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## Full-Text Articles in Physics

A Molecular Debye-Hückel Theory Of Solvation In Polar Fluids: An Extension Of The Born Model, Tiejun Xiao, Xueyu Song

#### A Molecular Debye-Hückel Theory Of Solvation In Polar Fluids: An Extension Of The Born Model, Tiejun Xiao, Xueyu Song

*Ames Laboratory Accepted Manuscripts*

A dielectric response theory of solvation beyond the conventional Born model for polar fluids is presented. The dielectric response of a polar fluid is described by a Born response mode and a linear combination of Debye-Hückel-like response modes that capture the nonlocal response of polar fluids. The Born mode is characterized by a bulk dielectric constant, while a Debye-Hückel mode is characterized by its corresponding Debye screening length. Both the bulk dielectric constant and the Debye screening lengths are determined from the bulk dielectric function of the polar fluid. The linear combination coefficients of the response modes are evaluated in ...

A Molecular Debye-Hückel Theory And Its Applications To Electrolyte Solutions: The Size Asymmetric Case, Tiejen Xiao, Xueyu Song

#### A Molecular Debye-Hückel Theory And Its Applications To Electrolyte Solutions: The Size Asymmetric Case, Tiejen Xiao, Xueyu Song

*Chemistry Publications*

A molecular Debye-Hückel theory for electrolyte solutions with size asymmetry is developed, where the dielectric response of an electrolyte solution is described by a linear combination of Debye-Hückel-like response modes. As the size asymmetry of an electrolyte solution leads to a charge imbalanced border zone around a solute, the dielectric response to the solute is characterized by two types of charge sources, namely, a bare solute charge and a charge distribution due to size asymmetry. These two kinds of charge sources are screened by the solvent differently, our theory presents a method to calculate the mean electric potential as well ...