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Full-Text Articles in Earth Sciences
Nutrient Dynamics Of Freshwater Estuarine Sediments Disturbed By Dredging, Ryan Allan John Roekle
Nutrient Dynamics Of Freshwater Estuarine Sediments Disturbed By Dredging, Ryan Allan John Roekle
Theses and Dissertations
This study examined the nutrient environment of sediments in the Milwaukee River estuary and the dynamics of those nutrients during simulated disturbance experiments within the context of large-scale dredging remediation. Surface sediments were collected from throughout the Milwaukee estuary (including river, harbor, and nearshore stations) by PONAR, centrifuged to separate porewater (interstitial water) from solid material, and filtered to further isolate and stabilize dissolved material. Porewaters were analyzed for dissolved nutrients including ammoniacal nitrogen (AN), nitrate, nitrite, and soluble reactive phosphorus (SRP). Surface sediment porewaters within the estuary were often highly enriched in AN and SRP, which were often 10-2000x …
Identifying Biogeochemical Factors Responsible For The Cyclical Precipitation Of Sphalerite And Galena In Low Temperature Mississippi Valley Type Ore Deposits, Daniel John Makowsky
Identifying Biogeochemical Factors Responsible For The Cyclical Precipitation Of Sphalerite And Galena In Low Temperature Mississippi Valley Type Ore Deposits, Daniel John Makowsky
Theses and Dissertations
Mississippi Valley Type (MVT) lead and zinc deposits provide a significant source of sedimentary galena and sphalerite. However, geochemical characteristics and genesis including the source and production of hydrogen sulfide required for galena and sphalerite ore formation and the reasoning for quick, episodic mineralization is not fully understood. By simulating regional MVT brines, the input and effect of biological by-products during the development of these ores as well as the cause of cyclicity within MVT deposits have been observed. Experiments using compositions from MVT fluid inclusions were conducted over two-week periods. Variables during the experiments included temperature, CO2, hydrogen sulfide …
Enabling High Quality Oxygen Measurements During Robotic Based Studies Of Ocean Ecological And Biogeochemical Processes, Brianna A. Alanis
Enabling High Quality Oxygen Measurements During Robotic Based Studies Of Ocean Ecological And Biogeochemical Processes, Brianna A. Alanis
Theses and Dissertations
Dissolved oxygen is an essential parameter necessary for understanding marine ecological and biogeochemical processes. New robotic vehicles and autonomous platforms are being applied to an even wider range of ecological and biogeochemical studies. Thus, arises the opportunity for matching the best possible oxygen sensing techniques and methods to these new platforms. In so doing, we can enable both more targeted and higher resolution oxygen measurements than previously possible and potentially use oxygen measurements for a wider range of applications, including in situ incubation experiments and primary productivity measurements. This thesis tested three different oxygen sensors in a trade study for …
Carbon Dynamics In Tropical Lake Malawi, Maxon Ngochera
Carbon Dynamics In Tropical Lake Malawi, Maxon Ngochera
Theses and Dissertations
Large lakes of the world play a vital role in the global carbon cycle as they act both as conduits and sinks of terrestrially and atmospherically derived carbon. Lake Malawi, lying at the extreme southernmost end of the East African Rift Valley is one of the largest, deepest and most ancient of the African Great Lakes. In this study, the spatial and seasonal variation of direct measurements of air and water pCO2 were taken for a period of one annual cycle using a vessel of opportunity along the north-south axis of Lake Malawi. These data, together with limnological and meteorological …
Stoichiometric Controls On Denitrification In High Nitrate Watersheds, Brian Grebliunas
Stoichiometric Controls On Denitrification In High Nitrate Watersheds, Brian Grebliunas
Theses and Dissertations
Watershed biogeochemistry throughout Midwestern agroecosystems have been altered through hydrologic manipulation and over-application of nitrogenous fertilizers. As a result, nitrate (NO3-N) export from subsurface drainage has negative impacts on local and downstream ecosystem health. Wetland installation has proven to be a viable option for targeted management where a large proportion of NO3-N is removed through the bacterially mediated process denitrification. For denitrification to maintain high rates under prolonged NO3-N saturation, a stable supply of labile dissolved organic carbon (DOC) is required. The focus of this dissertation was to study how the stoichiometry of agricultural wetlands limits denitrification within a controlled …