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Full-Text Articles in Physics

Smart Grid Control: Demand Side Management In Household Refrigerators As A Tool For Load Shifting, Anogh Utkalika Zaman, James Doyle May 2022

Smart Grid Control: Demand Side Management In Household Refrigerators As A Tool For Load Shifting, Anogh Utkalika Zaman, James Doyle

Macalester Journal of Physics and Astronomy

With improved supply of renewable sources of energy the focus has shifted away from simply producing clean energy to efficient consumption of energy. Until cheaper methods of energy storage are developed, Demand Side Management (DSM) is the best option for maximising energy efficiency. This paper proposes a method of turning regular refrigerators into smart demand response fridges. First, we develop an algorithm that accounts for small fluctuations in price and switches the device for optimal performance and lowered running cost. Then, we use longer price fluctuations to predict suitable times for pre-cooling and investigate the reduction in price as a …


Sustainable Energy Imaginaries: Utilizing Mie Optics To Reengineer Photobioreactors And Reimagine The Socio-Spatial Conditions Of Autonomous Energy Production, Spencer Morgan Checkoway Jan 2022

Sustainable Energy Imaginaries: Utilizing Mie Optics To Reengineer Photobioreactors And Reimagine The Socio-Spatial Conditions Of Autonomous Energy Production, Spencer Morgan Checkoway

Senior Projects Spring 2022

In order to build a more sustainable future, society must transition toward carbon negative energy production and infrastructure. Algae photobioreactors have proven to be an efficient producer of lipid rich oil which can be synthesized into carbon neutral biodiesel. However, the neutrality of such a technology rests in its ability to yield adequate algal biomass through photosynthesis. In order to reach maximum quantum efficiency of algal cells, solar flux must be transformed so that photon absorption can occur without oversaturating the constituent matter. This project looks at the scattering effects of iridocyte-like structures and their potential to create cost effective …


Investigation Of Environmental-Friendly, Membraneless Hydrogen Peroxide Fuel Cells, Bao Nguyen Aug 2021

Investigation Of Environmental-Friendly, Membraneless Hydrogen Peroxide Fuel Cells, Bao Nguyen

Dissertations and Theses

Human-induced climate change is one of the biggest threats to humanity in the 21st century. This is caused by the increase in greenhouse gas concentrations in the Earth's atmosphere. The burning of fossil fuels is the primary cause of climate change. This problem can be addressed by replacing fossil fuels with fuel sources that have clean by-products and are cost-effective. For the last few decades, hydrogen (H2) has been extensively studied as an alternative to carbon-based fossil fuels. Currently, H2 still has many shortcomings for commercial applications. The photocatalytic production of H2 still suffers from …


A Study Of The Frustrated Honeycomb Battery Material Na2ni2teo6, Nathan Christopher Episcopo May 2021

A Study Of The Frustrated Honeycomb Battery Material Na2ni2teo6, Nathan Christopher Episcopo

Open Access Theses & Dissertations

The P2-type layered hexagonal compound Na2Ni2TeO6 with Ni2+ on a honeycomb lattice was synthesized by the standard solid-state route. Structural characterization chemical phase purity was confirmed by Rietveld refinement of laboratory and synchrotron data. The crystal structure refines well in the P63/mcm space group. Single crystal growth trials using the self-flux-melt method were conducted with limited success. The magnetic transition temperature pertaining to Ni2+ lattice was confirmed by analysis of specific heat capacity to be . The magnetic susceptibility remains largely unchanged in magnetic field of and external pressure of . There is an almost linear response in isothermal magnetization …


Lecture 12: Recent Advances In Time Integration Methods And How They Can Enable Exascale Simulations, Carol S. Woodward Apr 2021

Lecture 12: Recent Advances In Time Integration Methods And How They Can Enable Exascale Simulations, Carol S. Woodward

Mathematical Sciences Spring Lecture Series

To prepare for exascale systems, scientific simulations are growing in physical realism and thus complexity. This increase often results in additional and changing time scales. Time integration methods are critical to efficient solution of these multiphysics systems. Yet, many large-scale applications have not fully embraced modern time integration methods nor efficient software implementations. Hence, achieving temporal accuracy with new and complex simulations has proved challenging. We will overview recent advances in time integration methods, including additive IMEX methods, multirate methods, and parallel-in-time approaches, expected to help realize the potential of exascale systems on multiphysics simulations. Efficient execution of these methods …


