Physics Commons^™

Novel As-S-Se Compositions Of Solution-Processed Chalcogenide Thin Films For Infrared Optics, Annabella Orsini

Physics and Astronomy Honors Papers

Chalcogenide glasses (ChGs) have a wide range of interdisciplinary applications. In industry, ChGs are used to vastly improve infrared sight abilities. There are, however, improvements that can be made to the films’ stability, cost, and flexibility. Our project seeks to produce thin films that have these improvements, with capabilities comparable or better than what is widely used in the field. Thin films created through solution-based processes have proven to be much more flexible in comparison to bulk glass versions. Other elements in Group 16, such as Sulfur and Selenium have shown across literature to be a cost-effective alternative to Tellurium …

Periodic Trends In The Infrared And Optical Absorption Spectra Of Metal Chalcogenide Clusters, Alain Ward

Theses and Dissertations

We have investigated the Optical absorption, Infrared spectra, Binding Energies, and various other cluster properties to determine the existence of periodic trend for Transition Metal Chalcogenide Clusters ligated with CO ligands. We were motivated to answer the question of whether periodic behavior can be observed in properties of octahedral metal-chalcogenide clusters. We have used the Amsterdam Density Functional code to calculate the electronic structure of Transition Metal Chalcogenide Clusters using gradient-corrected density functional theory. We determined the existence of several periodic trends in properties of octahedral Transition Metal Chalcogenide Clusters TM₆Se₈(CO)₆. To investigate these …

Characterization Of Infrared Metasurface Optics With An Optical Scatterometer, Matthew R. Miller

Theses and Dissertations

An optical scatterometer is used to characterize the infrared scatter of a dielectric metasurface cylindrical lens and two variants of that design. The design uses dielectric nanopillars to create the parabolic phase delay required for lensing; the variants change the length of the nanopillars from the design length of 4 microns to 0.9 and 5.2 microns. Scatter measurements were made at the design wavelength of 4 microns, and at 3.39 and 5 microns. These measurements showed wide-angle scatter greater than that measured for a conventional refractive optic, and that these metasurfaces perform their optical function best at the design wavelength …

Cyclotron Resonance In Graphene Heterostructurescyclotron Resonance In Graphene Heterostructures, Billy Jordan Russell

Arts & Sciences Electronic Theses and Dissertations

We present observations of cyclotron resonance in graphene Van der Waals heterostructure devices. Such devices provide dramatic improvements in sample quality and allow for ad- vanced electronic control, opening windows on previously inaccessible physics. The design and construction of a dedicated system for the measurement of electronic transport and infrared magnetospectroscopy in microscopic samples of atomically thin materials at cryogenic temperatures is presented. In high-mobility encapsulated monolayer graphene, electron- electron interaction effects are unambiguously observed to impact the interband cyclotron resonance as the Landau level filling factor is varied in a quantizing magnetic field. Additionally, a splitting of transitions involving …

Scattering In Infrared Microspectroscopy, Alex James Schofield

Theses and Dissertations

Mid-infrared absorbance spectra obtained from spatially inhomogeneous and finite samples often contain scattering effects that undermine the Beer-Lambert law assumption. Such spectra contain generally non-linear contributions from the scattering material’s complex refractive index, which may result in derivative-like bands with shifted peak positions. It is first shown using Mie theory for spherical scatterers, that these band distortions may be interpreted and accurately modeled by Fano theory when the imaginary part of its complex dielectric function is small and Lorentzian in nature—as is the case for many biological media. By fitting Fano line shapes to isolated absorbance bands, recovery of the …

Infrared And Electro-Optical Stereo Vision For Automated Aerial Refueling, William E. Dallmann

Theses and Dissertations

Currently, Unmanned Aerial Vehicles are unsafe to refuel in-flight due to the communication latency between the UAVs ground operator and the UAV. Providing UAVs with an in-flight refueling capability would improve their functionality by extending their flight duration and increasing their flight payload. Our solution to this problem is Automated Aerial Refueling (AAR) using stereo vision from stereo electro-optical and infrared cameras on a refueling tanker. To simulate a refueling scenario, we use ground vehicles to simulate a pseudo tanker and pseudo receiver UAV. Imagery of the receiver is collected by the cameras on the tanker and processed by a …

Infrared Properties Of Stars In The Bulge Asymmetries And Dynamical Evolution Survey, Eddie Hilburn

Physics & Astronomy ETDs

The Bulge Asymmetries and Dynamical Evolution (BAaDE) survey is an SiO maser survey of 28,062 infrared-selected evolved stars primarily in the Galactic plane. By cross-matching the BAaDE target sources with nine different infrared catalogs, we have constructed a catalog with wavelength coverage from 0.71 to 80 m. Using this catalog, we fit the data for each source to a model spectral energy distribution (SED) generated with the radiation transport program DUSTY in order to obtain characteristics such as bolometric flux, source effective temperature, and the optical depth of the circumstellar envelope.

