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Full-Text Articles in Physics
Domain Wall Saddle Point Morphology In Ferroelectric Triglycine Sulfate, C. J. Mccluskey, A. Kumar, Alexei Gruverman, I. Luk’Yanchuk, J. M. Gregg
Domain Wall Saddle Point Morphology In Ferroelectric Triglycine Sulfate, C. J. Mccluskey, A. Kumar, Alexei Gruverman, I. Luk’Yanchuk, J. M. Gregg
Alexei Gruverman Publications
Ferroelectric domain walls, across which there is a divergence in polarization, usually have enhanced electrical conductivity relative to bulk. However, in lead germanate, head-to-head and tail-to-tail walls are electrically insulating. Recent studies have shown that this is because, when oppositely oriented domains meet, polar divergence is obviated by a combination of domain bifurcation and suspected local dipolar rotation. To explore the uniqueness, or otherwise, of this microstructure, we have used tomographic piezoresponse force microscopy to map three-dimensional domain morphologies in another uniaxial ferroelectric system: triglycine sulfate. This mapping reveals an abundance of domain wall saddle points, which are characteristic of …
Ultra-High Carrier Mobilities In Ferroelectric Domain Wall Corbino Cones At Room Temperature, Conor J. Mccluskey, Matthew G. Colbear, James P.V. Mcconville, Shane J. Mccartan, Jesi R. Maguire, Michele Conroy, Kalani Moore, Alan Harvey, Felix Trier, Ursel Bangert, Alexei Gruverman, Manuel Bibes, Amit Kumar, Raymong G.P. Mcquaid, J. Marty Gregg
Ultra-High Carrier Mobilities In Ferroelectric Domain Wall Corbino Cones At Room Temperature, Conor J. Mccluskey, Matthew G. Colbear, James P.V. Mcconville, Shane J. Mccartan, Jesi R. Maguire, Michele Conroy, Kalani Moore, Alan Harvey, Felix Trier, Ursel Bangert, Alexei Gruverman, Manuel Bibes, Amit Kumar, Raymong G.P. Mcquaid, J. Marty Gregg
Alexei Gruverman Publications
Recently, electrically conducting heterointerfaces between dissimilar band-insulators (such as lanthanum aluminate and strontium titanate) have attracted considerable research interest. Charge transport has been thoroughly explored and fundamental aspects of conduction firmly established. Perhaps surprisingly, similar insights into conceptually much simpler conducting homointerfaces, such as the domain walls that separate regions of different orientations of electrical polarisation within the same ferroelectric band-insulator, are not nearly so well-developed. Addressing this disparity, we herein report magnetoresistance in approximately conical 180° charged domain walls, which occur in partially switched ferroelectric thin film single crystal lithium niobate. This system is ideal for such measurements: firstly, …
Ferroelectric Domain Wall Memristor, James P. V. Mcconville, Haidong Lu, Bo Wang, Yueze Tan, Charlotte Cochard, Michele Conroy, Kalani Moore, Alan Harvey, Ursel Bangert, Long-Qing Chen, Alexei Gruverman, J. M. Gregg
Ferroelectric Domain Wall Memristor, James P. V. Mcconville, Haidong Lu, Bo Wang, Yueze Tan, Charlotte Cochard, Michele Conroy, Kalani Moore, Alan Harvey, Ursel Bangert, Long-Qing Chen, Alexei Gruverman, J. M. Gregg
Alexei Gruverman Publications
A domain wall-enabled memristor is created, in thin film lithium niobate capacitors, which shows up to twelve orders of magnitude variation in resistance. Such dramatic changes are caused by the injection of strongly inclined conducting ferroelectric domain walls, which provide conduits for current flow between electrodes. Varying the magnitude of the applied electric-field pulse, used to induce switching, alters the extent to which polarization reversal occurs; this systematically changes the density of the injected conducting domain walls in the ferroelectric layer and hence the resistivity of the capacitor structure as a whole. Hundreds of distinct conductance states can be produced, …