Optimisation Of Retrofit Wall Insulation: An Irish Case Study, Rakshit D. Muddu, D M. Gowda, Anthony James Robinson, Aimee Byrne Jan 2021

Optimisation Of Retrofit Wall Insulation: An Irish Case Study, Rakshit D. Muddu, D M. Gowda, Anthony James Robinson, Aimee Byrne

Articles

Ireland has one of the highest rates of emissions per capita in the world and its residential sector is responsible for approximately 10% of total national CO2 emissions. Therefore, reducing the CO2 emissions in this sector will play a decisive role in achieving EU targets of reducing emissions by 40% by 2030. To better inform decisions regarding retrofit of the existing building stock, this study proposes Optimum Insulation Thicknesses (OIT) for typical walls in 25 regions in Ireland. The calculation of OIT includes annual heat energy expenditure, CO2 emissions, and material payback period. The approach taken is based on Heating …


Dual-Axis Solar Tracker, Bryan Kennedy Jan 2020

Dual-Axis Solar Tracker, Bryan Kennedy

All Undergraduate Projects

Renewable energies, and fuels that are not fossil fuel-based, are one of the prolific topics of debate in modern society. With climate change now becoming a primary focus for scientists and innovators of today, one of the areas for the largest amount of potential and growth is that of the capturing and utilization of Solar Energy. This method involves using a mechanical system to track the progression of the sun as it traverses the sky throughout the day. A dual-axis solar tracker such as the one designed and built for this project, can follow the sun both azimuthally and in …


Developing A Uas-Deployable Methane Sensor Using Low-Cost Modular Open-Source Components, Gavin Demali Jan 2020

Developing A Uas-Deployable Methane Sensor Using Low-Cost Modular Open-Source Components, Gavin Demali

Williams Honors College, Honors Research Projects

This project aimed to develop a methane sensor for deployment on an unmanned aerial system (UAS), or drone, platform. This design is centered around low cost, commercially available modular hardware components and open source software libraries. Once successfully developed, this system was deployed at the Bath Nature Preserve in Bath Township, Summit County Ohio in order to detect any potential on site fugitive methane emissions in the vicinity of the oil and gas infrastructure present. The deliverables of this project (i.e. the data collected at BNP) will be given to the land managers there to better inform future management and …


An In-Situ Study Of The Aqueous Speciation Of Uranium (Vi) Under Hydrothermal Conditions, Diwash Dhakal May 2019

An In-Situ Study Of The Aqueous Speciation Of Uranium (Vi) Under Hydrothermal Conditions, Diwash Dhakal

MSU Graduate Theses

Rigorous study of the speciation distribution of uranyl-chloride bearing solutions under hydrothermal conditions is important to understand the transport mechanism of uranium underground, which is of uttermost interest to parties studying the geological uranium deposits and those studying the possibilities of geological repositories for spent nuclear waste. I report an in-situ Raman spectroscopic study of the speciation distribution of aqueous uranyl-chloride complexes upto 500°C conducted using a HDAC as the high PT spectroscopic cell. The samples studied contained the species UO22+, UO2Cl+, UO2Cl20 and UO2Cl3- …


A Study Of Solvent Effects On The Ground And Excited States Of Endohedral Tri-Scandium Nitride C80 Fullerene Coupled With Zinc Phthalocyanine And Metal-Free Phthalocyanine Using Dft-Pcm Method, Timilsina Prasad Timlsina Jan 2019

A Study Of Solvent Effects On The Ground And Excited States Of Endohedral Tri-Scandium Nitride C80 Fullerene Coupled With Zinc Phthalocyanine And Metal-Free Phthalocyanine Using Dft-Pcm Method, Timilsina Prasad Timlsina

Open Access Theses & Dissertations

The photovoltaic active materials composed of endohedral metafullerene and phthalocyanine derivatives are known as excellent electron donor-acceptor pairs. The tri-metallic nitride endohedral C80 fullerene exhibits high absorption coefficients in the visible region of the spectrum and has similar electron-accepting abilities as that of C60 fullerene, which can allow for higher efficiencies in OPV devices. In this study, we examine the effect of solvent on the charge transfer excitation energies of Sc3N@C80-ZnPc and Sc3N@C80-H2Pc donor-acceptor molecular complexes. Three different solvents with different polarity - water, toluene, and acetone are used. The solvent is modeled as a polarizable continuum as implemented in …


Call For Abstracts - Resrb 2019, July 8-9, Wrocław, Poland, Wojciech M. Budzianowski Dec 2018

Call For Abstracts - Resrb 2019, July 8-9, Wrocław, Poland, Wojciech M. Budzianowski

Wojciech Budzianowski

No abstract provided.


