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Magnetic And Crystallographic Order In Α‐Manganese, A. C. Lawson, Allen C. Larson, M. C. Aronson, S. Johnson, Z. Fisk, Paul C. Canfield, J. D. Thompson, R. B. Von Dreele

Paul C. Canfield

We have made time‐of‐flight neutron diffractionmeasurements on α‐manganese metal. Powder diffraction measurements were made at 14 temperatures between 15 and 305 K, and single crystalmeasurements were made at 15 and 300 K. We found that the crystal structure of α‐Mn is tetragonal below its Néel point of 100 K, with crystal symmetryI4̄2m and magnetic (Shubnikov) symmetry P I 4̄21 c. In agreement with the earlier results of Yamada et al., there are six independent magnetic atoms, and we found that their moments are weakly temperature dependent. The onset of magnetic order causes slight changes in the atomic positions and in …