Physics Commons^™

Architecture Of Heptagonal Metallo-Macrocycles Via Embedding Metal Nodes Into Its Rigid Backbone, A.M.Shashika D. Wijerathna, He Zhao, Qiangqiang Dong, Qixia Bai, Zhiyuan Jiang, Jie Yuan, Jun Wang, Mingzhao Chen, Markus Zirnheld, Rockwell T. Li, Yuan Zhang, Yiming Li, Pingshan Wang

College of Sciences Posters

Metal-organic macrocycles have received increasing attention not only due to their versatile applications such as molecular recognition, compounds encapsulation, anti-bacteria and others, but also for their important role in the study of structure-property relationship at nano scale. However, most of the constructions utilize benzene ring as the backbone, which restricts the ligand arm angle in the range of 60, 120 and 180 degrees. Thus, the topologies of most metallo-macrocycles are limited as triangles and hexagons, and explorations of using other backbones with large angles and the construction of metallo-macrocycles with more than six edges are very rare.

In this study, …

Characterization Of Losses In Superconducting Radio-Frequency Cavities By Combined Temperature And Magnetic Field Mapping, Ishwari Prasad Parajuli

Physics Theses & Dissertations

Superconducting radio-frequency (SRF) cavities are one of the fundamental building blocks of modern particle accelerators. To achieve the highest quality factors (10¹⁰-10¹¹), SRF cavities are operated at liquid helium temperatures. Magnetic flux trapped on the surface of SRF cavities during cool-down below the critical temperature is one of the leading sources of residual RF losses. Instruments capable of detecting the distribution of trapped flux on the cavity surface are in high demand in order to better understand its relation to the cavity material, surface treatments and environmental conditions. We have designed, developed, and commissioned two novel …

Multi-Technique Characterization Of Superconducting Materials For Particle Accelerator Applications, Junki Makita

Physics Theses & Dissertations

We investigated the performance limitations of superconducting radio-frequency (SRF) cavities and materials using multiple experimental techniques. In particular, this study focuses on understanding the surface properties of nitrogen-doped Nb cavities and superconducting thin films with higher T_c such as Nb₃Sn. The main goal of this work is to use different techniques to better understand each aspect of the complex loss mechanism in superconductors to further improve the already highly efficient SRF cavities.

Nitrogen doping applied to a Nb SRF cavity significantly improves the quality factor Q₀ compared to a conventional Nb cavity, at an expense of …

Multi-Metallic Conduction Cooled Superconducting Radio-Frequency Cavity With High Thermal Stability, Gianluigi Ciovati, Gary Cheng, Uttar Pudasaini, Robert A. Rimmer

Physics Faculty Publications

Superconducting radio-frequency cavities are commonly used in modern particle accelerators for applied and fundamental research. Such cavities are typically made of high-purity, bulk Nb and with cooling by a liquid helium bath at a temperature of ∼2 K. The size, cost and complexity of operating a particle accelerator with a liquid helium refrigerator make the current cavity technology not favorable for use in industrial-type accelerators. We have developed a multi-metallic 1.495 GHz elliptical cavity conductively cooled by a cryocooler. The cavity has a ∼2 μm thick layer of Nb₃Sn on the inner surface, exposed to the rf field, …

Current-Driven Production Of Vortex-Antivortex Pairs In Planar Josephson Junction Arrays And Phase Cracks In Long-Range Order, Francisco Estellés-Duart, Miguel Ortuño, Andrés M. Somoza, Valerii M. Vinokur, Alex Gurevich

Physics Faculty Publications

Proliferation of topological defects like vortices and dislocations plays a key role in the physics of systems with long-range order, particularly, superconductivity and superfluidity in thin films, plasticity of solids, and melting of atomic monolayers. Topological defects are characterized by their topological charge reflecting fundamental symmetries and conservation laws of the system. Conservation of topological charge manifests itself in extreme stability of static topological defects because destruction of a single defect requires overcoming a huge energy barrier proportional to the system size. However, the stability of driven topological defects remains largely unexplored. Here we address this issue and investigate numerically …

Tuning Vortex Fluctuations And The Resistive Transition In Superconducting Films With A Thin Overlayer, Alex Gurevich

Physics Faculty Publications

It is shown that the temperature of the resistive transition T_r of a superconducting film can be increased by a thin superconducting or normal overlayer. For instance, deposition of a highly conductive thin overlayer onto a dirty superconducting film can give rise to an “antiproximity effect,” which manifests itself in an initial increase of T_r (d₂) with the overlayer thickness d₂ followed by a decrease of T_r (d₂)at larger d₂. Such a nonmonotonic thickness dependence of T_r (d₂) results from the interplay of the …

