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Nuclear-Spin-Relaxation Study Of Internal Motion In Two Organic Molecular Solids, Alfonso M. Albano, Peter A. Beckmann, M. E. Carrington, E. E. Fisch, F. A. Fusco, A. E. O'Neill, Mary E. Scott
Nuclear-Spin-Relaxation Study Of Internal Motion In Two Organic Molecular Solids, Alfonso M. Albano, Peter A. Beckmann, M. E. Carrington, E. E. Fisch, F. A. Fusco, A. E. O'Neill, Mary E. Scott
Physics Faculty Research and Scholarship
We investigate proton spin-lattice relaxation in two powdered organic molecular solids with reorienting methyl (CH3) and tert-butyl [C(CH3)3] groups: 3,5-di-tert-butylphenol (DTBP) and 1,3,5-tri-tert-butylbenzene (TTBZ). The temperature and Larmor frequency dependence of the relaxation rate is considerably more complicated than would be expected on the basis of random reorientations of the CH3 and C(CH3)3 groups. The spectral densities describing the relaxation are broader, and show more structure, than those customarily used to interpret relaxation data. Assuming that the spectral densities may be expressed as linear superpositions of Lorentzians, we are able to obtain a single, nonexponential correlation function which leads to …