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Restricted Dislocation Motion In Crystals Of Colloidal Dimer Particles, Sharon J. Gerbode, Stephanie H. Lee, Chekesha M. Liddell, Itai Cohen
Restricted Dislocation Motion In Crystals Of Colloidal Dimer Particles, Sharon J. Gerbode, Stephanie H. Lee, Chekesha M. Liddell, Itai Cohen
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Received 2 April 2008; published 1 August 2008; corrected 1 October 2008
At high area fractions, monolayers of colloidal dimer particles form a degenerate crystal (DC) structure in which the particle lobes occupy triangular lattice sites while the particles are oriented randomly along any of the three lattice directions. We report that dislocation glide in DCs is blocked by certain particle orientations. The mean number of lattice constants between such obstacles is Z̅ exp=4.6±0.2 in experimentally observed DC grains and Z̅ sim=6.18±0.01 in simulated monocrystalline DCs. Dislocation propagation beyond these obstacles is observed to proceed through dislocation reactions. …