Surface Impedance And Optimum Surface Resistance Of A Superconductor With An Imperfect Surface, Alex Gurevich, Takayuki Kubo

Physics Faculty Publications

We calculate a low-frequency surface impedance of a dirty, s-wave superconductor with an imperfect surface incorporating either a thin layer with a reduced pairing constant or a thin, proximity-coupled normal layer. Such structures model realistic surfaces of superconducting materials which can contain oxide layers, absorbed impurities, or nonstoichiometric composition. We solved the Usadel equations self-consistently and obtained spatial distributions of the order parameter and the quasiparticle density of states which then were used to calculate a low-frequency surface resistance R_s (T) and the magnetic penetration depth λ(T) as functions of temperature in the limit of local London electrodynamics. It …

Nonlinear Dynamics Of Vortices In Different Types Of Grain Boundaries, Ahmad K. Sheikhzada

Physics Theses & Dissertations

As a major component of linear particle accelerators, superconducting radio-frequency (SRF) resonator cavities are required to operate with lowest energy dissipation and highest accelerating gradient. SRF cavities are made of polycrystalline materials in which grain boundaries can limit maximum RF currents and produce additional power dissipation sources due to local penetration of Josephson vortices. The essential physics of vortex penetration and mechanisms of dissipation of vortices driven by strong RF currents along networks of grain boundaries and their contribution to the residual surface resistance have not been well understood. To evaluate how GBs can limit the performance of SRF materials, …

Femtosecond Laser Induced Structural Dynamics And Melting Of Cu (111) Single Crystal. An Ultrafast Time-Resolved X-Ray Diffraction Study, Runze Li, Omar A. Ashour, Jie Chen, H. E. Elsayed-Ali, Peter M. Rentzepis

Electrical & Computer Engineering Faculty Publications

Femtosecond, 8.04 keV x-ray pulses are used to probe the lattice dynamics of a 150 nm Cu (111) single crystal on a mica substrate irradiated with 400 nm, 100 fs laser pulses. For pump fluences below the damage and melting thresholds, we observed lattice contraction due to the formation of a blast force and coherent acoustic phonons with a period of ∼69 ps. At larger pump fluence, solid to liquid phase transition, annealing, and recrystallization were measured in real time by monitoring the intensity evolution of the probing fs x-ray rocking curves, which agreed well with theoretical simulation results. The …

Light Soaking Phenomena In Organic-Inorganic Mixed Halide Perovskite Single Crystals, Hye Ryung Byun, Dae Young Park, Hye Min Oh, Gon Namkoong, Mun Seok Jeong

Electrical & Computer Engineering Faculty Publications

Recently, organic inorganic mixed halide perovskite (MAPbX₃; MA = CH₃NH₃^+, X = Cl^-, Br^-, or I^-) single crystals with low defect densities have been highlighted as candidate materials for high-efficiency photovoltaics and optoelectronics. Here we report the optical and structural investigations of mixed halide perovskite (MAPbBr_3-xI_x) single crystals. Mixed halide perovskite single crystals showed strong light soaking phenomena with light illumination conditions that were correlated to the trapping and detrapping events from defect sites. By systematic investigation with optical analysis, we found that the …

Plasma Processes And Polymers Third Special Issue On Plasma And Cancer, Mounir Laroussi, Annemie Bogaerts, Nazir Barekzi

Electrical & Computer Engineering Faculty Publications

(First paragraph) This issue of Plasma Processes and Polymers is the third in a series on the applications of low temperature plasma (LTP) against cancer, or “plasma oncology.” The papers in this issue are inspired from the talks given at the third International Workshop on Plasma for Cancer Treatment (IWPCT) which took place on April 11–12, 2016 in Washington, DC, USA. IWPCT is an international workshop that was created in 2014 as a venue to share cutting edge plasma oncology research. The first IWPCT was held in Washington DC, under the co-chairmanship of Prof. Mounir Laroussi (Old Dominion University) and …

First Results Of Magnetic Field Penetration Measurements Of Multilayer Sis Structures, O. B. Malyshev, L. Gurran, R. Valizadeh, S. Pattalwar, N. Pattalwar, K. D. Dumbell, A. Gurevich

