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Environmental Chemistry Commons

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2000

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Articles 1 - 14 of 14

Full-Text Articles in Environmental Chemistry

Modeling Distinct Vertical Biogeochemical Structure Of The Black Sea: Dynamical Coupling Of The Oxic, Suboxic, And Anoxic Layers, T Oguz, Hw Ducklow, P Malanotte-Rizzoli Nov 2000

Modeling Distinct Vertical Biogeochemical Structure Of The Black Sea: Dynamical Coupling Of The Oxic, Suboxic, And Anoxic Layers, T Oguz, Hw Ducklow, P Malanotte-Rizzoli

VIMS Articles

A one-dimensional, vertically resolved, physical-biogeochemical model is used to provide a unified representation of the dynamically coupled oxic-suboxic-anoxic system for the interior Black Sea. The model relates the annual cycle of plankton production in the form of a series of successive phytoplankton, mesozooplankton, and higher consumer blooms to organic matter generation and to the remineralization-ammonification-nitrification-dentrification chain of the nitrogen cycle as well as to anaerobic sulfide oxidation in the suboxic-anoxic interface zone. The simulations indicate that oxygen consumption during remineralixation and nitrification, together with a lack of ventilation of subsurface waters due to the presence of strong stratification, are the …


Biogeochemistry And Contaminant Geochemistry Of Marine And Estuarine Sediments, New Haven, Connecticut (Usa), Michael A. Kruge, Gaboury Benoit Nov 2000

Biogeochemistry And Contaminant Geochemistry Of Marine And Estuarine Sediments, New Haven, Connecticut (Usa), Michael A. Kruge, Gaboury Benoit

Department of Earth and Environmental Studies Faculty Scholarship and Creative Works

The urbanized shore areas of Long Island Sound in the vicinity of New Haven, Connecticut (USA) have a long history of exposure to point and non-point sources of pollution, New Haven having been one of the birthplaces of the industrial revolution. As an unintended consequence of such activities, the region's sedimentary systems have incorporated a complex mixture of organic and inorganic contaminants. With its long and varied pollution history and the multiplicity of sedimentary environments (fluvial, estuarine, intertidal, marsh, etc.) present in a compact geographical area, the region is ideal natural laboratory for field testing new contamination assessment techniques. The …


Phytosociological Analysis Of Restored And Managed Grassland Habitat Within An Urban National Park, Andrew M. Greller, Celestine Durando, Leslie F. Marcus, D. Siril A. Wijesundara, Michael D. Byer, Robert Cook, John T. Tanacredi Ph.D. Oct 2000

Phytosociological Analysis Of Restored And Managed Grassland Habitat Within An Urban National Park, Andrew M. Greller, Celestine Durando, Leslie F. Marcus, D. Siril A. Wijesundara, Michael D. Byer, Robert Cook, John T. Tanacredi Ph.D.

Faculty Works: CERCOM

Floyd Bennett Field (FBF), 579 ha in extent, is a division of Gateway National Recreation Area. It is the site of a former airfield, constructed by filling salt marshes with dredged materials. Except for the portion known locally as the “North Forty,” all sections of FBF have been cut over to maintain low vegetation. A grassland management plan (GRAMP) for 165 ha was initiated in 1986, to maintain habitats for open-country birds. Over the next few years, encroaching woody vegetation was removed manually and mechanically from the management area. Since then, it has been maintained as a grassland and receives …


Binding Of Pb And Zn To Aluminium Oxide And Proton Stoichiometry, Wing H. Leung, A. Kimaro Apr 2000

Binding Of Pb And Zn To Aluminium Oxide And Proton Stoichiometry, Wing H. Leung, A. Kimaro

Virginia Journal of Science

The interaction of Pb and Zn with Al2O3 in aqueous solution was studied as a function of pH and metal ion concentration. Results indicated the complexation of metal ions by oxide surfaces is strongly pH dependent; the extent of adsorption is a function of pH with an abrupt change within approximately 2 pH units. The adsorption of Pb and Zn on aluminium oxide can be interpreted in terms of a surface complexation formed by association with one surface AlOH group, thus releasing one bound hydrogen ion. -AlOH + M2+ = -AlOM+ + H+ . …


In Situ Treatment Of Chlorinated Ethene-Contaminated Groundwater Using Horizontal Flow Treatment Wells, Derek R. Ferland Mar 2000

In Situ Treatment Of Chlorinated Ethene-Contaminated Groundwater Using Horizontal Flow Treatment Wells, Derek R. Ferland

Theses and Dissertations

The limitations of conventional containment technologies for groundwater contaminated with chlorinated solvents have motivated development of innovative technologies to achieve national groundwater remediation objectives. One inn9vative technology that is currently under development involves metal reductants or catalysts to chemically destroy the dissolved chlorinated solvent. Models are important tools that can be used to help transition this technology to the field. Model studies can be used to gain understanding about the technology, help determine when the prospective technology might work for a given site, and design full-scale field applications.


