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University of Nebraska - Lincoln

Stephen Ducharme Publications

Ferroelectricity

Articles 1 - 4 of 4

Full-Text Articles in Physics

The Promise Of Piezoelectric Polymers, Timothy D. Usher, Kimberley R. Cousins, Renwu Zhang, Stephen Ducharme Jan 2018

The Promise Of Piezoelectric Polymers, Timothy D. Usher, Kimberley R. Cousins, Renwu Zhang, Stephen Ducharme

Stephen Ducharme Publications

Recent advances provide new opportunities in the field of polymer piezoelectric materials. Piezoelectric materials provide unique insights to the fundamental understanding of the solid state. In addition, piezoelectric materials have a wide range of applications, representing billions of dollars of commercial applications. However, inorganic piezoelectric materials have limitations that polymer ferroelectric materials can overcome, if certain challenges can be addressed. This mini-review is a practical summary of the current research and future directions in the investigation and application of piezoelectric materials with an emphasis on polymeric piezoelectric materials. We will assume that the reader is well versed in the subject …


Fabrication Of Diisopropylammonium Bromide Aligned Microcrystals With In-Plane Uniaxial Polarization, Shashi Poddar, Haidong Lu, Jingfeng Song, Om Goit, Shah Valloppilly, Alexei Gruverman, Stephen Ducharme Jan 2016

Fabrication Of Diisopropylammonium Bromide Aligned Microcrystals With In-Plane Uniaxial Polarization, Shashi Poddar, Haidong Lu, Jingfeng Song, Om Goit, Shah Valloppilly, Alexei Gruverman, Stephen Ducharme

Stephen Ducharme Publications

Textured arrays of ferroelectric microcrystals of diisopropylammonium bromide were grown from solution at room temperature onto silicon substrates and studied by means of x-ray diffraction, atomic force microscopy, electron microscopy, and piezoresponse force microscopy. The needle-shaped crystals had dimensions of approximately 50 μm × 5 μm in the plane and were approximately 200 nm thick, where the dimensions and arrangement were influenced by growth conditions. The observations suggest an Ostwald ripening mechanism of the microcrystal growth. The crystals had the structure of the ferroelectric phase, where the polarization axis was in-plane and parallel to the long axis of …


The Ferroelectricity At The Nanoscale, Vladimir M. Fridkin, Stephen Ducharme Jan 2014

The Ferroelectricity At The Nanoscale, Vladimir M. Fridkin, Stephen Ducharme

Stephen Ducharme Publications

The review of ferroelectric properties at the nanoscale is presented. Determining the nanoscale, authors bear in mind the film thickness equal by the order of value to the size of critical domain nucleus. Three phenomena are considered: ferroelectric switching, scaling of coercive field and bulk photovoltaic effect. The investigation of ferroelectricity at the nanoscale started 20 years ago. The nanoscaled ferroelectricics with perovskite structure came to be considered only the last few years.


Why Ferroelectric Polyvinylidene Fluoride Is Special, Matt Poulsen, Stephen Ducharme Jan 2010

Why Ferroelectric Polyvinylidene Fluoride Is Special, Matt Poulsen, Stephen Ducharme

Stephen Ducharme Publications

Ferroelectric polymers entail a number of constraints, which together limit the useful compositional variations. These constraints include the following: a stable molecular dipole moment, compact crystal structure, conformational flexibility, and minimal steric hindrance. They are well satisfied by the prototype ferroelectric polymer, polyvinylidene fluoride, and yet almost every other conceivable molecular structure is limited by comparison.