Nmr Characterizations Of Candidate Battery Electrolytes, Stephen A. Munoz Sep 2018

Nmr Characterizations Of Candidate Battery Electrolytes, Stephen A. Munoz

Dissertations, Theses, and Capstone Projects

Enormous strides have been made in next-generation power sources to build a more sustainable society. Energy storage has become a limiting factor in our progress, and there are huge environmental and financial incentives to find the next step forward in battery technology. This work discusses NMR methods for characterizing materials for use in battery application, with a special focus on relaxometry and diffusometry. Examples are provided of various recent investigations involving novel candidate electrolyte materials with different collaborators. Works discussed in this thesis include: the characterization of a new disruptive solid polymer electrolyte technology, investigations of the dynamics of super …


The Effect Of Processing Conditions On The Energetic Diagram Of Cdte Thin Films Studied By Photoluminescence, Shamara P. Collins Jul 2018

The Effect Of Processing Conditions On The Energetic Diagram Of Cdte Thin Films Studied By Photoluminescence, Shamara P. Collins

USF Tampa Graduate Theses and Dissertations

The photovoltaic properties of CdTe-based thin films depend on recombination levels formed in the CdTe layer and at the heterojunction. The localized states are resultant of structural defects (metal sublattice, chalcogen sublattice, interstitial), controlled doping, deposition process, and/or post-deposition annealing. The photoluminescence study of CdTe thin films, from both the bulk and heterojunction, can reveal radiative states due to different defects or impurities. Identification of defects allows for potential explanation of their roles and influence on solar cell performance. A thorough understanding of the material properties responsible for solar cell performance is critical in further advancing the efficiency of devices. …


Radical Social Ecology As Deep Pragmatism: A Call To The Abolition Of Systemic Dissonance And The Minimization Of Entropic Chaos, Arielle Brender May 2018

Radical Social Ecology As Deep Pragmatism: A Call To The Abolition Of Systemic Dissonance And The Minimization Of Entropic Chaos, Arielle Brender

Student Theses 2015-Present

This paper aims to shed light on the dissonance caused by the superimposition of Dominant Human Systems on Natural Systems. I highlight the synthetic nature of Dominant Human Systems as egoic and linguistic phenomenon manufactured by a mere portion of the human population, which renders them inherently oppressive unto peoples and landscapes whose wisdom were barred from the design process. In pursuing a radical pragmatic approach to mending the simultaneous oppression and destruction of the human being and the earth, I highlight the necessity of minimizing entropic chaos caused by excess energy expenditure, an essential feature of systems that aim …


Detection And Characterization Of The Tin Dihydride (Snh2 And Snd2) Molecule In The Gas Phase, Tony C. Smith, Dennis J. Clouthier Jan 2018

Detection And Characterization Of The Tin Dihydride (Snh2 And Snd2) Molecule In The Gas Phase, Tony C. Smith, Dennis J. Clouthier

Chemistry Faculty Publications

The SnH2 and SnD2 molecules have been detected for the first time in the gas phase by laser-induced fluorescence (LIF) and emission spectroscopic techniques through the Ã1B1–X̃1A1 electronic transition. These reactive species were prepared in a pulsed electric discharge jet using (CH3)4Sn or SnH4/SnD4 precursors diluted in high pressure argon. Transitions to the electronic excited state of the jet-cooled molecules were probed with LIF, and the ground state energy levels were measured from single rovibronic level emission spectra. The LIF spectrum of SnD2 …


Automated Cfd Optimization To Maximize Wind Farms Performance And Land Use, Rafael Valotta Rodrigues Jan 2018

Automated Cfd Optimization To Maximize Wind Farms Performance And Land Use, Rafael Valotta Rodrigues

