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State-To-State Rotational Rate Constants For Co+He: Infrared Double Resonance Measurements And Simulation Of The Data Using The Sapt Theoretical Potential Energy Surface, Tony C. Smith, David A. Hostutler, Gordon D. Hager, Michael C. Heaven, George C. Mcbane
State-To-State Rotational Rate Constants For Co+He: Infrared Double Resonance Measurements And Simulation Of The Data Using The Sapt Theoretical Potential Energy Surface, Tony C. Smith, David A. Hostutler, Gordon D. Hager, Michael C. Heaven, George C. Mcbane
Peer Reviewed Articles
An extensive data set of 54 time-resolved pump-probe measurements was used to examine CO+He rotational energy transfer within the CO v=2 rotational manifold. Rotational levels in the range Ji=2-9 were excited and collisional energy transfer of population to the levels Jf=1-10 was monitored. The resulting data set was analyzed by fitting to numerical solutions of the master equation. State-to-state rate constant matrices were generated using fitting law functions and ab initio theoretical calculations that employed the SAPT potential energy surface of Heijmen et al. [J. Chem. Phys. 107, 9921 (1997)]. Fitting laws based on …