Earth Sciences Commons^™

Investigation Of Gas Dynamics In Water And Oil-Based Muds Using Das, Dts, And Dss Measurements, Temitayo S. Adeyemi

LSU Master's Theses

Reliable prediction of gas migration velocity, void fraction, and length of gas-affected region in water and oil-based muds is essential for effective planning, control, and optimization of drilling operations. However, there is a gap in our understanding of gas behavior and dynamics in water and oil-based muds. This is a consequence of the use of experimental systems that are not representative of field-scale conditions. This study seeks to bridge the gap via the well-scale deployment of distributed fiber-optic sensors for real-time monitoring of gas behavior and dynamics in water and oil-based mud. The aforementioned parameters were estimated in real-time using …

Investigating Gulf Coast Aquifer System: Stratigraphy Reconstruction, Inverse Modeling, And Groundwater Stress Assessment, Shuo Yang

LSU Doctoral Dissertations

The Mississippi Embayment aquifer system (MEAS) and the Coastal Lowlands aquifer system (CLAS) provide substantial groundwater resources for human activities in the U.S. Gulf Coastal Plain. However, the overexploitation has led to groundwater depletion in the MEAS and the CLAS, threatening sustainable groundwater use. Such concern highlights the crucial need for an advanced understanding of stratigraphy and groundwater in these aquifer systems, which is essential for effective regional groundwater management. This dissertation presents a comprehensive investigation of MEAS and CLAS in the Louisiana and southwestern Mississippi region, encompassing three fundamental dimensions: stratigraphy reconstruction, groundwater modeling, and groundwater stress assessments. A …

Sedimentary Processes And Instability On The Mississippi River Delta Front Near The Wreck Of The Ss Virginia, Nathan Figueredo

LSU Doctoral Dissertations

Multi-cores and piston cores were collected seaward of the Mississippi River Delta’s Southwest Pass at ~80 m water depth in 2017 to better understand sedimentary characteristics and processes on the Mississippi River Delta Front (MRDF) in the vicinity of the SS Virginia shipwreck, and to support marine archeological research. Core analyses were performed to inform our understanding of the dynamics of sediment motion in the study area through radionuclide activity (²¹⁰Pb and ¹³⁷Cs), volume frequency of grain size, bulk density, and fabric (X-Radiography). Sediment accumulation rates (SAR), calculated from multi-core ²¹⁰Pb activity are 0.22 - 0.29 …

Quantifying Mud Settling Velocity As A Function Of Turbulence And Salinity In A Deltaic Estuary, Michael W. Mcdonell

LSU Master's Theses

Mud settling velocity is controlled by flocculation, which in turn strongly depends on turbulence and on the chemistry and biology of the water-sediment mixture. As a result, mud settling velocity can be poorly constrained in coastal areas and vary in space and time by orders of magnitude. Here we quantified mud settling velocity in Barataria Basin, a deltaic estuary in Louisiana (USA), using three independent methods: eddy covariance (one station for 200 days), floc cameras (4 stations at one time), and Rouse profile inversion (14 stations, replicated 10-30 times each). Eddy covariance indicates that settling velocity increases with turbulence, at …

Snow Distribution And Influence In Taylor Valley, Antarctica, Using Remote Sensing, Katherine Mcnulty, Peter Doran, Mark Salvatore, Suniti Karunatillake

LSU Master's Theses

The McMurdo Dry Valleys is the largest ice-free area in Antarctica, but seasonal snow covers the valley floors sporadically throughout the year. In this study, a model to estimate areal snow coverage from satellite imagery was created. An area-volume model was created to estimate the amount of snow water equivalent (SWE) from the snow area extracted from the imagery. Snow cover influences the total albedo, the hydrologic budget, and the soil moisture and soil temperature in Taylor Valley (TV). Quantifying snow precipitation in TV is challenging because snow redistributes with winds, sublimates, or melts within a short period. Previous estimates …

Visual Analytics And Modeling Of Materials Property Data, Diwas Bhattarai

LSU Doctoral Dissertations

Due to significant advancements in experimental and computational techniques, materials data are abundant. To facilitate data-driven research, it calls for a system for managing and sharing data and supporting a set of tools for effective data analysis and modeling. Generally, a given material property M can be considered as a multivariate data problem. The dimensions of M are the values of the property itself, the conditions (pressure P, temperature T, and multi-component composition X) that control the concerned property, and relevant metadata I (source, date).