The overall goal of the BAaDE survey is to …

Plasmonic Grating Geometrics And Wavelength-Dependent Focus Depth In Infrared Detectors, Patrick R. Kennedy

Theses and Dissertations

The objective for this research is to determine a relationship between plasmonic grating geometries and the wavelength-dependent focus depth. This research is focused on enhancing the signal collected by infrared detectors by using a metal grating as a planar lens to focus light in the detecting region of the substrate. This can be used to maintain a thinner absorbing region and possibly to create multi-color imaging in a single pixel. Simulations demonstrate that the plasmonic lens is capable of creating a wavelength dependent focus spot.

Biomedical Applications Of Mid-Infrared Spectroscopic Imaging And Multivariate Data Analysis: Contribution To The Understanding Of Diabetes Pathogenesis, Ebrahim Aboualizadeh

Theses and Dissertations

Diabetic retinopathy (DR) is a microvascular complication of diabetes and a leading cause of adult vision loss. Although a great deal of progress has been made in ophthalmological examinations and clinical approaches to detect the signs of retinopathy in patients with diabetes, there still remain outstanding questions regarding the molecular and biochemical changes involved. To discover the biochemical mechanisms underlying the development and progression of changes in the retina as a result of diabetes, a more comprehensive understanding of the bio-molecular processes, in individual retinal cells subjected to hyperglycemia, is required. Animal models provide a suitable resource for temporal detection …

Total Electron Count Variability And Stratospheric Ozone Effects On Solar Backscatter And Lwir Emissions, John S. Ross

Theses and Dissertations

The development of an accurate ionospheric Total Electron Content (TEC) model is of critical importance to High Frequency (HF) radio wave propagation. However, the TEC is highly variable and is continuously influenced by geomagnetic storms, extreme Ultraviolet (UV) radiation, diurnal variation, and planetary waves. The ability to capture this variability is essential to improve current TEC models. Analysis of the growing body of data involving ionospheric fluctuations and thermal tides has revealed persistent correlation between increases in stratospheric ozone and variability of the TEC. The spectral properties of ozone show that it is a greenhouse gas that alters longwave emissions …

Fabrication Of Infrared Photodetectors Utilizing Lead Selenide Nanocrystals, Justin Anthony Hill

Graduate Theses and Dissertations

Colloidal lead selenide and lead selenide / lead sulfide core/shell nanocrystals were grown using a wet chemical synthesis procedure. Absorbance and photoluminescence measurements were made to verify the quality of the produced nanocrystals. Absorbance spectra were measured at room temperature, while photoluminescence spectra were measured at 77 K. Organic ligands were exchanged for shorter ligands in order to increase the conductivity of the nanocrystals. Absorption and PL spectra for both core and core/shell nanocrystals were compared. Interdigital photodetector devices with varying channel widths were fabricated by depositing gold onto a glass substrate. Lead selenide nanocrystals were deposited onto these metallic …

New Facet Of Solar Activities Revealed By High-Resolution Imaging At He I 10830 Å, Zhicheng Zeng

Dissertations

Major solar activities such as major flares and associated coronal mass ejections (CMEs), have a great impact on space weather, which requires us to develop the ability to predict them. Despite the extensive studies already made, however, many basic processes, such as energy accumulation processes in solar active regions and the triggering mechanism of solar activities, are still not well understood.

