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Physical Chemistry

2012

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Dynamical Signature Of The Mott-Hubbard Transition In Ni(S,Se)(2), Yevgeniya Zastavker, Anke Husmann, Deborah Jin, Thomas Rosenbaum, X Yao, J Honig Jun 2012

Dynamical Signature Of The Mott-Hubbard Transition In Ni(S,Se)(2), Yevgeniya Zastavker, Anke Husmann, Deborah Jin, Thomas Rosenbaum, X Yao, J Honig

Yevgeniya V. Zastavker

The transition metal chalcogenide Ni(S,Se)2 is one of the few highly correlated, Mott-Hubbard systems without a strong first-order structural distortion that normally cuts off the critical behavior at the metal-insulator transition. The zero-temperature (T) transition was tuned with pressure, and significant deviations were found near the quantum critical point from the usual T1/2 behavior of the conductivity characteristic of electron-electron interactions in the presence of disorder. The transport data for pressure and temperature below 1 kelvin could be collapsed onto a universal scaling curve.