Here we present a comprehensive database considering both experimental and computational sources …

Archean Metamorphosed Ultramafic Rocks And Chromitites From The Beartooth Mountains, Montana, Usa: Insights Into Mantle Geochemistry And Tectonics, Rachel M. Gnieski

LSU Master's Theses

Metamorphosed ultramafic rocks and associated chromitite pods in the eastern Beartooth Mountains, Montana (USA) provide a window into the tectonic evolution of the Archean northern Wyoming Province. Meta-ultramafic rocks occur with a variety of metasupracrustal rocks as xenoliths in an extensive 2.8 Ga suite of TTG (meta)plutonic rocks. The origin of the ultramafic rocks is obscured by an upper amphibolite-to-greenschist facies overprint. Major element analyses (XRF, wt. %) of meta-ultramafic host rocks show SiO₂ from 40.53-50.37, MgO from 15.33-45.25, TiO₂ from 0.07-0.62, Al₂O₃ from 1.25-10.62, and Fe₂O₃(t) from 8.06-14.54. Total alkali …

Snapshots Of Coastal Ecology During Glacial And Deglacial Intervals: A Multiproxy Assessment Of Northern Gulf Of Mexico Sediment Cores, Kendall Emilie Brome

LSU Master's Theses

Terrestrial ecosystems along exposed continental shelves during times of relatively low sea level and glaciation are rarely preserved due to the mechanically erosive nature of marine transgression and regression. In this study, I investigate the geochemical and palynological characteristics of two well-preserved sites in the northern Gulf of Mexico (NGOM) to determine the ecologic settings and subsequent mechanisms of preservation in this region. Both sites contain preserved terrigenous sediments of previously exposed coastal margins; the first is located at the Alabama Underwater Forest (~13 km south of Gulf Shores, AL, at ~15 mbsl), and optically stimulated luminescence dates to 72–56 …

Hydrogeologic Investigation Of A Covered Karst Terrain, Joseph Peter Honings

LSU Doctoral Dissertations

Increasing demand for water for agricultural use within the Dougherty Plain of the Southeastern United States has depleted surface water bodies. In karstic landscapes, such as the Dougherty Plain in southwest Georgia where the linkages between surface and ground waters are close, there is a need to understand the physical characteristics of the subsurface that allow these close linkages. Having a better understanding of the subsurface characteristics will aid numerical modeling efforts that underpin policy decisions and economic analyses. Two common features on this karstic landscape are draws and geographically isolated wetlands. Using LiDAR, aerial imagery, and ground-penetrating radar, this …

Wetland Soil Development Along Salinity And Hydrogeomorphic Gradients In Active And Inactive Deltaic Basins Of Coastal Louisiana, Amanda Fontenot

LSU Master's Theses

Coastal wetlands provide an abundance of ecosystem services that benefit society, such as essential habitat for commercial species, storm protection, nutrient cycling, and carbon storage. Louisiana faces rapid rates of relative sea level rise (natural subsidence and eustatic sea levels) that threaten wetland survival, which are amplified by a reduction of riverine sediment input. An important determining factor of marsh survival is the formation of wetland platform elevation, known as vertical accretion, which is determined by several processes including sediment deposition & erosion, below ground biomass (BGB) productivity, decomposition of organic matter, shallow & deep subsidence, and soil compaction. Feldspar …

Quantitative Analysis Of The Maximum Rate And Minimum Duration For A 200 Km Stepwise Retreat Of The Bindschadler Ice Stream At ~11.5 Cal Kyr Bp, Matthew E Kratochvil