One reason why the basic processes are hard to be understood is that the large-scale activities are complicated, involving many small-scale energy releases, making it hard to understand the basic picture of the events. Small-scale solar activities, such as …

Stellar Spectroscopy: New Methods And Insights, Sanaz S. Golriz

Electronic Thesis and Dissertation Repository

The study of the chemical evolution of stars is of crucial importance since they play a major role in the enrichment of the chemistry of the universe. Throughout their lifetime, stars undergo several processes that can alter their chemistry. Gradually, the nucleosynthesis products from the interior of the star are radiatively and convectively levitated and mixed with the upper layers of the atmosphere. In the later stages of their evolution, low to intermediate mass stars (0.8-8.0~M☉) eject a significant fraction of these nucleosynthesis products, resulting in a circumstellar envelope of gas and dust around the central star with a very …

Synchrotron Based Infrared Microspectroscopy Of Carbonaceous Chondrites., Mehmet Yesiltas

Electronic Theses and Dissertations

Relationships between organic molecules and inorganic minerals are investigated in five carbonaceous chondrites, Northwest Africa 852 (CR2), Tagish Lake (C2-ungroupped), Orgueil (CI1), Sutter's Mill (CM), and Murchison (CM2), with micron spatial resolution using synchrotron-based imaging micro-FTIR spectroscopy. Correlations based on absorption strength for various constituents are determined using statistical correlation analysis. Silicate band is found to be positively correlated with stretching modes of aliphatic hydrocarbons in NWA 852 and Tagish Lake. The former is highly correlated with the hydration band in all meteorites. Negative correlation is observed between water+organics and carbonate bands in all meteorites. Two dimensional infrared maps for …

Large Area Conformal Infrared Frequency Selective Surfaces, Jeffrey D'Archangel

Electronic Theses and Dissertations

Frequency selective surfaces (FSS) were originally developed for electromagnetic filtering applications at microwave frequencies. Electron-beam lithography has enabled the extension of FSS to infrared frequencies; however, these techniques create sample sizes that are seldom appropriate for real world applications due to the size and rigidity of the substrate. A new method of fabricating large area conformal infrared FSS is introduced, which involves releasing miniature FSS arrays from a substrate for implementation in a coating. A selective etching process is proposed and executed to create FSS particles from crossed-dipole and square-loop FSS arrays. When the fill-factor of the particles in the …

Broad Bandwidth, All-Fiber, Thulium-Doped Photonic Crystal Fiber Amplifier For Potential Use In Scaling Ultrashort Pulse Peak Powers, Alex Sincore

Electronic Theses and Dissertations

Fiber based ultrashort pulse laser sources are desirable for many applications; however generating high peak powers in fiber lasers is primarily limited by the onset of nonlinear effects such as self-phase modulation, stimulated Raman scattering, and self-focusing. Increasing the fiber core diameter mitigates the onset of these nonlinear effects, but also allows unwanted higher-order transverse spatial modes to propagate. Both large core diameters and single-mode propagation can be simultaneously attained using photonic crystal fibers. Thulium-doped fiber lasers are attractive for high peak power ultrashort pulse systems. They offer a broad gain bandwidth, capable of amplifying sub-100 femtosecond pulses. The longer …

Probing Bonding And Dynamics At Heterogeneous Adsorbate/Graphene Interfaces, Eric Charles Mattson

Theses and Dissertations

Graphene-based materials are becoming an astoundingly promising choice for many relevant technological and environmental applications. Deriving graphene from the reduction of graphene oxide (GO) is becoming a popular and inexpensive route toward the synthesis of these materials. While the desired product from GO reduction is pristine graphene, defects and residual oxygen functional groups inherited from the parent GO render reduced graphene oxide (RGO) distinct from graphene. In this work, the structure and bonding for GO and RGO is investigated to the end of a working understanding of the composition and properties of these materials. In situ selected area electron diffraction …

Spectral And Spatial Coherent Emission Of Thermal Radiation From Metal-Semiconductor Nanostructures, Shane N. Mcconnell

Theses and Dissertations

The spectral and spatial radiative properties of coherent thermal emission in the mid- and far-IR through the use of micro and nano-structured metal-semiconductor materials were designed and demonstrated experimentally. Using an implementation of the Rigorous Coupled Wave Analysis and Computer Simulation Technology (CST), two structures were designed to selectively emit at mid- and far-IR wavelengths, a 1-D truncated multilayer resonator and a 3-D hybrid photonic crystal (PC)-multilayer. A High Impulse Power Magnetron Sputtering (HIPIMS) deposition technique was used to fabricate two silver-germanium-silver (Ag-Ge-Ag) resonating structures with layer thicknesses of 6-240-160 nm for one sample and 6-700-200 nm for the other. …

Infraded Surface Plasmon Polaritons On Semiconductor, Semimetal And Conducting Polymer, Monas Shahzad

