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Intergranular Phases In Cyclically Annealed Yba2cu3o7-X And Their Implications For Critical Current Densities, Andrew Peter Clarke

All Graduate Theses and Dissertations, Spring 1920 to Summer 2023

We report changes in the intergranular material and grain morphology of YBa₂Cu₃O_7-x during cyclic anneals between 780 and 980 ºC in oxygen at atmospheric pressure. Two endothermic reactions were detected: (a) the eutectic reaction of YBa₂Cu₃O_7-x with CuO and BaCuO₂ at 900 ºC (enthalpy ∆H_a) and (b) the peritectic reaction of YBa₂Cu₃O_7-x with CuO at 950 ºC (∆H_b). During the first anneal, only reaction (b) is detected, and although it should only occur if there is an excess of CuO, …