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Self-Assembled Composite Nano-/Micronecklaces With Sio2 Beads In Boron Strings, Hai Ni, Xiaodong Li

Xiaodong Li

Nano-/micronecklaces with SiO₂ beads in boron strings were synthesized by simply sublimating the desired powders in a sealed quartz tube at high temperature. The boron strings have a rectangular cross section with width varying from 80to1000nm while the SiO₂ beads bear either spindle or spherical shape with a size ranging from 100nmto5μm. The spacing between the SiO₂ beads is uniform in each boron string. Both the boron strings and the SiO₂ beads are amorphous and free of defects. The supersaturated vapors of silicon and oxygen induced the SiO₂ bead formation.