Electronic Theses and Dissertations

Conductors with IR (infrared) plasma frequencies are potentially useful hosts of surface plasmon polaritons (SPPs) with subwavelength mode confinement for sensing applications. The underlying aim of this work is to identify such conductors that also have sharp SPP excitation resonances for biosensor applications at infrared (3-11 m) wavelengths, where biological analytes are strongly differentiated by their IR absorption spectra. In this work, various materials were investigated such as a heavily doped semiconductor, a semimetal, a conducting polymer and its composite. Heavily doped silicon was investigated by tuning its plasma frequency to the infrared region by heavily doping. The measured complex …

Infrared Tapered Slot Antennas Coupled To Tunnel Diodes, Louis A. Florence

Electronic Theses and Dissertations

Tapered slot antennas (TSAs) have seen considerable application in the millimeter-wave portion of the spectrum. Desirable characteristics of TSAs include symmetric E- and H-plane antenna patterns, and broad non-resonant bandwidths. We investigate extension of TSA operation toward higher frequencies in the thermal infrared (IR), using a metal-oxide-metal diode as the detector. Several different infrared TSA design forms are fabricated using electronbeam lithography and specially developed thin-film processes. The angular antenna patterns of TSA-coupled diodes are measured at 10.6 micrometer wavelength in both E- and H-planes, and are compared to results of finite-element electromagnetic modeling using Ansoft HFSS. Parameter studies are …

Evanescent Wave Coupling Using Different Subwavelength Gratings For A Mems Accelerometer, Al-Aakhir A. Rogers

USF Tampa Graduate Theses and Dissertations

A novel technique of coupling near-field evanescent waves by means of variable period subwavelength gratings (1.2 ìm and 1.0 ìm), using a 1.55 ìm infrared semiconductor laser is presented for the use of an optical MEMS accelerometer. The subwavelength gratings were fabricated on both glass and silicon substrates respectively.

Optical simulation of the subwavelength gratings was carried out to obtain the maximum coupling efficiency of the two subwavelength gratings; the grating thickness, grating width, and the grating separation were optimized. This was performed for both silicon and glass substrates.

The simulations were used to determine the total system noise, including …

Vibrational Spectroscopic Study Of The 1,3,5,7-Cyclooctatetraene At High Static Pressures, Edward Romano

UNLV Theses, Dissertations, Professional Papers, and Capstones

1,3,5,7-cyclooctatetraene (COT) is a single-ringed hydrocarbon that has not been studied extensively under high static pressures. It was the intent of this study to reveal its high-pressure behavior through its vibrational spectra. To this end, its infrared spectra as a function of pressure were collected at the National Synchrotron Light Source (NSLS) U2A beamline, as well as its Raman spectra over pressure using a micro-Raman spectrometer.

The spectra show the typical stiffening of force constants with increasing pressure for most peaks, particularly those which would theoretically exhibit a mode-softening behavior under hypotheses of molecular planarization and aromatization. Additionally, the data …

Surface Plasmon Hosts For Infrared Waveguides And Biosensors, And Plasmons In Gold-Black Nano-Structured Films, Justin Cleary

Electronic Theses and Dissertations

Applications of surface plasmon polaritons (SPPs) have thus far emphasized visible and near-infrared wavelengths. Extension into the long-wave infrared (LWIR) has numerous potential advantages for biosensors and waveguides, which are explored in this work. A surface plasmon resonance (SPR) biosensor that operates deep into the infrared (3-11 µm wavelengths) is potentially capable of biomolecule recognition based on both selective binding and characteristic vibrational modes. The goal is to operate such sensors at wavelengths where biological analytes are strongly differentiated by their IR absorption spectra and where the refractive index is increased by dispersion, which will provide enhanced selectivity and sensitivity. …

Spectroscopic Study Of The Inhibition Of Calcium Oxalate Calculi By Larrea Tridentata, Luis Alonso Pinales

Open Access Theses & Dissertations

The causes of urolithiasis include such influences as diet, metabolic disorders, and genetic factors which have been documented as sources that aggravate urinary calculi depositions and aggregations, and, implicitly, as causes of urolithiasis. This study endeavors to detail the scientific mechanisms involved in calcium oxalate calculi formation, and, more importantly, their inhibition under growth conditions imposed by the traditional medicinal approach using the herbal extract, Larrea tridentata. The calculi were synthesized without and with Larrea tridentata infusion by employing the single diffusion gel technique. A visible decrease in calcium oxalate crystal growth with increasing amounts of Larrea tridentata herbal infusion …

Spectroscopic Analysis Of Tungsten Oxide Thin Films For Sensor Applications, Jose Luis Enriquez Carrejo

Open Access Theses & Dissertations

The objective of this study is targeted toward improving the quality of pure tungsten oxide (WO3) for application to the detection of poisoning gases, especially of H2S. While pure WO3 is a recognized candidate for gas sensing, its characteristics are strongly dependent on the conditions and methods used in its deposition.

