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Full-Text Articles in Physics
Low‐Temperature Phase Diagram Of Ybbipt, R. Movshovich, A. Lacerda, Paul C. Canfield, J. D. Thompson, Z. Fisk
Low‐Temperature Phase Diagram Of Ybbipt, R. Movshovich, A. Lacerda, Paul C. Canfield, J. D. Thompson, Z. Fisk
Paul C. Canfield
Resistivity measurements are reported on the cubic heavy‐fermion compound YbBiPt at ambient and hydrostatic pressures to ≊19 kbar and in magnetic fields to 1 T. The phase transition at T c =0.4 K is identified by a sharp rise in resistivity. That feature is used to build low‐temperature H‐T and P‐Tphase diagrams. The phase boundary in the H‐T plane follows the weak‐coupling BCS expression remarkably well from T c to T c /4, while small hydrostatic pressure of ≊1 kbar suppresses the low‐temperature phase entirely. These effects of hydrostatic pressure and magnetic field on the phase transition are consistent with …
Compositional Short-Range Ordering In Metallic Alloys: Band-Filling, Charge-Transfer, And Size Effects From A First-Principles All-Electron Landau-Type Theory, J. B. Staunton, Duane D. Johnson, F. J. Pinski
Compositional Short-Range Ordering In Metallic Alloys: Band-Filling, Charge-Transfer, And Size Effects From A First-Principles All-Electron Landau-Type Theory, J. B. Staunton, Duane D. Johnson, F. J. Pinski
Duane D. Johnson
Using a mean-field statistical description, we derive a general formalism to investigate atomic short-range order in alloys based on a density-functional description of the finite-temperature, grand potential of the random alloy. This ‘‘first-principles,’’ Landau-type approach attempts to treat several contributions (electronic structure, Fermi surface, electrostatics, magnetism, etc.) to the electronic energy on an equal footing. An important ingredient for the statistical averaging is the replacement of the molecular mean fields (Weiss fields) with Onsager cavity fields, which forces the diagonal part of the fluctuation-dissipation theorem to be obeyed. To show its general applicability and usefulness, we apply the theory to …
First-Principles All-Electron Theory Of Atomic Short-Range Ordering In Metallic Alloys: D022- Versus L12-Like Correlations, Duane D. Johnson, J. B. Staunton, F. J. Pinski
First-Principles All-Electron Theory Of Atomic Short-Range Ordering In Metallic Alloys: D022- Versus L12-Like Correlations, Duane D. Johnson, J. B. Staunton, F. J. Pinski
Duane D. Johnson
We use a ‘‘first-principles’’ concentration-wave approach based on a finite-temperature, electronic density-functional, mean-field, grand potential of the random alloy to investigate the high-temperature atomic short-range order (ASRO) in Ni75V25 and Pd75V25 solid solutions. Experimentally, these similar alloys both develop D022-type long-range order at low temperatures but different ASRO at high temperatures. Our calculations describe the measured ASRO well. We compare these results with those found for a hypothetical Co75Ti25 solid solution. Since this alloy orders directly from the melt into the L12 phase, it should exhibit strong L12-like ASRO, as we find in our calculations. We analyze the features in …
Surface-Induced Ordering In Asymmetric Block Copolymers, Y. Liu, W. Zhao, X. Zheng, Alexander H. King, A. Sing, M. H. Rafailovich, J. Sokolov, K. H. Dai, E. J. Kramer, S. A. Schwarz, O. Gebizlioglu, S. K. Sinha
Surface-Induced Ordering In Asymmetric Block Copolymers, Y. Liu, W. Zhao, X. Zheng, Alexander H. King, A. Sing, M. H. Rafailovich, J. Sokolov, K. H. Dai, E. J. Kramer, S. A. Schwarz, O. Gebizlioglu, S. K. Sinha
Alexander H. King
The surface-induced ordering in thin films of asymmetric deuterated polystyrene (dPS)- poly(viny1pyridine) (PVP) diblock and triblock copolymers of comparable polymerization index and PVP volume fraction - 0.25) was studied using transmission electron microscopy, atomic force microscopy, secondary ion massspectrometry, and neutron reflectivity. The morphology of both di- and triblock copolymer films was found to be cylindrical except for the layer adjacent to the silicon oxide surface, which due to the strong interaction of silica with PVP, was lamellar. The spacing between adjacent cylindrical layers was found to be consistent with mean field theory predictions. In the triblock copolymer films the …
Magnetic And Crystallographic Order In Α‐Manganese, A. C. Lawson, Allen C. Larson, M. C. Aronson, S. Johnson, Z. Fisk, Paul C. Canfield, J. D. Thompson, R. B. Von Dreele
Magnetic And Crystallographic Order In Α‐Manganese, A. C. Lawson, Allen C. Larson, M. C. Aronson, S. Johnson, Z. Fisk, Paul C. Canfield, J. D. Thompson, R. B. Von Dreele
Paul C. Canfield
We have made time‐of‐flight neutron diffractionmeasurements on α‐manganese metal. Powder diffraction measurements were made at 14 temperatures between 15 and 305 K, and single crystalmeasurements were made at 15 and 300 K. We found that the crystal structure of α‐Mn is tetragonal below its Néel point of 100 K, with crystal symmetryI4̄2m and magnetic (Shubnikov) symmetry P I 4̄21 c. In agreement with the earlier results of Yamada et al., there are six independent magnetic atoms, and we found that their moments are weakly temperature dependent. The onset of magnetic order causes slight changes in the atomic positions and in …