Electronic Theses and Dissertations

In this research, a computational system was designed to analyze and optimize the layout of wind farms under variable operational conditions. At first, a wind turbine computational fluid dynamic (CFD) model was developed covering the near wake. The near wake flow field was validated against near wake velocity data from the MEXICO experiment. The CFD simulation demonstrated that the tip speed ratio and the pitch angle greatly influence the near wake behavior, affecting the velocity deficit and the turbulence intensity profile in this region. The CFD model was extended to cover the far wake, aiming to become a computational tool …


Functionalized Nanoporous Carbon Scaffolds For Hydrogen Storage Applications, Christopher L. Carr Jan 2018

Functionalized Nanoporous Carbon Scaffolds For Hydrogen Storage Applications, Christopher L. Carr

Doctoral Dissertations

"Recent efforts have demonstrated confinement in porous scaffolds at the nanoscale can alter the hydrogen sorption properties of metal hydrides, though not to an extent feasible for use in onboard hydrogen storage applications, proposing the need for a method allowing further modifications. The work presented here explores how the functionalization of nanoporous carbon scaffold surfaces with heteroatoms can modify the hydrogen sorption properties of confined metal hydrides in relation to non-functionalized scaffolds (FS). Investigations of nanoconfined LiBH4 and NaAlH4 indicate functionalizing the carbon scaffold surface with nitrogen can shift the activation energy of hydrogen desorption in excess of …


Synergistic Interactions Of H2 And N2 With Molten Gallium In The Presence Of Plasma, Maria L. Carreon, Daniel F. Jaramillo-Cabanzo, Indira Chaudhuri, Madhu Menon, Mahendra K. Sunkara Dec 2017

Synergistic Interactions Of H2 And N2 With Molten Gallium In The Presence Of Plasma, Maria L. Carreon, Daniel F. Jaramillo-Cabanzo, Indira Chaudhuri, Madhu Menon, Mahendra K. Sunkara

Physics and Astronomy Faculty Publications

The present study examines the interaction of hydrogen and nitrogen plasmas with gallium in an effort to gain insights into the mechanisms behind the synergetic effect of plasma and a catalytic metal. Absorption/desorption experiments were performed, accompanied by theoretical-computational calculations. Experiments were carried out in a plasma-enhanced, Ga-packed, batch reactor and entailed monitoring the change in pressure at different temperatures. The results indicated a rapid adsorption/dissolution of the gas into the molten metal when gallium was exposed to plasma, even at a low temperature of 100 °C. The experimental observations, when hydrogen was used, indicate that gallium acts as a …


One-Step Laser-Induced Hydrogen Generation From Coal Powders In Water, Dovletgeldi Seyitliyev Jul 2017

One-Step Laser-Induced Hydrogen Generation From Coal Powders In Water, Dovletgeldi Seyitliyev

Masters Theses & Specialist Projects

This study presents a simple way of obtaining hydrogen gas (H2) from various ranks of coal, coke, and graphite using nanosecond laser pulses. Powder samples of coal and graphite with and without water were irradiated with 1064 nm and 532 nm pulses from an Nd: YAG laser for 45 minutes under air and argon atmospheres. It was observed that 532 nm laser pulses were more effective than 1064 nm pulses in gas generation and both were nonlinearly correlated with respect to the laser energy density. Mainly hydrogen (H2) and carbon monoxide (CO) were observed. The H2 to CO ratio shows …


Strengthening The Development Of The Short-Rotation Plantations Bioenergy Sector: Policy Insights From Six European Countries, Carlos Parra-Lopez, Martin Holley, Kevin Lindegaard, Samir Sayadi, Gonzalo Esteban-Lopez, Victor Duran-Zuazo, Christoph Knauer, Hans-Georg Von Engelbrechten, Ralf Winterber, Annika Henriksson, Annette Lamley, Anders Nylander, Susanne Paulrud, Pauline Leonard, Patrick Daly, Lukasz Drzewaszewski, Wojciech Rzewuski Jan 2017

Strengthening The Development Of The Short-Rotation Plantations Bioenergy Sector: Policy Insights From Six European Countries, Carlos Parra-Lopez, Martin Holley, Kevin Lindegaard, Samir Sayadi, Gonzalo Esteban-Lopez, Victor Duran-Zuazo, Christoph Knauer, Hans-Georg Von Engelbrechten, Ralf Winterber, Annika Henriksson, Annette Lamley, Anders Nylander, Susanne Paulrud, Pauline Leonard, Patrick Daly, Lukasz Drzewaszewski, Wojciech Rzewuski