Physics Faculty Publications

The performance of superconducting RF cavities made of bulk Nb is limited by a breakdown field of B_p ≈200 mT, close to the superheating field for Nb. A potentially promising solution to enhance the breakdown field of the SRF cavities beyond the intrinsic limits of Nb is a multilayer coating suggested in [1]. In the simplest case, such a multilayer may be a superconductor-insulator-superconductor (S-I-S) coating, for example, bulk niobium (S) coated with a thin film of insulator (I) followed by a thin layer of another superconductor (S) which could be e.g. dirty niobium [2]. Here we report the …

Plasma Processes And Polymers Special Issue On: Plasma And Cancer, Mounir Laroussi, Michael Keidar

Electrical & Computer Engineering Faculty Publications

During the last two decades, research efforts on the application of low temperature plasmas in biology and medicine have positioned nonequilibrium lowtemperature plasmas as a technology that has the potential of revolutionizing healthcare.[1,2] Low temperature plasmas can be applied in direct contact with living tissues to inactivate bacteria,[3] to disinfect wounds and accelerate wound healing,[4] and to induce damage in some cancer cells.[5–11]

Investigation Of Nbnx Thin Films And Nanoparticles Grown By Pulsed Laser Deposition And Thermal Diffusion, Ashraf Hassan Farha

Electrical & Computer Engineering Theses & Dissertations

Niobium nitride films (NbNx) were grown on Nb and Si (100) substrates using pulsed laser deposition (PLD), laser heating, and thermal diffusion methods. Niobium nitride films were deposited on Nb substrates using PLD with a Q-switched Nd: YAG laser (λ = 1064 nm, 40 ns pulse width, and 10 Hz repetition rate) at different laser fluences, different nitrogen background pressures and deposition temperatures. The effect of changing PLD parameters for films done by PLD was studied. The seen observations establish guidelines for adjusting the laser parameters to achieve the desired morphology and phase of the grown NbNx films.

When the …

Excitation-Induced Ge Quantum Dot Growth On Si(100)-2x1 By Pulsed Laser Deposition, Ali Oguz Er

Physics Theses & Dissertations

Self-assembled Ge quantum dots (QD) are grown on Si(100)-(2×1) with laser excitation during growth processes by pulsed laser deposition (PLD). In situ reflection-high energy electron diffraction (RHEED) and post-deposition atomic force microscopy (AFM) are used to study the growth dynamics and morphology of the QDs. A Q-switched Nd:YAG laser (λ = 1064 nm, 40 ns pulse width, 5 J/cm² fluence, and 10 Hz repetition rate) were used to ablate germanium and irradiate the silicon substrate. Ge QD formation on Si(100)-(2×1) with different substrate temperatures and excitation laser energy densities was studied. The excitation laser reduces the epitaxial growth temperature …

Ultrafast High-Energy Electron Diffraction Study Of Photoexcited Bismuth Nanoclusters By Femtosecond Laser Pulses, Ahmed R. Esmail

Electrical & Computer Engineering Theses & Dissertations

The advancement in ultrafast electron crystallography (UEC) over the past few decades facilitated the study of structural dynamics in all phases of matter induced by femtosecond laser pulses. This technique became very powerful when the spatial resolution was combined with the temporal resolution, and succeeded in studying chemical reactions by ultrafast electron diffraction, bulk crystal phonons and melting by X-ray diffraction.

In this dissertation, I demonstrate the uniqueness of UEC and its potential in monitoring in real time the structural dynamics of bismuth (Bi) nanoclusters and islands induced by femtosecond laser pulses. Our approach to accomplish this task includes building …

Unitary-Quantum-Lattice Algorithm For Two-Dimensional Quantum Turbulence, Bo Zhang, George Vahala, Linda L. Vahala, Min Soe

Electrical & Computer Engineering Faculty Publications

Quantum vortex structures and energy cascades are examined for two-dimensional quantum turbulence (2D QT) at zero temperature. A special unitary evolution algorithm, the quantum lattice algorithm, is employed to simulate the Bose-Einstein condensate governed by the Gross-Pitaevskii (GP) equation. A parameter regime is uncovered in which, as in 3D QT, there is a short Poincare recurrence time. It is demonstrated that such short recurrence times are destroyed by stronger nonlinear interaction. The similar loss of Poincare recurrence is also seen in the 3D GP equation. Various initial conditions are considered in an attempt to discern if 2D QT exhibits inverse …

Comment On "On The Theory Of Nuclear Resonant Forward Scattering Of Synchrotron Radiation", Gilbert R. Hoy, Jos Odeurs

