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Full-Text Articles in Physics
Fluctuant Magnetism In Metal Oxide Nanocrystals Capped With Surfactants, Aaron Thurber, Michael S. Jones, Dmitri Tenne, Charles B. Hanna, Alex Punnoose
Fluctuant Magnetism In Metal Oxide Nanocrystals Capped With Surfactants, Aaron Thurber, Michael S. Jones, Dmitri Tenne, Charles B. Hanna, Alex Punnoose
Physics Faculty Publications and Presentations
We demonstrate experimentally that magnetism in ZnO, TiO2, CeO2, andSnO2 nanocrystals (NCs) has a fluctuant nature that varies with capping surfactant type and concentration. By developing a forced hydrolysis approach with additional postprocessing for the synthesis and surfactant capping of these NCs, we effectively avoid the influence of size, shape, and magnetic impurities on the magnetic behavior of NCs, thus revealing the systematic influence of the capping surfactants on the NC magnetism. The x-ray photoelectron spectroscopy results and theoretical calculations clearly show that the magnetism fluctuation with surfactant concentration can be attributed to the periodic …
Optimization Of Force Sensitivity In Q-Controlled Amplitude-Modulation Atomic Force Microscopy, Jongwoo Kim, Baekman Sung, Byung I. Kim, Wonho Jhe
Optimization Of Force Sensitivity In Q-Controlled Amplitude-Modulation Atomic Force Microscopy, Jongwoo Kim, Baekman Sung, Byung I. Kim, Wonho Jhe
Physics Faculty Publications and Presentations
We present control of force sensitivity in Q-controlled amplitude-modulation atomic force microscopy (AM-AFM) that is based on the high-Q quartz tuning-fork. It is found that the phase noise is identical to the amplitude noise divided by oscillation amplitude in AM-AFM. In particular, we observe that while Q-control does not compromise the signal-to-noise ratio, it enhances the detection sensitivity because the minimum detectable force gradient is inversely proportional to the effective quality factor for large bandwidths, which is due to reduction of frequency noise. This work demonstrates Q-control in AM-AFM is a useful technique for enhancement of …
Direct Observation Of Self-Assembled Chain-Like Water Structures In A Nanoscopic Water Meniscus, Byung I. Kim, Ryan D. Boehm, Jeremy R. Bonander
Direct Observation Of Self-Assembled Chain-Like Water Structures In A Nanoscopic Water Meniscus, Byung I. Kim, Ryan D. Boehm, Jeremy R. Bonander
Physics Faculty Publications and Presentations
Sawtooth-like oscillatory forces generated by water molecules confined between two oxidized silicon surfaces were observed using a cantilever-based optical interfacial force microscope when the two surfaces approached each other in ambient environments. The humidity-dependent oscillatory amplitude and periodicity were 3-12 nN and 3-4 water diameters, respectively. Half of each period was matched with a freely jointed chain model, possibly suggesting that the confined water behaved like a bundle of water chains. The analysis also indicated that water molecules self-assembled to form chain-like structures in a nanoscopic meniscus between two hydrophilic surfaces in air. From the friction force data measured simultaneously, …
Magnetic Properties Of Fe Doped, Co Doped, And Fe+Co Co-Doped Zno, J. J. Beltrán, J. A. Osorio, C. A. Barrero, Charles B. Hanna, A. Punnoose
Magnetic Properties Of Fe Doped, Co Doped, And Fe+Co Co-Doped Zno, J. J. Beltrán, J. A. Osorio, C. A. Barrero, Charles B. Hanna, A. Punnoose
Physics Faculty Publications and Presentations
The structural, electronic, and magnetic properties of Zn0.95Co0.05O, Zn0.95Fe0.05O, and Zn0.90Fe0.05Co0.05O nanoparticles prepared by a sol-gel method are presented and discussed. X-ray diffraction and optical analysis indicated that high spin Co2+ ions substitute for the Zn2+ ions in tetrahedral sites. 57Fe Mössbauer spectroscopy showed the presence of isolated paramagnetic Fe3+ ions in both Fe doped and Fe+Co co-doped ZnO, however, no evidence of ferromagnetically ordered Fe3+ ions is observed. In the Zn0.95Fe0.05O sample, weak presence of ZnFe …
Cantilever-Based Optical Interfacial Force Microscope In Liquid Using An Optical-Fiber Tip, Byung I. Kim, Luke Smith, Thanh Tran, Steven Rossland, Erik Parkinson
Cantilever-Based Optical Interfacial Force Microscope In Liquid Using An Optical-Fiber Tip, Byung I. Kim, Luke Smith, Thanh Tran, Steven Rossland, Erik Parkinson
Physics Faculty Publications and Presentations
We developed a novel cantilever-based optical interfacial force microscope (COIFM) to study molecular interaction in liquid environments. The force sensor was created by attaching a chemically etched optical-fiber tip to the force sensor with UV epoxy, and characterized by imaging on a calibration grid. The performance of the COIFM was then demonstrated by measuring the force between two oxidized silicon surfaces in 1 mM KCl as a function of distance. The result was consistent with previously reported electrical double layer forces, suggesting that a COIFM using an optical-fiber tip is capable of measuring force in a liquid environment.
Imaging Stability In Force-Feedback High-Speed Atomic Force Microscopy, Byung I. Kim, Ryan Boehm
Imaging Stability In Force-Feedback High-Speed Atomic Force Microscopy, Byung I. Kim, Ryan Boehm
Physics Faculty Publications and Presentations
We studied the stability of force-feedback high-speed atomic force microscopy (HSAFM) by imaging soft, hard, and biological sample surfaces at various applied forces. The HSAFM images showed sudden topographic variations of streaky fringes with a negative applied force when collected on a soft hydrocarbon film grown on a grating sample, whereas they showed stable topographic features with positive applied forces. The instability of HSAFM images with the negative applied force was explained by the transition between contact and noncontact regimes in the force-distance curve. When the grating surface was cleaned, and thus hydrophilic by removing the hydrocarbon film, enhanced imaging …