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Iowa State University

Ceramic engineering

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Full-Text Articles in Physics

Preparation And Characterization Of B2s3-Based Chalcogenide Glasses , Jaephil Cho Jan 1995

Preparation And Characterization Of B2s3-Based Chalcogenide Glasses , Jaephil Cho

Retrospective Theses and Dissertations

The discovery of the fast ion conducting B[subscript]2S[subscript]3-based glasses has been one of the most significant development in the field of solid electrolytes. Considerable experimental studies have been done to maximize conductivities and chemical stabilities of these glass systems. Recently, the study of the structure and properties of these glasses compared to their oxide analog has become important;The IR spectra of M[subscript]2S + B[subscript]2S[subscript]3 (M = Li, K, Rb and Cs) and MS + B[subscript]2S[subscript]3 (M = Sr and Ba) thioborate glasses have shown the monotonic increase in tetrahedral ...


Impedance Spectroscopy And Nmr Studies Of Fast Ion Conducting Chalcogenide Glasses , Hitendra Kumar Patel Jan 1993

Impedance Spectroscopy And Nmr Studies Of Fast Ion Conducting Chalcogenide Glasses , Hitendra Kumar Patel

Retrospective Theses and Dissertations

Two fully automated, temperature controlled, impedance spectroscopy workstations have been developed for this project. Impedance spectroscopy studies of glasses have been performed over the wide frequency (1 Hz-1 GHz) and wide temperature (100-500 K) range;This study yields the first-ever full compositional (three decades) range examination of the Na[subscript]2S + B[subscript]2S[subscript]3 and K[subscript]2S + B[subscript]2S[subscript]3 systems. The activation energy is modeled using a modified Anderson-Stuart model that predicts well the results for the low alkali glasses. a.c. conductivity is examined through the electrical modulus formalism and the Kohlrausch-Williams-Watts decay ...