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2000

Organic superconductors

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Full-Text Articles in Physics

Shubnikov–De Haas Effect In The Superconducting State Of An Organic Superconductor, J. Wosnitza, S. Wanka, J. Hagel, R. Häussler, H. V. Löhneysen, J. A. Schlueter, U. Geiser, P. G. Nixon, Rolf Walter Winter, Gary L. Gard Nov 2000

Shubnikov–De Haas Effect In The Superconducting State Of An Organic Superconductor, J. Wosnitza, S. Wanka, J. Hagel, R. Häussler, H. V. Löhneysen, J. A. Schlueter, U. Geiser, P. G. Nixon, Rolf Walter Winter, Gary L. Gard

Chemistry Faculty Publications and Presentations

We report the observation of Shubnikov–de Haas (SdH) oscillations in the mixed state of the organic superconductor β″-(BEDT-TTF)₂SF₅CH₂CF₂SO₃ (Tc≈4.4K). At low temperatures the SdH oscillations persist clearly below the upper critical field Bc₂(0)≈3.6 T almost down to the field where the resistivity vanishes. Rather unusually, no additional damping of the SdH-signal amplitude — as well as of the de Haas–van Alphen amplitude — is observed in the superconducting state. This indicates that the damping in the vortex state of this quasi-two-dimensional superconductor is different in character to that observed for most three-dimensional materials.


Comparative Thermal-Expansion Study Of Β″-(Et)2sf5ch2cf2so3 And Κ-(Et)2cu(Ncs)2: Uniaxial Pressure Coefficients Of Tc And Upper Critical Fields, J. Müller, M. Lang, F. Steglich, J. A. Schlueter, A. M. Kini, U. Geiser, Javid Mohtasham, Rolf Walter Winter, Gary L. Gard, T. Sasaki, N. Toyota May 2000

Comparative Thermal-Expansion Study Of Β″-(Et)2sf5ch2cf2so3 And Κ-(Et)2cu(Ncs)2: Uniaxial Pressure Coefficients Of Tc And Upper Critical Fields, J. Müller, M. Lang, F. Steglich, J. A. Schlueter, A. M. Kini, U. Geiser, Javid Mohtasham, Rolf Walter Winter, Gary L. Gard, T. Sasaki, N. Toyota

Chemistry Faculty Publications and Presentations

We report high-resolution measurements of the coefficient of thermal expansion, α=l⁻¹ x (δl/δΤ), on single crystals of the organic superconductors β″-(ET)₂SF₅CH₂CF₂SO₃ and κ-(ET)₂Cu(NCS)₂. For both salts we find large and highly anisotropic phase-transition anomalies at Tc. Combining these data with literature results on the specific heat via the Ehrenfest relation, the uniaxial pressure coefficients of Tc can be determined. Most remarkably, a strikingly similar in-plane vs out-of-plane anisotropy is found for both compounds: the strong suppression of Tc observed in hydrostatic-pressure experiments is dominated by a huge negative uniaxial stress effect perpendicular to the conducting planes. Therefore we expect that …


Two-Dimensional Fermi Liquid With Fixed Chemical Potential, J. Wosnitza, S. Wanka, J. Hagel, E. Balthes, N. Harrison, J. A. Schlueter, A. M. Kini, U. Geiser, Javid Mohtasham, Rolf Walter Winter, Gary L. Gard Mar 2000

Two-Dimensional Fermi Liquid With Fixed Chemical Potential, J. Wosnitza, S. Wanka, J. Hagel, E. Balthes, N. Harrison, J. A. Schlueter, A. M. Kini, U. Geiser, Javid Mohtasham, Rolf Walter Winter, Gary L. Gard

Chemistry Faculty Publications and Presentations

de Haas-van Alphen measurements made on the organic metal β″-(ET)₂SF₅CH₂CF₂SO₃ reveal the existence of an ideal two-dimensional (2D) Fermi surface, but rather than having the conventional sawtooth wave form that is normally observed in all other 2D electron gases, instead, an ‘‘inverse sawtooth’’ wave form is observed, which is to be expected when the chemical potential is pinned at a constant value. While this proves the existence of the theoretically predicted quasi-one-dimensional band, it further implies that this band has an exceptionally large density of states.