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Strain-Induced Disorder, Phase Transformations, And Transformation-Induced Plasticity In Hexagonal Boron Nitride Under Compression And Shear In A Rotational Diamond Anvil Cell: In Situ X-Ray Diffraction Study And Modeling, Valery I. Levitas, Yanzhang Ma, Javad Hashemi, Mark Holtz, Necip Guven
Strain-Induced Disorder, Phase Transformations, And Transformation-Induced Plasticity In Hexagonal Boron Nitride Under Compression And Shear In A Rotational Diamond Anvil Cell: In Situ X-Ray Diffraction Study And Modeling, Valery I. Levitas, Yanzhang Ma, Javad Hashemi, Mark Holtz, Necip Guven
Valery I. Levitas
Plastic shear significantly reduces the phase transformation (PT) pressure when compared to hydrostatic conditions. Here, a paradoxical result was obtained: PT of graphitelike hexagonal boron nitride (hBN) to superhard wurtzitic boron nitride under pressure and shear started at about the same pressure(∼10GPa) as under hydrostatic conditions. In situ x-ray diffraction measurement and modeling of the turbostratic stacking fault concentration (degree of disorder) and PT in hBN were performed. Under hydrostaticpressure, changes in the disorder were negligible. Under a complex compression and shear loading program, a strain-induced disorder was observed and quantitatively characterized. It is found that the strain-induced disorder suppresses …