Physics Faculty Publications

Recently, in a paper by Kohn and Smirnov, a formula previously derived by Kagan et al. was developed to explain the forward scattering of gamma radiation by a nuclear-resonant sample excited by pulsed synchrotron radiation. Their derivation followed, directly, a procedure developed by Heitler, Harris, and Hoy. Previously, a completely different formula was developed by Hoy et al. to explain the same process. As a result, Kohn and Smirnov discuss the correctness and validity of the two models. In this Comment a detailed numerical comparison of the two theories has also been made. It is shown that their comparison is …

Reflection High-Energy Electron Diffraction Studies Of Indium Phosphide (100) And Growth On Indium And Indium Nitride On Silicon (100), Mohamed Abd-Elsattar Hafez

Electrical & Computer Engineering Theses & Dissertations

Study of the effects of atomic hydrogen exposure on structure and morphology of semiconductor surfaces is important for fundamental properties and applications. In this dissertation, the electron yield of a hydrogen-cleaned indium phosphide (InP) surface was measured and correlated to the development of the surface morphology, which was monitored by in situ reflection high-energy electron diffraction (RHEED). Atomic hydrogen treatment produced a clean, well-ordered, and (2x4)-reconstructed InP(100) surface. The quantum efficiency, after activation to negative electron affinity, and the secondary electron emission were shown to increase with hydrogen cleaning time. RHEED patterns of low-index InP(100) surface were modified by the …

Plasma Medicine, Mounir Laroussi, Alexander Fridman

Electrical & Computer Engineering Faculty Publications

Recent demonstrations of plasma technology in the treatment of living cells, tissues, and organs are creating a newfield at the intersection of plasma science and technology with biology and medicine - Plasma Medicine.

Investigation Of The Superconducting Properties Of Niobium Radio-Frequency Cavities, Gianluigi Ciovati

Physics Theses & Dissertations

Radio-frequency (rf) superconducting cavities are widely used to increase the energy of a charged particle beam in particle accelerators. The maximum gradients of cavities made of bulk niobium have constantly improved over the last ten years and they are approaching the theoretical limit of the material. Nevertheless, rf tests of niobium cavities are still showing some "anomalous" losses (so-called "Q-drop"), characterized by a marked increase of the surface resistance at high rf fields, in absence of field emission. A low temperature "in-situ" baking under ultra-high vacuum has been successfully applied by several laboratories to reduce those losses and …

Condensation On (002) Graphite Of Liquid Bismuth Far Below Its Bulk Melting Point, M. K. Zayed, H. E. Elsayed-Ali

Electrical & Computer Engineering Faculty Publications

Condensation of thermally evaporated Bi on (002) graphite, at temperatures of 300-523K, was studied using in situ reflection high-energy electron diffraction (RHEED) and room temperature ex situ atomic force microscopy (AFM). For deposition at temperatures below 415±5K, transmission RHEED patterns of Bi appeared at an average thickness of ∼0.5 monolayer (ML). AFM images showed that the film consisted of crystallites in the shape of triangular step pyramids with step heights corresponding to single and double Bi layers in the [111] direction. This morphology indicates crystallization from the vapor. For deposition at higher temperatures, diffuse RHEED patterns appeared independent of the …

Role Of Nanophase Oxides In Short-Term Atmospheric Corrosion Of Structural Steels, Rama Balasubramanian

Physics Theses & Dissertations

Systematic studies on the development of nanophase iron oxides in the corrosion products of carbon and weathering steel were performed to understand the role of nanophase oxides in short-term atmospheric corrosion. Similarities and/or differences between short-term and long-term atmospheric corrosion were established by studying carbon steel and weathering steel coupons exposed in mild marine environments for short-term and comparing it with previously established long-term data. Influence of substitutional elements, in particular chromium, in forming nanophase goethite was investigated. Crystallographic, magnetic and morphological properties of nanophase chromium substituted goethite have been characterized in order to understand the protective nature of chromium-substituted …

Dynamics Of Phase Transitions On Low-Index Metal Surfaces, Bo Lin

Electrical & Computer Engineering Theses & Dissertations

The surface superheating and phase transitions at the low-index surface of metal were investigated using conventional continuous and 100-ps time-resolved reflection high-energy electron diffraction. Three metal surfaces, In(111), Au(110) and Pb(111), have been investigated in this work. The high temperature behavior of the In(111) surface was investigated using reflection high-energy electron diffraction with 100-ps temporal resolution. The change of surface vacancy density on In(111) is observed from 300 K to near the bulk melting point. The vacancy-formation energy of In(111) surface is estimated from experimental results. The surface vacancy density is observed to increase with temperature; however, the average random …

Time-Resolved Structural Study Of Low-Index Surfaces Of Germanium Near Its Bulk Melting Temperature, Xinglin Zeng, H. E. Elsayed-Ali