LSU Master's Theses

Small-scale morainal ridges on the middle continental shelf of the Whales Deep Basin partly record the rapid opening of a 200-km grounding line embayment slightly after ~11.5 cal kyr BP. The overlapping pattern of backstepped moraines indicates that the grounding line oscillated back and forth during the retreat. Published sediment fluxes were combined with new sediment volume mapping of the moraines to infer the rates at which the grounding line retreated. The analyses indicate that the rates of grounding line retreat on the eastern flank of the embayment ranged from ~490 m a^-1 to 1,300 m a^-1. …

Connections Between Interglacial Variation And Lithological Variability Within Midland Basin Permian Shale Rocks In Martin County, Texas, Helen Rice Hammon

LSU Master's Theses

The Upper Pennsylvanian (323.2–289.9 Ma) and Lower Permian (289.9-251 Ma), (Wolfcamp and Spraberry formations) interval of the Midland Basin, West Texas, contains a mixed succession of shale, carbonate, and siltstone/sandstone lithofacies that accumulated in a deep-water marine environment under variable hydrographic restrictions. The heterogenous stratigraphy found in the Wolfcamp and Spraberry formation was formed in response to variations in sea level and a transition from a glacial to an interglacial climate during the Early Permian. These fluctuations left behind alternating beds of mudstone and carbonate, interwoven with thin sandstone beds. Because the Wolfcamp and Spraberry formations are highly heterolithic, it …

Connections Between Interglacial Variation And Lithological Variability Within Midland Basin Permian Shale Rocks In Martin County, Texas, Helen Rice Hammon

LSU Master's Theses

The Upper Pennsylvanian (323.2–289.9 Ma) and Lower Permian (289.9-251 Ma), (Wolfcamp and Spraberry formations) interval of the Midland Basin, West Texas, contains a mixed succession of shale, carbonate, and siltstone/sandstone lithofacies that accumulated in a deep-water marine environment under variable hydrographic restrictions. The heterogenous stratigraphy found in the Wolfcamp and Spraberry formation was formed in response to variations in sea level and a transition from a glacial to an interglacial climate during the Early Permian. These fluctuations left behind alternating beds of mudstone and carbonate, interwoven with thin sandstone beds. Because the Wolfcamp and Spraberry formations are highly heterolithic, it …

Sediment Buffering And Recycling On An Annual To Centennial Scale Along The Mississippi River, Nikki E. Neubeck

LSU Master's Theses

Although the Mississippi River and its tributaries have been investigated for many years, the alteration of the river through dams, levees, and diversions has affected how sediment is transported from source to sink (>10³ y). Previous provenance research using detrital zircon U-Pb dating indicates a slow transport time from source-to-sink, but recent anthropogenic alterations of the river may potentially diminish the transportation time of heavy minerals due to an increase in flow efficiency. The objective of this study is to analyze the degree of buffering and recycling of Mississippi River sediment over a range of short time scales, …

A Numerical Investigation Of Flood And Sediment Dynamics Over The Coastal Watersheds During Hurricane Events, Dongxiao Yin

LSU Doctoral Dissertations

Landfalling tropical cyclones can cause catastrophic floods and sediment disturbance over the coastal watersheds. This study aims to unravel the contribution of different processes to hurricane-induced flooding, to assess the uncertainties in flood modelling and forecasting, and to advance the techniques in sediment simulation over coastal watersheds during hurricanes.

First, I examined the hydrometeorology and hydrology of Hurricane Florence (2018) induced inland flooding. My results suggest that the slow motion in combination with the “L-shaped” path was the most distinctive feature of the hurricane that incurred catastrophic and widespread rainfall and flooding over the Cape Fear River Basin (CFRB).

