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1993

Iowa State University

Condensed Matter Physics

Materials Science and Engineering Publications

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Full-Text Articles in Physics

Correlation Functions For Ionic Motion From Nmr Relaxation And Electrical Conductivity In The Glassy Fast-Ion Conductor (Li2s)0.56(Sis2)0.44, Ivar Svare, Ferdinando Borsa, D. R. Torgeson, Steve W. Martin Oct 1993

Correlation Functions For Ionic Motion From Nmr Relaxation And Electrical Conductivity In The Glassy Fast-Ion Conductor (Li2s)0.56(Sis2)0.44, Ivar Svare, Ferdinando Borsa, D. R. Torgeson, Steve W. Martin

Materials Science and Engineering Publications

The Li7 NMR spin-lattice relaxation and the electrical conductivity in the typical glassy fast-ion conductor (Li2S)0.56(SiS2)0.44 are discussed from models of Li+ionic motion with distributions of activation energies, as well as from stretched-exponential time-correlation functions. The measured correlation times from the two effects differ by two orders of magnitude, and the derived distributions are shifted greatly relative to each other. We relate the great differences to percolation around the high barriers in the distribution. We present a phenomenological theory that yields good quantitative fits to the observed NMR relaxation with a Gaussian distribution, and ...