Articles

This paper, based on a participatory methodological framework involving expert stakeholders and researchers from six European countries (Germany, Ireland, Poland, Spain, Sweden and UK), analyses the priority issues for the development of short-rotation plantations (SRP), and proposes a series of policy strategies to strengthen this development. The results indicate that there is a lack of awareness of the multifaceted benefits of SRP at the level of farmers, policy makers and public authorities. More research is required to put a value on the multifunctionality of SRP and justify its public support. Small-scale projects using established technologies are also required with energy …


C.V. - Wojciech Budzianowski, Wojciech M. Budzianowski Jan 2017

C.V. - Wojciech Budzianowski, Wojciech M. Budzianowski

Wojciech Budzianowski

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Renewable Energy And Sustainable Development (Resd) Group, Wojciech M. Budzianowski Jan 2017

Renewable Energy And Sustainable Development (Resd) Group, Wojciech M. Budzianowski

Wojciech Budzianowski

No abstract provided.


Plasmonic Luminescent Down Shifting Layers For The Enhancement Of Cdte Mini-Modules Performance, Hind Ahmed, S.J. Mccormack, John Doran Jan 2017

Plasmonic Luminescent Down Shifting Layers For The Enhancement Of Cdte Mini-Modules Performance, Hind Ahmed, S.J. Mccormack, John Doran

Articles

In this investigation, plasmonic coupling between luminescent species (lumogen yellow, and silver nanoparticles (Ag NPs) has been exploited to produce significant enhancement in absorption and fluorescence emission of lumogen yellow dye luminescent downshifting (LDS) layers. The optimum dye concentration in a poly(methyl,methacrylate) polymer LDS layer of ∼100μm thickness was established. Subsequently, plasmonic coupling with Ag NPs was introduced and optimum concentration has been determined for the composite plasmonic Luminescent Down-Shifting (pLDS) layers. The optimum plasmonic coupling has been observed to produce fluorescence emission enhancement of up to 81% for the dye-pLDS layers. The pLDS layers were deposited on top of …


Targeting Residential Energy Reduction For City Utilities Using Historical Electrical Utility Data And Readily Available Building Data, Kevin P. Hallinan, J. Kelly Kissock, Robert J. Brecha, Austin Mitchell Sep 2016

Targeting Residential Energy Reduction For City Utilities Using Historical Electrical Utility Data And Readily Available Building Data, Kevin P. Hallinan, J. Kelly Kissock, Robert J. Brecha, Austin Mitchell

J. Kissock

Energy use data for the eight-year period 2003–2010 was analyzed for over 1200 single family residences in Village of Yellow Springs, Ohio. Electricity, natural gas, residential building, and weather databases are merged to permit determination of the energy intensity of each home in the village. The energy use intensity for each home is disaggregated into weather independent and weather dependent electric and natural gas use. This use is compared to typical baseline, cooling, and heating energy use for the region. From this comparison, priority homes are identified for energy reduction investment. Collective potential low cost energy reduction is estimated for …


Prioritizing Investment In Residential Energy Efficiency And Renewable Energy: A Case Study For The U.S. Midwest, Robert J. Brecha, Austin Mitchell, Kevin P. Hallinan, J. Kelly Kissock Sep 2016

Prioritizing Investment In Residential Energy Efficiency And Renewable Energy: A Case Study For The U.S. Midwest, Robert J. Brecha, Austin Mitchell, Kevin P. Hallinan, J. Kelly Kissock

J. Kissock

Residential building energy use is an important contributor to greenhouse gas emissions and in the United States represents about 20% of total energy consumption. A number of previous macro-scale studies of residential energy consumption and energy-efficiency improvements are mainly concerned with national or international aggregate potential savings. In this paper we look into the details of how a collection of specific homes in one region might reduce energy consumption and carbon emissions, with particular attention given to some practical limits to what can be achieved by upgrading the existing residential building stock. Using a simple model of residential, single-family home …


Targeting Residential Energy Reduction For City Utilities Using Historical Electrical Utility Data And Readily Available Building Data, Kevin P. Hallinan, J. Kelly Kissock, Robert J. Brecha, Austin Mitchell Jun 2016