Ch3Nh3Pbi3 Perovskites: Ferroelasticity Revealed, Evgheni Strelcov, Qingfeng Dong, Tao Li, Jungseok Chae, Yuchuan Shao, Yehao Deng, Alexei Gruverman, Jinsong Huang, Andrea Centrone
Ch3Nh3Pbi3 Perovskites: Ferroelasticity Revealed, Evgheni Strelcov, Qingfeng Dong, Tao Li, Jungseok Chae, Yuchuan Shao, Yehao Deng, Alexei Gruverman, Jinsong Huang, Andrea Centrone
Alexei Gruverman Publications
Ferroelectricity has been proposed as a plausible mechanism to explain the high photovoltaic conversion efficiency in organic-inorganic perovskites; however, convincing experimental evidence in support of this hypothesis is still missing. Identifying and distinguishing ferroelectricity from other properties, such as piezoelectricity, ferroelasticity, etc., is typically nontrivial because these phenomena can coexist in many materials. In this work, a combination of microscopic and nanoscale techniques provides solid evidence for the existence of ferroelastic domains in both CH3NH3PbI3 polycrystalline films and single crystals in the pristine state and under applied stress. Experiments show that the configuration of CH …
Anomalous Photovoltaic Effect In Organic-Inorganic Hybrid Perovskite Solar Cells, Yongbo Yuan, Tao Li, Qi Wang, Jie Xing, Alexei Gruverman, Jinsong Huang
Anomalous Photovoltaic Effect In Organic-Inorganic Hybrid Perovskite Solar Cells, Yongbo Yuan, Tao Li, Qi Wang, Jie Xing, Alexei Gruverman, Jinsong Huang
Alexei Gruverman Publications
Organic-inorganic hybrid perovskites (OIHPs) have been demonstrated to be highly successful photovoltaic materials yielding very-high-efficiency solar cells. We report the room temperature observation of an anomalous photovoltaic (APV) effect in lateral structure OIHP devices manifested by the device’s open-circuit voltage (VOC) that is much larger than the bandgap of OIHPs. The persistent VOC is proportional to the electrode spacing, resembling that of ferroelectric photovoltaic devices. However, the APV effect in OIHP devices is not caused by ferroelectricity. The APV effect can be explained by the formation of tunneling junctions randomly dispersed in the polycrystalline films, which allows …
Theoretical Approach To Electroresistance In Ferroelectric Tunnel Junctions, Sou-Chi Chang, Azad Naeemi, Dmitri E. Nikonov, Alexei Gruverman
Theoretical Approach To Electroresistance In Ferroelectric Tunnel Junctions, Sou-Chi Chang, Azad Naeemi, Dmitri E. Nikonov, Alexei Gruverman
Alexei Gruverman Publications
In this paper, a theoretical approach comprising the nonequilibrium Green’s function method for electronic transport and the Landau-Khalatnikov equation for electric polarization dynamics is presented to describe polarization-dependent tunneling electroresistance (TER) in ferroelectric tunnel junctions. Using appropriate contact, interface, and ferroelectric parameters, the measured current-voltage characteristic curves in both inorganic (Co/BaTiO3/La0.67Sr0.33MnO3) and organic (Au/PVDF/W) ferroelectric tunnel junctions can be well described by the proposed approach. Furthermore, under this theoretical framework, the controversy of opposite TER signs observed experimentally by different groups in Co/BaTiO3/La0.67Sr0.33MnO3 systems is …
Domain Wall Conductivity In Semiconducting Hexagonal Ferroelectric Tbmno3 Thin Films, D. J. Kim, J. G. Connell, S. S. A. Seo, Alexei Gruverman
Domain Wall Conductivity In Semiconducting Hexagonal Ferroelectric Tbmno3 Thin Films, D. J. Kim, J. G. Connell, S. S. A. Seo, Alexei Gruverman
Alexei Gruverman Publications
