Earth Sciences Commons^™

The Distribution And Comparative Biogeochemistry Of Silver With Other Selected Trace Metals In Coastal Waters Near Massachusetts, Usa, Christian F. Krahforst

Graduate Doctoral Dissertations

Water samples and hydrologic data were collected during 1994-1996 in New England coastal waters near Massachusetts, USA to examine the distribution of silver and other trace metals (Cu, Pb, Cd, Zn, and Fe) in the coastal systems of Massachusetts and Cape Cod Bays. These investigations were designed to test the hypothesis that silver could serve as a tracer of dispersion of municipal wastewater in Boston Harbor into Massachusetts and Cape Cod Bays and estimate the relative contribution of wastewater discharge to the overall silver budget of the Massachusetts Bays system. Silver concentrations in both particulate and filtered (<0.4 µm) fractions averaged 103 and 117 pmol kg-1 for Boston Harbor, 34 and 10 pmol kg-1 in western Massachusetts Bay, and 11 and 7 pmol kg-1 in the central portion of Massachusetts Bay, respectively. Average Ag concentrations in southern Gulf of Maine coastal waters were 10 and 2 pmol kg-1 for filtered and particulate fractions, respectively. While nearly half of the silver existed in particulate form in Boston Harbor, nearly 80% of the silver in Massachusetts and Cape Cod Bays occurred in the filterable fraction. Coastal water surveys revealed non-conservative Ag behavior and probably the result of incomplete mixing of three or more water masses with unique Ag signatures (e.g., Merrimack River, Boston Harbor, surface and intermediate Gulf of Maine waters). Quasi-steady state mass balance approaches estimate most of the silver entering into the Massachusetts Bays system during the study period was the result of municipal wastewater discharge to Boston Harbor (84-93%).

Multivariate analyses …