Targeting Residential Energy Reduction For City Utilities Using Historical Electrical Utility Data And Readily Available Building Data, Kevin P. Hallinan, J. Kelly Kissock, Robert J. Brecha, Austin Mitchell

Kevin Hallinan

Energy use data for the eight-year period 2003–2010 was analyzed for over 1200 single family residences in Village of Yellow Springs, Ohio. Electricity, natural gas, residential building, and weather databases are merged to permit determination of the energy intensity of each home in the village. The energy use intensity for each home is disaggregated into weather independent and weather dependent electric and natural gas use. This use is compared to typical baseline, cooling, and heating energy use for the region. From this comparison, priority homes are identified for energy reduction investment. Collective potential low cost energy reduction is estimated for …


Prioritizing Investment In Residential Energy Efficiency And Renewable Energy: A Case Study For The U.S. Midwest, Robert J. Brecha, Austin Mitchell, Kevin P. Hallinan, J. Kelly Kissock Jun 2016

Prioritizing Investment In Residential Energy Efficiency And Renewable Energy: A Case Study For The U.S. Midwest, Robert J. Brecha, Austin Mitchell, Kevin P. Hallinan, J. Kelly Kissock

Kevin Hallinan

Residential building energy use is an important contributor to greenhouse gas emissions and in the United States represents about 20% of total energy consumption. A number of previous macro-scale studies of residential energy consumption and energy-efficiency improvements are mainly concerned with national or international aggregate potential savings. In this paper we look into the details of how a collection of specific homes in one region might reduce energy consumption and carbon emissions, with particular attention given to some practical limits to what can be achieved by upgrading the existing residential building stock. Using a simple model of residential, single-family home …


Cost-Availability Curves For Hierarchical Implementation Of Residential Energy-Efficiency Measures, Roman Villoria-Siegert, Philip Brodrick, Kevin P. Hallinan, Robert J. Brecha Jun 2016

Cost-Availability Curves For Hierarchical Implementation Of Residential Energy-Efficiency Measures, Roman Villoria-Siegert, Philip Brodrick, Kevin P. Hallinan, Robert J. Brecha

Kevin Hallinan

Historical residential electricity data and natural gas consumption data were collected for, respectively, 1,200 and 178 residences in a small town in the USA. These data were merged with local building and weather databases, and energy consumption models were developed for each residence, revealing substantial variation in heating and cooling intensity. After estimating approximate physical building characteristics, energy profiles for each residence were calculated, and savings from adoption of the most cost-effective energy-efficiency measures for each residence were estimated. Effectively, we wish to leverage commonly available data sets to infer characteristics of building envelopes and equipment, without the need for …


Emissions Scenarios In The Face Of Fossil-Fuel Peaking, Robert Brecha Feb 2016

Emissions Scenarios In The Face Of Fossil-Fuel Peaking, Robert Brecha

Robert J. Brecha

Emissions scenarios used by the Intergovernmental Panel on Climate Change (IPCC) are based on detailed energy system models in which demographics, technology and economics are used to generate projections of future world energy consumption, and therefore, of greenhouse gas emissions. We propose in this paper that it is useful to look at a qualitative model of the energy system, backed by data from short- and medium-term trends, to gain a sense of carbon emission bounds. Here we look at what may be considered a lower bound for 21st century emissions given two assumptions: first, that extractable fossil-fuel resources follow the …


Cost Optimization With Solar And Conventional Energy Production, Energy Storage, And Real Time Pricing, Ata Raziei, Kevin Hallinan, Robert Brecha Feb 2016

Cost Optimization With Solar And Conventional Energy Production, Energy Storage, And Real Time Pricing, Ata Raziei, Kevin Hallinan, Robert Brecha

Robert J. Brecha

Research is presented that investigates the potential for solar power generation with battery energy storage for reducing the effective cost of energy delivered to residential customers if real time pricing is present. A linear optimization approach is developed based upon a two-step process. In step one, given a specified solar array area and battery capacity, the optimal means to meet loads based upon grid power, solar power, and/or battery power is determined. This analysis considers an expected lifespan of the solar panel. With these results established, in the next step, the capital costs for the solar arrays and batteries are …