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University of Central Florida

Theses/Dissertations

Raman spectroscopy

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Development Of Laser Spectroscopy For Elemental And Molecular Analysis, Yuan Liu Jan 2013

Development Of Laser Spectroscopy For Elemental And Molecular Analysis, Yuan Liu

Electronic Theses and Dissertations

Laser-Induced Breakdown Spectroscopy (LIBS) and Raman spectroscopy are still growing analytical and sensing spectroscopic techniques. They significantly reduce the time and labor cost in analysis with simplified instrumentation, and lead to minimal or no sample damage. In this dissertation, fundamental studies to improve LIBS analytical performance were performed and its fusion with Raman into one single sensor was explored. On the fundamental side, Thomson scattering was reported for the first time to simultaneously measure the electron density and temperature of laser plasmas from a solid aluminum target at atmospheric pressure. Comparison between electron and excitation temperatures brought insights into the …


Raman Spectroscopy Of Glasseswith High And Broad Raman Gain In The Boson Peak Region, Yu Guo Jan 2006

Raman Spectroscopy Of Glasseswith High And Broad Raman Gain In The Boson Peak Region, Yu Guo

Electronic Theses and Dissertations

This thesis investigates Raman spectra of novel glasses and their correlation with structure for Raman gain applications. Raman gain for all-optical amplification by fibers depends significantly on the cross section for spontaneous Raman scattering allowing to compare signal strength and spectral coverage. We also investigate the relationship between glass structure and the Boson peak (enhancement of the low-frequency vibrational density of states) and report new inelastic neutron scattering spectra for niobium-phosphate glasses. Polarization resolved Raman spectra of glasses based on tellurite and phosphate formers have been measured from 6 – 1500 cm-1 using an excitation wavelength of 514 nm. The …


High Gain / Broadband Oxide Glasses For Next Generation Raman Amplifiers, Clara Rivero Jan 2005

High Gain / Broadband Oxide Glasses For Next Generation Raman Amplifiers, Clara Rivero

Electronic Theses and Dissertations

Interest in Raman amplification has undergone a revival due to the rapidly increasing bandwidth requirements for communications transmission, both for long haul and local area networks, and recent developments in the telecom fiber industry and diode laser technology. In contrast to rare earth doped fiber amplifiers, for which the range of wavelengths is fixed and limited, Raman gain bandwidths are larger and the operating wavelength is fixed only by the pump wavelength and the bandwidth of the Raman active medium. In this context, glasses are the material of choice for this application due to their relatively broad spectral response, and …


Towards Direct Writing Of 3-D Photonic Circuits Using Ultrafast Lasers, Arnaud Zoubir Jan 2004

Towards Direct Writing Of 3-D Photonic Circuits Using Ultrafast Lasers, Arnaud Zoubir

Electronic Theses and Dissertations

The advent of ultrafast lasers has enabled micromachining schemes that cannot be achieved by other current techniques. Laser direct writing has emerged as one of the possible routes for fabrication of optical waveguides in transparent materials. In this thesis, the advantages and limitations of this technique are explored. Two extended-cavity ultrafast lasers were built and characterized as the laser sources for this study, with improved performance over existing systems. Waveguides are fabricated in oxide glass, chalcogenide glass, and polymers, these being the three major classes of materials for the telecommunication industry. Standard waveguide metrology is performed on the fabricated waveguides, …