneaniline) (PPEA) derivatives are shown. The source wavelength, [lambda][subscript]ex, dependence of the ODMR is investigated on several [pi]-conjugated polymers including poly(p-phenylenevinylene) (PPV), poly(p-phenyleneacetylene) (PPA), and poly(3-alkylthiophene) (P3AT) derivative films. The effects of photo-oxidation on the UV- and laser-excited ODMR of dioctoxy substituted PPV (DOOPPV) films is shown. The ODMR results on unsubstituted PPV and CN-PPV films are ...

Active Noise Control In A Three-Dimensional Space , Jihe Yang

#### Active Noise Control In A Three-Dimensional Space , Jihe Yang

*Retrospective Theses and Dissertations*

In this research, a new approach is presented for optimizing the performance of active noise control in three-dimensional space. The work focuses on the critical role of determining the locations for secondary sources in active noise suppression. A systematic technique is proposed for estimating optimal locations of secondary sources on the boundary of a three-dimensional domain for both local and global active control of harmonic sound fields. The theoretical foundation of this work is Huygen's principle. The indirect boundary element method (IBEM) which is a numerical implementation of Huygen's principle is employed as a basis for the numerical ...

#### Photoemission Study Of Some Novel Materials: Rare Earth/Transition Metal Interface, Ba06k04bio3 And Alpdmn , Xilin Wu

*Retrospective Theses and Dissertations*

Synchrotron radiation photoemission spectroscopy and low energy electron diffraction (LEED) are applied to explore several novel materials: (a) Ce epitaxial growth on W (110) surfaces; (b) Eu epitaxial growth on Ta (110) surfaces; (c) Sm epitaxial growth on Ta (110) surfaces; (d) quasicrystalline AlPdMn; (e) superconducting Ba[subscript]1-xK[subscript] xBiO[subscript]3. In the case of rare earth overlayers on transition metal surface, resonance photoemission spectroscopy is used to enhance the 4f features. The metal surface phase transition is investigated on an atomic-scale. In the case of quasicrystalline AlPdMn and superconducting Ba[subscript]1-xK[subscript] xBiO[subscript]3 the ...

Magnetization Studies Of Oxides Related To The High Temperature Cuprate Superconductors , Zhaorong Wang

#### Magnetization Studies Of Oxides Related To The High Temperature Cuprate Superconductors , Zhaorong Wang

*Retrospective Theses and Dissertations*

An Oxford Instruments Faraday magnetometer, capable of operating in the temperature range between 1.5 K and 1000 K, and magnetic field range between 0 T to 8 T, with a sensitivity of 3x10[superscript]-8 cm[superscript]3G, was assembled and calibrated. The pumping station which supported this magnetometer was designed and built. Software for reducing the raw data and generating calibration files was written. The magnetic properties of several oxides related to the high temperature cuprate superconductors BaCuO[subscript]2+x, La[subscript]2CuO[subscript]4, Sr[subscript]2IrO[subscript]4, Sr[subscript]2RhO[subscript]4, Sr[subscript ...

Connection Between Nmr And Electrical Conductivity In Glassy Chalcogenide Fast Ionic Conductors , Kyung-Han Kim

#### Connection Between Nmr And Electrical Conductivity In Glassy Chalcogenide Fast Ionic Conductors , Kyung-Han Kim

*Retrospective Theses and Dissertations*

Pulsed Nuclear Magnetic Resonance measurements and electric conductivity measurements have been performed in glassy fast ionic conductors, lithium thiogermanates ( xLi2S+(1-x)GeS2) and lithium thioborates ( xLi2S+(1-x)B2S3) in order to investigate the microscopic mechanism of ion dynamics. Both 7Li nuclear spin lattice relaxation rate (NSLR) versus temperature at several resonance frequencies (4 MHz to 135 MHz) and conductivity, [sigma]([omega]) versus temperature, in the frequency range from 1 Hz to 4 MHz have been measured. The 7Li NSLR show BPP-type behavior with strong asymmetry of the bell shaped curve on the two sides of the maximum. A sizable dependence ...