Samples of WO3 thin films analyzed in this work were grown on silicon and sapphire substrates using RF magnetron sputtering at a number of different substrate temperatures and Ar:O2 pressure ratios. The properties of the samples were investigated spectroscopically with the goal of determining how variations in the above …

Probing The Complex Magnetic, Electronic And Structural Properties In Correlated Manganese Oxides, Peng Gao

Dissertations

Rare-earth Manganese Oxides (RMnO₃) exhibit two distinct structural phases: the orthorhombic structure and the hexagonal structure. The doped orthorhombic phase exhibits a metal to insulator transition, charge ordering and a strong response of electron transport properties to magnetic fields (colossal magneto-resistance). At low temperatures, this system may also exhibit a finite polarization which couples to external magnetic fields. The hexagonal phase is known to have a large spontaneous polarization at high temperatures which couples to the low temperature magnetic order. These materials are important from the basic point of view of understanding strong electronic correlations and …

Sizing Up The Stars, Tabetha Suzanne Boyajian

Physics and Astronomy Dissertations

For the main part of this dissertation, I have executed a survey of nearby, main sequence A, F, and G-type stars with the CHARA Array, successfully measuring the angular diameters of forty-four stars to better than 4% accuracy. The results of these observations also yield empirical determinations of stellar linear radii and effective temperatures for the stars observed. In addition, these CHARA-determined temperatures, radii, and luminosities are fit to Yonsei-Yale isochrones to constrain the masses and ages of the stars. These quantities are compared to the results found in Allende Prieto & Lambert (1999), Holmberg et al. (2007), and Takeda …

Dust Within The Central Regions Of Seyfert Galaxies, Rajesh Deo

Physics and Astronomy Dissertations

We present a detailed study of mid-infrared spectroscopy and optical imaging of Seyfert galaxies with the goal of understanding the properties of astronomical dust around the central supermassive black hole and the accretion disk. Specifically, we have studied Spitzer Space Telescope mid-infrared spectra of 12 Seyfert 1.8-1.9s and 58 Seyfert 1s and 2s available in the Spitzer public archive, and the nuclear dust morphology in the central 500 pc of 91 narrow and broad-line Seyfert 1s using optical images from the Hubble Space Telescope. We have also developed visualization software to aid the understanding of the geometry of the central …

Electrical And Optical Characterization Of Group Iii-V Heterostructures With Emphasis On Terahertz Devices, Aruna Bandara Weerasekara

Physics and Astronomy Dissertations

Electrical and optical characterizations of heterostructures and thin films based on group III-V compound semiconductors are presented. Optical properties of GaMnN thin films grown by Metalorganic Chemical Vapor Deposition (MOCVD) on GaN/Sapphire templates were investigated using IR reflection spectroscopy. Experimental reflection spectra were fitted using a non - linear fitting algorithm, and the high frequency dielectric constant (ε∞), optical phonon frequencies of E1(TO) and E1(LO), and their oscillator strengths (S) and broadening constants (Γ) were obtained for GaMnN thin films with different Mn fraction. The high frequency dielectric constant (ε∞) of InN thin films grown by the high pressure chemical …

Evanescent Field Absorption Sensing Using Sapphire Fibers, Michael Grossman

USF Tampa Graduate Theses and Dissertations

This thesis explores the application of coiled sapphire multimode optical fibers for evanescent wave chemical sensing in both the visible spectrum and the near infrared. As has been suggested in the literature pertaining to silica fibers, bending converts low-order modes to high order ones, which leads to more evanescent absorption and thus a more sensitive chemical detector. By coiling the fiber many times, it was expected that even greater sensitivity would be attained.

Experiments were performed to investigate the sensor response to different solutions and to characterize this response. In the first of three experiments, the large absorption peak of …