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Series

All HMC Faculty Publications and Research

2008

Condensed Matter Physics

Articles 1 - 2 of 2

Full-Text Articles in Physics

Synthesis And Assembly Of Nonspherical Hollow Silica Colloids Under Confinement, Stephanie H. Lee, Sharon J. Gerbode, Bettina S. John, Angie K. Wolfgang, Fernando A. Escobedo, Itai Cohen, Chekesha M. Liddell Sep 2008

Synthesis And Assembly Of Nonspherical Hollow Silica Colloids Under Confinement, Stephanie H. Lee, Sharon J. Gerbode, Bettina S. John, Angie K. Wolfgang, Fernando A. Escobedo, Itai Cohen, Chekesha M. Liddell

All HMC Faculty Publications and Research

Hard peanut-shaped colloids were synthesized and organized into a degenerate crystal (DC), a phase previously observed only in simulations. In this structure, particle lobes tile a triangular lattice while their orientations uniformly populate the three underlying crystalline directions.


Restricted Dislocation Motion In Crystals Of Colloidal Dimer Particles, Sharon J. Gerbode, Stephanie H. Lee, Chekesha M. Liddell, Itai Cohen Aug 2008

Restricted Dislocation Motion In Crystals Of Colloidal Dimer Particles, Sharon J. Gerbode, Stephanie H. Lee, Chekesha M. Liddell, Itai Cohen

All HMC Faculty Publications and Research

Received 2 April 2008; published 1 August 2008; corrected 1 October 2008

At high area fractions, monolayers of colloidal dimer particles form a degenerate crystal (DC) structure in which the particle lobes occupy triangular lattice sites while the particles are oriented randomly along any of the three lattice directions. We report that dislocation glide in DCs is blocked by certain particle orientations. The mean number of lattice constants between such obstacles is Z̅ exp=4.6±0.2 in experimentally observed DC grains and Z̅ sim=6.18±0.01 in simulated monocrystalline DCs. Dislocation propagation beyond these obstacles is observed to proceed through dislocation reactions. …