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Full-Text Articles in Physics

Resistivity Of The High-Temperature Metallic Phase Of Vo2, Werner W. Schulz, Philip B. Allen, Renate M. Wentzcovitch, Paul C. Canfield Aug 1993

Resistivity Of The High-Temperature Metallic Phase Of Vo2, Werner W. Schulz, Philip B. Allen, Renate M. Wentzcovitch, Paul C. Canfield

Paul C. Canfield

Measurements are reported on the electrical resistivity ρ(T) along the c axis of a single crystal of VO2, from the metal-insulator transition at T=333 K up to 840 K. The temperature dependence is very linear, and a fit to Bloch-Grüneisen theory gives a residual resistivity ρ0=65 μΩ cm and a ratio ρ(840 K)/ρ0=8. With the help of a local-density-approximation band-structure calculation, we further pursue the conventional (Bloch-Boltzmann) interpretation by extracting the electron-phonon coupling constant λ=1.1 and the mean free path l(800 K)=3.3 Å. The short mean free path implies that the conventional interpretation is internally inconsistent. The most likely explanation …


Doping And Pressure Studies On Ybbipt, A. Lacerda, R. Movshovich, M. F. Hundley, Paul C. Canfield, D. Arms, G. Sparn, J. D. Thompson, Z. Fisk, N. E. Philips, H.-R. Ott Jan 1993

Doping And Pressure Studies On Ybbipt, A. Lacerda, R. Movshovich, M. F. Hundley, Paul C. Canfield, D. Arms, G. Sparn, J. D. Thompson, Z. Fisk, N. E. Philips, H.-R. Ott

Paul C. Canfield

The compound YbBiPt exhibits an extremely large low‐temperature C/T (γ∼8 J K−2 mol−1/Yb) which, if due solely to a renormalized effective mass, would make this material the heaviest correlated electron system known to date. In the Kondo model, the very large γ corresponds to a small characteristic energy scale that is expected to be pressure dependent. We have studied the effect of chemical pressure on YbBiPt single crystals by heat‐capacity measurements on Y and Lu‐doped samples. We have also made preliminary low‐temperature measurements under hydrostatic pressure of the heat capacity (300 mK≤T≤2 K, up to 8 kbar) and resistance (30 …


Nqr Study Of Local Structure And Cooling Rate‐Dependent Superconductivity In La2cuo4+Δ, A. P. Reyes, E. T. Ahrens, P. C. Hammel, J. D. Thompson, Paul C. Canfield, Z. Fisk, R. H. Heffner, J. E. Schirber Jan 1993

Nqr Study Of Local Structure And Cooling Rate‐Dependent Superconductivity In La2cuo4+Δ, A. P. Reyes, E. T. Ahrens, P. C. Hammel, J. D. Thompson, Paul C. Canfield, Z. Fisk, R. H. Heffner, J. E. Schirber

Paul C. Canfield

Preliminary results of structural studies in oxygen‐annealed La2CuO4+δ(δ∼0.03) using 139La nuclear quadrupole resonance (NQR) spectroscopy are reported. Superconducting critical temperatures were found to depend on the rate of cooling through a narrow temperature range near 195 K. Analysis of the 139La NQR spectra reveal that lanthanum atoms in the oxygen‐rich metallic region occupy two sites having different local environments. One site has a structural configuration closely related to the stoichiometric oxygen‐poor compound. The second appears only below 200 K and exhibits a large shift and broad distribution of NQR frequency ν Q . Shifts in ν Q in the vicinity …