Electrical & Computer Engineering Faculty Publications

The structure of the low-index surfaces of germanium near its bulk melting temperature is investigated using 100-ps time-resolved reflection high-energy electron diffraction. The surface is heated by 100-ps laser pulses while a synchronized electron beam probes the structure. Ge(111)was observed to remain in its incomplete melting structure up to at least T_m + 134 ± 40 K when heated by a 100-ps laser pulse. Both the Ge(100) and Ge(110) surfaces are observed to melt near the bulk melting temperature when heated with 100-ps laser pulses. Because of the low-diffraction intensity-to-background ratio at high temperatures and because of the temperature …

Time-Resolved Reflection High-Energy Electron Diffraction Study Of The Ge(111)-C(2×8)-(1×1) Phase Transition, Xinglin Zeng, Bo Lin, Ibrahim El-Kholy, Hani E. Elsayed-Ali

Electrical & Computer Engineering Faculty Publications

The dynamics of the Ge(111)-c(2×8)-(1×1) phase transition is investigated by 100-ps time-resolved reflection high-energy electron diffraction. A laser pulse heats the surface while a synchronized electron pulse is used to obtain the surface diffraction pattern. Slow heating shows that the adatoms in Ge(111)-c(2×8) start to disorder at ∼510 K and are converted to a disordered adatom arrangement at 573 K. For heating with 100-ps laser pulses, the Ge(111)-c(2×8) reconstructed adatom arrangement starts to disorder at 584±16K, well above the onset temperature of ∼510 K for the disordering of Ge(111)-c(2×8) observed for slow …

Temperature Dependence Of Step Density On Vicinal Pb(111), Z. H. Zhang, H. E. Elsayed-Ali

Electrical & Computer Engineering Faculty Publications

The temperature dependence of step density on the vicinal Pb(111) surface is investigated using reflection high-energy electron diffraction. When the temperature is increased from 323 to 590 K. the average terrace width and the average string length at the step edge decrease from 85±25 to 37±16 Å and from 220±33 to 25±8 Å, respectively. Thermal step collapse on the Pb(111) surface near its bulk melting temperature is not observed. Above 530±7 K, the change in the string length at the step edge with temperature becomes small, and the intensity of the (00) beam is significantly decreased. We conclude that partial …

Surface Morphology Of Laser-Superheated Pb(111) And Pb(100), Z. H. Zhang, Bo Lin, X. L. Zeng, H. E. Elsayed-Ali

Electrical & Computer Engineering Faculty Publications

The surface step density on the vicinal Pb(111) and the surface vacancy density on Pb(100) after laser superheating and melting are investigated using reflection high-energy electron diffraction. With ∼100-ps laser pulses, Pb(111) surface superheating does not significantly change the density of the steps and step-edge roughness. However, after laser surface melting, the average terrace width and the string length at the step edge become as large as those at room temperature. The average terrace width at 573 K changes from 38±15 to 64±19 Å after laser surface melting, while the average string length at the step edge changes from 90±14 …

Femtosecond Photoemission Study Of Ultrafast Electron Dynamics In Single-Crystal Au(111) Films, J. Cao, Y. Gao, H. E. Elsayed-Ali, R. J. D. Miller, D. A. Mantell

Electrical & Computer Engineering Faculty Publications

The energy-dependent relaxation of photoexcited electrons has been measured by time-resolved two-photon photoemission spectroscopy on single-crystal Au(111) films with thickness ranging from 150 to 3000 Å. It is found that the energy-dependent relaxation does not show any significant thickness dependence, which indicates that electron transport is a much slower dynamical process in the near-surface region than expected from bulk properties. Furthermore, lifetimes of the photoexcited electrons can be fitted well by the Fermi-liquid theory with a scaling factor plus an effective upper lifetime. This observation enables separation of electron-electron scattering, and to a lesser extent electron-phonon scattering, processes from electron-transport …

Reflection High-Energy Electron-Diffraction Study Of Melting And Solidification Of Pb On Graphite, Z. H. Zhang, P. Kulatunga, H. E. Elsayed-Ali

Electrical & Computer Engineering Faculty Publications

The melting and solidification of Pb thin films on pyrolytic graphite are investigated in situ by reflection high-energy electron diffraction. Thin films with thicknesses of 4-150 monolayers are investigated. The surface morphology of the thin films were studied by scanning electron microscopy. Superheating of the Pb thin films by 4±2 to 12±2 K is observed from diffraction intensity measurements. Upon cooling the substrate, the Pb on graphite is seen to supercool by ∼69±4 K.