Although enhanced conductivity of ferroelectric domain boundaries has been found in BiFeO3 and Pb(Zr,Ti)O3 films as well as hexagonal rare-earth manganite single crystals, the mechanism of the domain wall conductivity is still under debate. Using conductive atomic force microscopy, we observe enhanced conductance at the electrically-neutral domain walls in semiconducting hexagonal ferroelectric TbMnO3 thin films where the structure and polarization direction are strongly constrained along the c-axis. This result indicates that domain wall conductivity in ferroelectric rare-earth manganites is not limited to charged domain walls. We show that the observed conductivity in the TbMnO3 films is …
Scaling Of Electroresistance Effect In Fully Integrated Ferroelectric Tunnel Junctions, Mohammad Abuwasib, Haidong Lu, Tao Li, Pratyush Buragohain, Hyungwoo Lee, Chang-Beom Eom, Alexei Gruverman, Uttam Singisetti
Scaling Of Electroresistance Effect In Fully Integrated Ferroelectric Tunnel Junctions, Mohammad Abuwasib, Haidong Lu, Tao Li, Pratyush Buragohain, Hyungwoo Lee, Chang-Beom Eom, Alexei Gruverman, Uttam Singisetti
Alexei Gruverman Publications
Systematic investigation of the scalability for tunneling electroresistance (TER) of integrated Co/BaTiO3/SrRuO3 ferroelectric tunnel junctions (FTJs) has been performed from micron to deep submicron dimensions. Pulsed measurements of the transient currents confirm the ferroelectric switching behavior of the FTJs, while the hysteresis loops measured by means of piezoresponse force microscopy verify the scalability of these structures. Fully integrated functional FTJ devices with the size of 300×300 nm2 exhibiting a tunneling electroresistance (TER) effect of the order of 2.7×104% have been fabricated and tested. Measured current density of 75 A/cm2 for the ON state …
Electrostatic Charge On Flying Hummingbirds And Its Potential Role In Pollination, Marc Badger, Victor Manuel Ortega-Jimenez, Lisa Von Ribenau, Ashley Smiley, Robert Dudley, Alexei Gruverman , Editor
Electrostatic Charge On Flying Hummingbirds And Its Potential Role In Pollination, Marc Badger, Victor Manuel Ortega-Jimenez, Lisa Von Ribenau, Ashley Smiley, Robert Dudley, Alexei Gruverman , Editor
Alexei Gruverman Publications
Electrostatic phenomena are known to enhance both wind- and insect-mediated pollination, but have not yet been described for nectar-feeding vertebrates. Here we demonstrate that wild Anna's Hummingbirds (Calypte anna) can carry positive charges up to 800 pC while in flight (mean ± s.d.: 66 ± 129 pC). Triboelectric charging obtained by rubbing an isolated hummingbird wing against various plant structures generated charges up to 700 pC. A metal hummingbird model charged to 400 pC induced bending of floral stamens in four plants (Nicotiana, Hemerocallis, Penstemon, and Aloe spp.), and also attracted falling Lycopodium spores at distances of < 2 mm. Electrostatic forces may therefore influence pollen transfer onto nectar-feeding birds.
Mesoscale Flux-Closure Domain Formation In Single-Crystal Batio3, R. G.P. Mcquaid, L. J. Mcgilly, Pankaj Sharma, Alexei Gruverman, J. M. Gregg
Mesoscale Flux-Closure Domain Formation In Single-Crystal Batio3, R. G.P. Mcquaid, L. J. Mcgilly, Pankaj Sharma, Alexei Gruverman, J. M. Gregg
Alexei Gruverman Publications
Over 60 years ago, Charles Kittel predicted that quadrant domains should spontaneously form in small ferromagnetic platelets. He expected that the direction of magnetization within each quadrant should lie parallel to the platelet surface, minimizing demagnetizing fields, and that magnetic moments should be configured into an overall closed loop, or flux-closure arrangement. Although now a ubiquitous observation in ferromagnets, obvious flux-closure patterns have been somewhat elusive in ferroelectric materials. This is despite the analogous behaviour between these two ferroic subgroups and the recent prediction of dipole closure states by atomistic simulations research. Here we show Piezoresponse Force Microscopy images of …