Modeling Chlorinated Ethene Removal In Constructed Wetlands: A System Dynamics Approach, Colby D. Hoefar Mar 2000

Modeling Chlorinated Ethene Removal In Constructed Wetlands: A System Dynamics Approach, Colby D. Hoefar

Theses and Dissertations

The purpose of this study is to gain understanding of the dynamics of the processes that degrade Perchloroethene (PCE) to ethylene, or carbon dioxide (CO2), within the confines of a constructed wetland. A system dynamics approach will be used. This model is focused on identifying and optimizing the naturally occurring processes in stratified wetland sediment that reduce mass, toxicity, mobility, volume or concentration of contaminants in groundwater. Contaminant fate and transport within a wetland system is extremely complex and the mechanisms that drive wetland behavior are dynamic. Confidence in the model was built through verification and testing. Reasonable …


Chromate Dissociation From Primer Paint In Simulated Lung Fluid, Tiffany J. R. Morgan Mar 2000

Chromate Dissociation From Primer Paint In Simulated Lung Fluid, Tiffany J. R. Morgan

Theses and Dissertations

OSHA has proposed a new strontium chromate exposure standard that would potentially cause Air Force paint facilities to be in violation of the proposed standard if adopted. This proposed reduction make the continued use of chromate containing primer paints very difficult. There is currently no acceptable replacements for chromate containing primer paints on AF aircraft. This study suggests that paint particles with chromate bound in primer paint may be unavailable for bodily absorption if inhaled and a reduced standard for painting applications may be unnecessary. Primer paint overspray was collected into simulated lung fluid (SLF) and allowed 6 hr, 24 …


Analysis Of Remote Sensing Data For Development Of I/M Program Evaluation Protocols, Sajal S. Pokharel, Gary A. Bishop, Donald H. Stedman Jan 2000

Analysis Of Remote Sensing Data For Development Of I/M Program Evaluation Protocols, Sajal S. Pokharel, Gary A. Bishop, Donald H. Stedman

Fuel Efficiency Automobile Test Publications

No abstract provided.


On-Road Remote Sensing Of Automobile Emissions In The Los Angeles Area: Year 1, Gary A. Bishop, Sajal S. Pokharel, Donald H. Stedman Jan 2000

On-Road Remote Sensing Of Automobile Emissions In The Los Angeles Area: Year 1, Gary A. Bishop, Sajal S. Pokharel, Donald H. Stedman

Fuel Efficiency Automobile Test Publications

No abstract provided.


Parameters Influencing Sediments Resuspension And The Link To Sorption Of Inorganic Compounds, Eid A. Alkhatib, Keith Castor Jan 2000

Parameters Influencing Sediments Resuspension And The Link To Sorption Of Inorganic Compounds, Eid A. Alkhatib, Keith Castor

Chemistry & Physics Faculty Publications

In the aquatic environment, the accumulation of chemicalcontaminants by sediments poses a potential threat to endemiclife forms and drinking water resources. Trace metals such asCd, Cu, Cr, Ni, Pb, and toxic organic compounds, are among awide variety of contaminants having an affinity for sediments.In this study, experiments were performed simulating sedimentresuspension in the lower Housatonic River, Connecticut, using aParticle Entrainment Simulator. Analyses of grain sizedistributions, porosities and total organic contents of thesediments suggested that these parameters influence theredistribution and entrainment of settleable solids in the watercolumn. These findings were established by evaluating the impactof one parameter on sediment resuspension as …


New Emission Test Would Cost More, Do Less, Donald H. Stedman Jan 2000

New Emission Test Would Cost More, Do Less, Donald H. Stedman

Fuel Efficiency Automobile Test Publications

No abstract provided.


On-Road Remote Sensing Of Automobile Emissions In The Chicago Area: Year 3, Sajal S. Pokharel, Gary A. Bishop, Donald H. Stedman Jan 2000

On-Road Remote Sensing Of Automobile Emissions In The Chicago Area: Year 3, Sajal S. Pokharel, Gary A. Bishop, Donald H. Stedman

Fuel Efficiency Automobile Test Publications

No abstract provided.


Rsd Versus Im240 Fleet Average Correlations, Sajal S. Pokharel, Donald H. Stedman, Gary A. Bishop Jan 2000

Rsd Versus Im240 Fleet Average Correlations, Sajal S. Pokharel, Donald H. Stedman, Gary A. Bishop

Fuel Efficiency Automobile Test Publications

No abstract provided.


Surrounding Denver Metro Smart Sign Study Summer 2000, Michael Duncan Jan 2000

Surrounding Denver Metro Smart Sign Study Summer 2000, Michael Duncan

Fuel Efficiency Automobile Test Publications

No abstract provided.