Second, …

Competitive Sorption And Transport Of Heavy Metals In Soil And Mn Oxide-Coated Sand, Joshua Tyler Padilla

LSU Doctoral Dissertations

This study investigated the competitive sorption of Ni, Pb, and Zn as well as synergistic interactions between Ni and phosphate (P) in soils and Mn oxide-coated sand. During stirred-flow experiments, the sorption of heavy metal cations by Olivier soil was mutually reduced when applied simultaneously. When applied consecutively, the cation of higher affinity was able to displace the cation of lower affinity from the soil surface, however, no evidence for the reverse case was observed. A novel general exchange kinetics model was able to correctly describe such displacement. Competition between Ni and Zn mutually increased mobility in Olivier and Windsor …

Application Of Gravity Data For Hydrocarbon Exploration Using Machine Learning Assisted Workflow, Oluwafemi Temidayo Alaofin

LSU Master's Theses

Gravity survey has played an essential role in many geoscience fields ever since it was conducted, especially as an early screening tool for subsurface hydrocarbon exploration. With continued improvement in data processing techniques and gravity survey accuracy, in-depth gravity anomaly studies, such as characterization of Bouguer and isostatic residual anomalies, have the potential to delineate prolific regional structures and hydrocarbon basins. In this study, we focus on developing a cost-effective, quick, and computationally efficient screening tool for hydrocarbon exploration using gravity data employing machine learning techniques. Since land-based gravity surveys are often expensive and difficult to obtain in remote places, …

Testing Xrf Identification Of Marine Washover Sediment Beds In A Coastal Lake In Southeastern Texas, Usa, Harry F. L. Williams, Chelsea E. Beaubouef, Kam-Biu Liu, Nicholas Culligan, Lance Riedlinger

Faculty Publications

This study tests the ability of a novel approach to identifying washover beds in coastal lakes. Combined X-Ray Fluorescence (XRF) and cluster analysis was used to identify hurricane washover beds in sediment cores from Clam Lake on the McFaddin National Wildlife Refuge in southeastern Texas. The lake is known to contain washover beds from recent hurricanes, but the washover sediment has similar microfossil, loss-on-ignition and textural characteristics to non-washover sediment and is not readily distinguishable. Sediment cores taken from marshes surrounding the lake do contain visually-recognizable sandy washover beds of Hurricanes Ike, Rita, Carla and Audrey. XRF analysis of these …

Floodplain Forests Vegetation Dynamics Driven By Water Deficits Across Scales, Nga Thanh Nguyen

LSU Doctoral Dissertations

Restoration of floodplain ecosystems relies on identifying the most crucial hydrologic process which has been altered by human and climate. Flooding is a well-known dominant hydrologic process for floodplain ecosystems, but surprisingly little is known about drought's role in structuring ecosystems. In addition, several issues remained uncertain, such as the nature of drought within floodplains and the sensitivity of floodplain species-specific growth to climate. These gaps of understanding have in common in missing observations of mechanistic pathways of vegetation response to water deficits at multiple scales in time and space.Generally, this research contributed to floodplain management by expanding our understanding …

Diffusional Fractionation Of Helium Isotopes In Silicate Melts, Haiyang Luo, Bijaya Karki, Dipta B. Ghosh, Huiming Bao

Faculty Publications

Estimating Helium (He) concentration and isotope composition of the mantle requires quantifying He loss during magma degassing. The knowledge of diffusional He isotope fractionation in silicate melts may be essential to constrain the He loss. Isotopic mass dependence of He diffusion can be empirically expressed as D3He/D4He = (4/3)^β, where D is the diffusivity of a He isotope. However, no studies have reported any β values for He in silicate melts due to technical challenges in both experiments and computations. Here, molecular dynamics simulations based on deep neural network potentials trained by ab initio data …

Blue Carbon In South Florida's Mangroves: The Role Of Large Roots And Necromass, Zoë I. Shribman

