Open Access. Powered by Scholars. Published by Universities.®

Physics Commons

Open Access. Powered by Scholars. Published by Universities.®

Physical Chemistry

2014

Acetylene; Linestrength; Collisional broadening; Infrared spectroscopy; Quantum cascade lasers

Articles 1 - 1 of 1

Full-Text Articles in Physics

Measurements Of Linestrengths, N2-, Ar-, He- And Self-Broadening Coefficients Of Acetylene In The Ν4+Ν5 Combination Band Using A Cw Quantum Cascade Laser, Muhammad Bilal Sajid, Et-Touhami Es-Sebbar, Aamir Farooq Jun 2014

Measurements Of Linestrengths, N2-, Ar-, He- And Self-Broadening Coefficients Of Acetylene In The Ν4+Ν5 Combination Band Using A Cw Quantum Cascade Laser, Muhammad Bilal Sajid, Et-Touhami Es-Sebbar, Aamir Farooq

Dr. Et-touhami Es-sebbar

Linestrengths, N2-, Ar-, He- and self-broadening coefficients of acetylene have been measured at 296 K in the P branch of the ν4+ν5 combination band for 25 rotational transitions. The effect of gas temperature is studied over 296–683 K for five transitions to allow the determination of the temperature dependent exponent n for N2- and Ar-broadening coefficients. These measurements were performed using a continuous-wave quantum cascade laser (cw-QCL) operating over 1253–1310 cm−1. Spectroscopic parameters were obtained by fitting absorption spectra using Voigt, Galatry and Rautian profiles. Linestrength and broadening results are compared with previous studies available in literature for the ν4+ν5 …