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Physical Chemistry

University of Colorado, Boulder

Aromatic radicals

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Photoelectron Spectroscopy Of Organic Aromatic Anions, Daniel John Nelson Jan 2017

Photoelectron Spectroscopy Of Organic Aromatic Anions, Daniel John Nelson

Chemistry & Biochemistry Graduate Theses & Dissertations (1986-2018)

Nelson, Daniel John (Ph.D. Chemical Physics)

Photoelectron Spectroscopy of Organic Aromatic Anions

Thesis directed by Professor W. Carl Lineberger

This dissertation reports and interprets the results of experiments in which photoelectron spectroscopy was performed on a variety of aromatic anions. In addition to these photoelectron studies, the results and conclusions of an experiment in which HCl is scattered off atomically flat Au (111) surfaces are also presented.

Photoelectron spectroscopy of the isomers of methylphenoxide reveals that these molecules display minimal vibrational excitation upon photodetachment, accessing the electronic ground and first excited state of the corresponding radicals. The photoelectron spectra ...