LSU Master's Theses

Blue carbon sequestration and storage in mangroves largely result from belowground biomass allocation in response to flooded anaerobic soil conditions and nutrient availability. Biomass allocation to belowground roots is a major driver of mangrove soil formation and organic matter accumulation leading to blue carbon storage potential. Belowground biomass sampling in mangroves is labor intensive, limiting data availability on biomass stocks, particularly for large roots (>20 mm diameter) and necromass (dead roots). The mangrove nutrient model (NUMAN) uses mostly literature values to parameterize a soil cohort approach to simulate depth distribution of root mass and organic carbon concentration. We evaluated …

Spatiotemporal Variability Of Soil Water Δ18o And Δ2h Reveals Hydrological Processes In Two Floodplain Soils, Amanda Ceming-Barbato

LSU Master's Theses

The movement of water through soil is preferential and heterogeneous. Subsurface interactions between mobile flows and the soil matrix are not uniform and are therefore difficult to predict through time and space. The use of stable isotopes of hydrogen (²H) and oxygen (¹⁸O) as conservative tracers of water movement is improving understanding of soil hydrological processes, yet field-scale observations of isotopic variability remain scarce despite implications for identifying dominant hydrologic processes. We sampled two adjacent soils at a ridge-swale topography floodplain forest to determine soil water isotopic variability at a 20 cm depth resolution in soils …

Palynology And Paleoclimatology Of The Chicxulub Impact Crater In The Early Paleogene, Vann Smith

LSU Doctoral Dissertations

At the end of the Cretaceous Period, a large bolide impacted the Earth and formed the Chicxulub impact crater in the Yucatán Peninsula, Mexico. In 2016, International Ocean Discovery Program (IODP) Expedition 364 Site M0077 drilled into the buried peak ring of the crater, recovering a marine Paleocene to early Eocene post-impact section deposited on top of the impact breccia. Palynological analysis of 195 samples from the post-impact section has yielded the first pre-Holocene vegetational record from inside the Chicxulub impact crater and the first palynological record of the recovery of life following the end-Cretaceous mass extinction from inside the …

Spatiotemporal Trends And Variability In The Centroid Of The Northern Hemisphere's Circumpolar Vortex, Nazla Bushra, Robert V. Rohli

Faculty Publications

Recent previous research has established the "sharpest gradient" approach to defining the circumpolar vortex and has identified correlations of the area and circularity of the Northern Hemisphere's circumpolar vortex (NHCPV) to important atmospheric-oceanic teleconnections. However, because geographical shifts in the NHCPV, independent of area or circularity changes, could affect surface environmental conditions, this research addresses the question of the extent to which the NHCPV centroid undergoes such shifts, both intra- and inter-annually. Results show that during the 1979-2017 period, the centroid has moved less on a daily basis in more recent years, perhaps indicative of a stabilization in circulation, with …

Phragmites Australis Dieback In The Mississippi River Delta: Chemical Profiles Of Soil Types And Restoration Potential, Herie Lee

LSU Master's Theses

Since 2016, there has been widespread dieback of P. australis in the Lower Mississippi River Delta (hereafter referred to as Lower MRD, which is defined as the Birds Foot Delta) with relatively little to no signs of recovery. The cause of the current dieback is not fully understood. This thesis explores P. australis with emphasis on chemical profile characterization of different soil types and its effects on plant growth and the potential for restoration in the Lower MRD.

In chapter 2, I characterized the chemical profiles of soils collected from healthy and dieback stands of Phragmites, and from newly …

Causes And Characteristics Of Electrical Resistivity Variability In Shallow (<4 M) Soils In Taylor Valley, East Antarctica, William S. Gutterman

