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Transition Probabilities And Franck-Condon Factors For The Second Negative Band System Of O2+, Jane L. Fox, Alexander Dalgarno

Physics Faculty Publications

Transition probabilities for the second negative band system of O₂⁺ are computed using the dipole transition moment presented by Wetmore et al. [1984]. Vibrational levels υ″ = 0 − 54 of the X²Π_g ground state and υ′ = 0 − 33 of the excited A²Π_u state are included. Franck-Condon factors for ionization-excitation of O₂ (X³Σ_g⁻; υ = 0 − 25) to O₂⁺(A²Π_u;υ′ = 0 − 33) are also presented.