Open Access. Powered by Scholars. Published by Universities.®
Articles 1 - 4 of 4
Full-Text Articles in Physics
Defect Driven Magnetism In Doped Sno2 Nanoparticles: Surface Effects, Pushpa Raghani, Pankaj Kumar, Balaji Ramanujam, Alex Punnoose
Defect Driven Magnetism In Doped Sno2 Nanoparticles: Surface Effects, Pushpa Raghani, Pankaj Kumar, Balaji Ramanujam, Alex Punnoose
Pushpa Raghani
Magnetism and energetics of intrinsic and extrinsic defects and defect clusters in bulk and surfaces of SnO2 is investigated using first-principles to understand the role of surfaces in inducing magnetism in Zn doped nanoparticles. We find that Sn vacancies induce the largest magnetic moment in bulk and on surfaces. However, they have very large formation energies in bulk as well as on surfaces. Oxygen vacancies on the other hand are much easier to create than VSn, but neutral and VO+2 vacancies do not induce any magnetism in bulk as well as on surfaces. VO+1 induce small magnetism in bulk and …
Helical Single-Lamellar Crystals Thermotropically Formed In A Synthetic Nonracemic Chiral Main-Chain Polyester, Christopher Y. Li, Donghang Yan, Stephen Z. D. Cheng, Feng Bai, Jason J. Ge, Bret H. Calhoun, Tianbai He, Liang-Chy Chien, Frank W. Harris, Bernard Lotz
Helical Single-Lamellar Crystals Thermotropically Formed In A Synthetic Nonracemic Chiral Main-Chain Polyester, Christopher Y. Li, Donghang Yan, Stephen Z. D. Cheng, Feng Bai, Jason J. Ge, Bret H. Calhoun, Tianbai He, Liang-Chy Chien, Frank W. Harris, Bernard Lotz
Liang-Chy Chien
Phase structures and transformation mechanisms of nonracemic chiral biological and synthetic polymers are fundamentally important topics in understanding their macroscopic responses in different environments. It has been known for many years that helical structures and morphologies can exist in low-ordered chiral liquid crystalline (LC) phases. However, when the chiral liquid crystals form highly ordered smectic liquid crystal phases, the helical morphology is suppressed due to the crystallization process. A double-twisted morphology has been observed in many liquid crystalline biopolymers such as dinoflaggellate chromosomes (in Prorocentrum micans) in an in vivo arrangement. Helical crystals grown from solution have been reported in …
Viscoelasticity, Dielectric Anisotropy, And Birefringence In The Nematic Phase Of Three Four-Ring Bent-Core Liquid Crystals With An L-Shaped Molecular Frame, Nejmettin Acvi, Volodymyr Borshch, Dipika Debnath Sarkar, Rahul Deb, Gude Venkatesh, Taras Turiv, Sergij V. Shiyanovskii, Nandiraju V. S. Rao, Oleg Lavrentovich
Viscoelasticity, Dielectric Anisotropy, And Birefringence In The Nematic Phase Of Three Four-Ring Bent-Core Liquid Crystals With An L-Shaped Molecular Frame, Nejmettin Acvi, Volodymyr Borshch, Dipika Debnath Sarkar, Rahul Deb, Gude Venkatesh, Taras Turiv, Sergij V. Shiyanovskii, Nandiraju V. S. Rao, Oleg Lavrentovich
Oleg Lavrentovich
Molecular shape is an important factor in determining the material properties of thermotropic liquid crystals (LCs). We synthesized and investigated several LC compounds formed by asymmetrically bent molecules with a rigid four-ring core in the shape of the letter 'L'. We measured the temperature dependencies of dielectric permittivities, birefringence, splay K-1 and bend K-3 elastic constants, splay viscosity eta(splay) and flow viscosities eta(parallel to) and eta(perpendicular to). The bend-splay anisotropy delta K-31 - K-3 - K-1 is negative, similar to the case of nematic LCs formed by symmetrically bent molecules of V-shape. The dielectric anisotropy Delta epsilon and birefringence are …
Crossing Of Disclinations In Nematic Slabs, T. Ishikawa, Oleg Lavrentovich
Crossing Of Disclinations In Nematic Slabs, T. Ishikawa, Oleg Lavrentovich
Oleg Lavrentovich
It is shown experimentally that crossing and intercommutation of disclinations in a bounded nematic cell depend on surface orientation of the director and the relative strength of disclinations. Lines of opposite strength switch the pinned ends between the bounding plates and vanish independently of each other if the surface orientation is tangential. In contrast, tilted surface orientation preserves the stability of lines.