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Full-Text Articles in Physics

Kinetics Of The Crystal-Melt Phase Transformation In Semicrystalline Polymers, Kiran Subramaniam Iyer Jul 2020

Kinetics Of The Crystal-Melt Phase Transformation In Semicrystalline Polymers, Kiran Subramaniam Iyer

Doctoral Dissertations

The assembly of long-chain polymers into an ordered state is a process that has puzzled polymer scientists for several decades. A process that is largely controlled by the strength of intermolecular attractions in small molecular systems, this crystallization in the case of polymers is controlled by a competition between the aforementioned force of attraction between monomers and the formidable conformational entropy of polymer chains. Any factor that affects this conformational entropy, whether that is an equilibrium thermodynamic factor or a kinetic factor, has the ability to control polymer crystallization. In this thesis, we focus on understanding the underlying kinetic processes …


Poincare Recurrence And Spectral Cascades In Three-Dimensional Quantum Turbulence, George Vahala, Jeffrey Yepez, Linda L. Vahala, Min Soe, Bo Zhang, Sean Ziegeler Jan 2011

Poincare Recurrence And Spectral Cascades In Three-Dimensional Quantum Turbulence, George Vahala, Jeffrey Yepez, Linda L. Vahala, Min Soe, Bo Zhang, Sean Ziegeler

Electrical & Computer Engineering Faculty Publications

The time evolution of the ground state wave function of a zero-temperature Bose-Einstein condensate (BEC) gas is well described by the Hamiltonian Gross-Pitaevskii (GP) equation. Using a set of appropriately interleaved unitary collision-stream operators, a qubit lattice gas algorithm is devised, which on taking moments, recovers the Gross-Pitaevskii (GP) equation under diffusion ordering (time scales as length2). Unexpectedly, there is a class of initial states whose Poincaré recurrence time is extremely short and which, as the grid resolution is increased, scales with diffusion ordering (and not as length3). The spectral results of J. Yepez et al. …