Physics Commons^™

Absolute Nitrogen Atom Density Measurements By Two-Photon Laser-Induced Fluorescence Spectroscopy In Atmospheric Pressure Dielectric Barrier Discharges Of Pure Nitrogen, Et-Touhami Es-Sebbar, Christian Sarra-Bournet, Nicolas Naudé, Françoise Massines, Nicolas Gherardi

Dr. Et-touhami Es-sebbar

In this paper, two-photon absorption laser induced fluorescence spectroscopy is used to follow the nitrogen atom density in flowing dielectric barrier discharges fed with pure nitrogen and operating at atmospheric pressure. Two different dielectric barrier discharge regimes are investigated: the Townsend regime, which is homogeneous although operating at atmospheric pressure, and the more common filamentary regime. In both regimes, densities as high as 3x1014 /cm3 are detected. However, the N atoms kinetic formation depends on the discharge regime. The saturation level is reached more rapidly with a filamentary discharge. For a given discharge regime, the N atom density depends strongly …

Contributions To The Development Of The S.E.T.U.P. (Experimental And Theoretical Simulations Useful For Planetology) Project, E. Arzoumanian, C. Romanzin, M-C. Gazeau, Et. Es-Sebbar, A. Jolly, S. Perrier, Y. Benilan

Dr. Et-touhami Es-sebbar

No abstract provided.

Multiwavelength Studies For Titan's Atmospheric Composition Analysis, Y. Benilan, Et. Es-Sebbar, N. Fray, M-C. Gazeau, A. Jolly, M. Schwell, J. Guillemin

Dr. Et-touhami Es-sebbar

Titan's atmosphere mainly made of nitrogen and methane is rich in organic molecules. Hydrocarbons are formed from the photolytic dissociation of CH4 and nitriles are created by dissociation of N2 followed by reactions with hydrocarbons. In order to understand the physicochemical mechanisms responsible for the evolution of Titan's atmosphere, photochemical models are built. The latter need constrains for vertical profiles of organic compounds from the high thermosphere down to the low stratosphere as well as photodissociation rates. Those profiles over the entire atmosphere can be retrieved from Cassini observations, in particular by limb sounding, coupling infrared and ultraviolet spectroscopy. However, …

Vuv Photostability Of Prebiotic Species, M. Schwell, Y. Bénilan, M.-C. Gazeau, N. Fray, A. Jolly, Et. Es-Sebbar, N. Champion, S. Leach, H. W Jochims, H. Baumgärtel, E. Rühl

Dr. Et-touhami Es-sebbar

No abstract provided.

S.E.T.U.P. Experimental And Theoretical Simulations Useful For Planetology- Related Studies In The Frame Of A Program Of Titan’S Atmosphere Laboratory Simulations, M.-C. Gazeau, Et. Es-Sebbar, E. Arzoumanian, C. Romanzin, A. Jolly, S. Perrier, Y. Bénilan

Dr. Et-touhami Es-sebbar

No abstract provided.

Characterization Of An N2 Flowing Microwave Post-Discharge By Oes Spectroscopy And Determination Of Absolute Ground-State Nitrogen Atom Densities By Talif, Et. Es-Sebbar, Y. Benilan, A. Jolly, M-C. Gazeau

Dr. Et-touhami Es-sebbar

A flowing microwave post-discharge source sustained at 2.45 GHz in pure nitrogen has been investigated by optical emission spectroscopy (OES) and two-photon absorption laser-induced fluorescence (TALIF) spectroscopy. Variations of the optical emission along the post-discharge (near, pink and late afterglow) have been studied and the gas temperature has been determined. TALIF spectroscopy has been used in the late afterglow to determine the absolute ground-state nitrogen atomic densities using krypton as a reference gas. Measurements show that the microwave flowing post-discharge is an efficient source of N (4S) atoms in late afterglow. In our experimental conditions, the maximum N (4S) density …

Effect Of Salts On The Electrospinning Of Poly(Vinyl Alcohol), Jonathan J. Stanger, Nick Tucker, Mark P. Staiger, Kerry Kirwan, Stuart Coles, Daniel Jacobs, Nigel Larsen

Jonathan J Stanger

Fibres with a diameter in the nanometer range were electrospun from aqueous poly(vinyl alcohol) (PVOH). In order to improve the mass deposition rate and decrease the final fibre diameter salts (NaCl, LiCl, LiBr and LiF) were added to the solution. The aim was to increase the charge density and hence increase the electrostatic forces on the fluid. It was found that with increasing salt concentration the charge density did increase. However the mass deposition rate was found to decrease and the final fibre diameter was found to increase. The decrease in mass deposition rate is explained by considering the concept …

Effect Of Charge Density On The Taylor Cone In Electrospinning, Jonathan J. Stanger, Nick Tucker, Kerry Kirwan, Stuart Coles, Daniel Jacobs, Mark P. Staiger

Jonathan J Stanger

A detailed understanding of charge density and its origins during the electrospinning process is desirable for developing new electrospinnable polymer-solvent systems and ensuring mathematical models of the process are accurate. In this work, two different approaches were taken to alter the charge density in order to measure its effect on the Taylor cone, mass deposition rate and initial jet diameter. It was found that an increase in charge density results in a decrease in the mass deposition rate and initial jet diameter. A theory is proposed for this behaviour in that an increase in charge density leads to the tip …

The Effect Of Electrode Configuration And Substrate Material On The Mass Deposition Rate Of Electrospinning, Jonathan J. Stanger, Nick Tucker, Andrew Wallace, Nigel Larsen, Mark P. Staiger, Roger Reeves

Jonathan J Stanger

Poly(vinyl alcohol) (PVOH) was electrospun using different methods to charge the polymer solution. A positive high voltage relative to the collecting electrode significantly increased the fibre deposition rate. Electron microscopy showed that approximately half of the increase in fibre mass was due to thicker fibres being deposited. The current flowing from the grounded electrode was measured to determine the charge carried on the PVOH jet. This showed that for a positive voltage charging condition there is a much larger current and hence more charge carriers generated in the PVOH solution. As a result, more mass is ejected from the Taylor …

Gathering Leadership Momentum Across Great Distances: Creating An Online Community Of Practice, Erin L. Davis, Danielle Theiss-White

Erin Davis

At the 2007 Mountain Plains Library Association Leadership (MPLA) Institute, held in New Mexico, USA, eight academic librarians formed an online multi-state, multigenerational community of practice. MPLA is a twelve-state library association within the United States. Using Google Groups™, the members formed an online environment called the MPLA Community of Practice for continuing development of the leadership skills presented at the Institute. These early-career librarians represent diverse educational backgrounds and work in libraries serving varied populations with differing disciplinary emphases.

The group meets monthly with each member preparing and facilitating online discussions, complete with personal assessments, topical readings, and questions. …