LSU Master's Theses

The McMurdo Dry Valleys are the largest ice-free region in Antarctica and are characterized as a polar desert environment. Soils in the region are typically very dry (<1% soil water by weight) and remain frozen for most of the year. Increases in air temperature and incoming solar radiation during the austral summer generate meltwater from glaciers, ground ice, and snow patches supplying moisture to soils and altering the physical and chemical makeup of the subsurface. Previous studies have utilized airborne electromagnetic surveys (AEM) to analyze groundwater systems in the deep subsurface but have not yet examined soil moisture in the shallow (<4 m) subsurface. Here, I used electrical resistivity data from two AEM surveys (2011 and 2018) and soil geochemical data from three transects to characterize the spatial heterogeneity of soil properties in the near-subsurface of lower Taylor Valley. Soil resistivities from 2011 and 2018 range from 33.2 Ωm to 3535 Ωm with low elevations of <100 meters above sea level (masl) typically displaying the lowest resistivities and high elevations displaying greater resistivities. Liquid brine fractions were empirically estimated from electrical resistivity values using Archie’s Law and range from 0.3% to 68.2% for soils with resistivities <200 Ωm. Additionally, soil transect data show greater percentages of fine-grained sediments (<63 µm) exist at elevations <100 masl where soil resistivities begin decreasing. Resistivity variability in the subsurface is ultimately controlled by the site history, local and regional climate, soil salinity, soil moisture, soil lithology.

Late Miocene Unroofing Of The Inner Lesser Himalaya Recorded In The Nw Himalaya Foreland Basin, Elise Marie Exnicios

LSU Master's Theses

Testing models that link climate and solid Earth tectonics requires independent erosional, structural and climatic histories. Two well preserved stratigraphic sections of the Himalayan foreland basin are exposed in NW India. The Jawalamukhi (13–5 Ma) and Joginder Nagar sections (21–13 Ma) are dated by magnetostratigraphy and span a period of significant climate change and tectonic evolution. We use detrital zircon U-Pb dating and apatite fission track analyses to reconstruct changes in the patterns of erosion and exhumation in this area from the Early Miocene to Pliocene. The provenance of the foreland sediments shows that since at least ~21 Ma the …

Computer Simulations Of Diffusional Isotope Effects And Dynamical Properties Of Silicate Melts, Haiyang Luo

LSU Doctoral Dissertations

Silicate melts have served as transport agents in the chemical and thermal evolution of Earth. Diffusional isotope effect in silicate melts is the key to interpret isotope variations in lots of geological samples. Isotopic mass dependence of diffusion is commonly expressed as (Di/Dj)=(mj/mi)^β, where Di and Dj are diffusion coefficients of two isotopes whose masses are mi and mj. However, how the dimensionless empirical parameter β depends on temperature, pressure, and composition remains poorly constrained. Viscosity and electrical conductivity are two fundamental dynamical properties of silicate melts needed to constrain melt distribution in Earth's interior but remain unclear for most …

Simulation Of Compound Flood Events In Low-Gradient Coastal Watershed, Felix Luis Santiago-Collazo

LSU Doctoral Dissertations

Low-gradient coastal watersheds are susceptible to flooding caused by various flows such as rainfall, tides, and storm surge. Compound flooding occurs when at least two of these mechanisms happen simultaneously or in close succession. Different inundation models, observed data, and/or a combination of these are coupled through varying techniques involving one-way, loosely, tightly, or fully coupled approaches to assess compound flooding. This study presents a one-dimensional (1-D), fully coupled compound inundation model based on the Shallow Water equations. This model approach simultaneously simulates the free water surface variations in the ocean domain (i.e., tide and storm surge modeling), rainfall-runoff in …

Wildfires: Vegetation Recovery And The Potential For Future Fires, Moses Okonkwo

LSU Master's Theses

Analysis of satellite imagery combined with Geographic Information Systems (GIS), often allows for observing the increasing changes in land cover dynamics. These changes are often on a macro scale buoyed by natural hazards such as wildfires. This study examines the vegetation recovery dynamics by using multispectral data and also gleaned insight in the applications of Hyperspectral satellite imagery in the study of vegetation dynamics. Both Landsat 8 Operational Land Imager (OLI) (multispectral) and the Earth-Observing One (EO-1) (hyperspectral) data are freely available; however the former has a limited spatial and temporal coverage. The relationship between vegetation recovery, elevation, aspect and …