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Articles 1 - 30 of 198
Full-Text Articles in Environmental Chemistry
Toward A Coordinated Understanding Of Hydro-Biogeochemical Root Functions In Tropical Forests For Application In Vegetation Models, Daniela F. Cusack, Bradley Christoffersen, Chris M. Smith-Martin, Kelly M. Andersen, Amanda L. Cordeiro, Katrin Fleischer, S. Joseph Wright, Nathaly R. Guerrero-Ramírez, Laynara F. Lugli, Lindsay A. Mcculloch, Mareli Sanchez-Julia, Sarah A. Batterman, Caroline Dallstream, Claire Fortunel, Laura Toro, Lucia Fuchslueger, Michelle Y. Wong, Daniela Yaffar, Joshua B. Fisher, Marie Arnaud, Lee H. Dietterich, Shalom D. Addo-Danso, Oscar J. Valverde-Barrantes, Monique Weemstra, Jing Cheng Ng, Richard J. Norby
Toward A Coordinated Understanding Of Hydro-Biogeochemical Root Functions In Tropical Forests For Application In Vegetation Models, Daniela F. Cusack, Bradley Christoffersen, Chris M. Smith-Martin, Kelly M. Andersen, Amanda L. Cordeiro, Katrin Fleischer, S. Joseph Wright, Nathaly R. Guerrero-Ramírez, Laynara F. Lugli, Lindsay A. Mcculloch, Mareli Sanchez-Julia, Sarah A. Batterman, Caroline Dallstream, Claire Fortunel, Laura Toro, Lucia Fuchslueger, Michelle Y. Wong, Daniela Yaffar, Joshua B. Fisher, Marie Arnaud, Lee H. Dietterich, Shalom D. Addo-Danso, Oscar J. Valverde-Barrantes, Monique Weemstra, Jing Cheng Ng, Richard J. Norby
Biology, Chemistry, and Environmental Sciences Faculty Articles and Research
Tropical forest root characteristics and resource acquisition strategies are underrepresented in vegetation and global models, hampering the prediction of forest–climate feedbacks for these carbon-rich ecosystems. Lowland tropical forests often have globally unique combinations of high taxonomic and functional biodiversity, rainfall seasonality, and strongly weathered infertile soils, giving rise to distinct patterns in root traits and functions compared with higher latitude ecosystems. We provide a roadmap for integrating recent advances in our understanding of tropical forest belowground function into vegetation models, focusing on water and nutrient acquisition. We offer comparisons of recent advances in empirical and model understanding of root characteristics …
Sulfate Enhances The Adsorption And Retention Of Cu(Ii) And Zn(Ii) To Dispersed And Aggregated Iron Oxyhydroxide Nanoparticles, Emma M. Kocik, Abigail Kim, Miranda L. Aiken, Lauren Smith, Christopher S. Kim
Sulfate Enhances The Adsorption And Retention Of Cu(Ii) And Zn(Ii) To Dispersed And Aggregated Iron Oxyhydroxide Nanoparticles, Emma M. Kocik, Abigail Kim, Miranda L. Aiken, Lauren Smith, Christopher S. Kim
Biology, Chemistry, and Environmental Sciences Faculty Articles and Research
The adsorption and retention of metal ions to nanoscale iron (hydr)oxides in aqueous systems is significantly influenced by prevailing environmental conditions. We examined the influence of sulfate, the second most common anion in seawater that is present in many other natural aquatic systems, on the adsorption and retention of Cu(II) and Zn(II) to synthetic iron oxyhydroxide nanoparticles (NPs) and their aggregates. Batch uptake experiments with monodisperse NPs and NPs aggregated by changes in pH, ionic strength, and temperature were conducted over sulfate concentrations ranging from 0 to 0.30 M. The introduction of 0.03 M sulfate significantly increased the initial adsorption …
Impact Of Solar Radiation On Perchlorate Formation In The Atmosphere: Evidence From Ice Core Measurements, Bishnu Kunwar
Impact Of Solar Radiation On Perchlorate Formation In The Atmosphere: Evidence From Ice Core Measurements, Bishnu Kunwar
Electronic Theses and Dissertations
Perchlorate, which derives from both anthropogenic and natural sources in the current environment, poses a substantial health hazard to humans as it competes with iodine uptake in the thyroid gland. Consequently, there has been considerable concern about minimizing human exposure to environmental perchlorate by restricting its release from man-made sources. However, the absence of a clear understanding regarding the respective contributions of man-made and natural sources has hindered widespread regulation efforts. A 300-year (1700–2007) Summit, Greenland ice core record from a previous study showed relatively stable perchlorate concentrations in Greenland snow prior to 1980, with some elevated perchlorate levels associated …
Permafrost Carbon: Progress On Understanding Stocks And Fluxes Across Northern Terrestrial Ecosystems, Claire C. Treat, Anna-Maria Virkkala, Eleanor Burke, Lori Bruhwiler, Abhishek Chatterjee, Joshua B. Fisher, Josh Hashemi, Frans-Jan W. Parmentier, Brendan M. Rogers, Sebastian Westermann, Jennifer D. Watts, Elena Blanc-Betes, Matthias Fuchs, Stefan Kruse, Avni Malhotra, Kimberley Miner, Jens Strauss, Amanda Armstrong, Howard E. Epstein, Bradley Gay, Mathias Goeckede, Aram Kalhori, Dan Kou, Charles E. Miller, Susan M. Natali, Youmi Oh, Sarah Shakil, Oliver Sonnentag, Ruth K. Varner, Scott Zolkos, Edward A.G. Schuur, Gustaf Hugelius
Permafrost Carbon: Progress On Understanding Stocks And Fluxes Across Northern Terrestrial Ecosystems, Claire C. Treat, Anna-Maria Virkkala, Eleanor Burke, Lori Bruhwiler, Abhishek Chatterjee, Joshua B. Fisher, Josh Hashemi, Frans-Jan W. Parmentier, Brendan M. Rogers, Sebastian Westermann, Jennifer D. Watts, Elena Blanc-Betes, Matthias Fuchs, Stefan Kruse, Avni Malhotra, Kimberley Miner, Jens Strauss, Amanda Armstrong, Howard E. Epstein, Bradley Gay, Mathias Goeckede, Aram Kalhori, Dan Kou, Charles E. Miller, Susan M. Natali, Youmi Oh, Sarah Shakil, Oliver Sonnentag, Ruth K. Varner, Scott Zolkos, Edward A.G. Schuur, Gustaf Hugelius
Biology, Chemistry, and Environmental Sciences Faculty Articles and Research
Significant progress in permafrost carbon science made over the past decades include the identification of vast permafrost carbon stocks, the development of new pan-Arctic permafrost maps, an increase in terrestrial measurement sites for CO2 and methane fluxes, and important factors affecting carbon cycling, including vegetation changes, periods of soil freezing and thawing, wildfire, and other disturbance events. Process-based modeling studies now include key elements of permafrost carbon cycling and advances in statistical modeling and inverse modeling enhance understanding of permafrost region C budgets. By combining existing data syntheses and model outputs, the permafrost region is likely a wetland methane …
Enhancing Urban Water Quality Through Biological-Chemical Treatment: Aquatic Macroinvertebrate Community And Temporal Chlorophyll-A Response, Matthew Chaffee
Enhancing Urban Water Quality Through Biological-Chemical Treatment: Aquatic Macroinvertebrate Community And Temporal Chlorophyll-A Response, Matthew Chaffee
Department of Agricultural and Biological Systems Engineering: Dissertations, Theses, and Student Research
With a growing human population, urbanization is impeding a plethora of natural waterways. Of these, urban ponds play a vital role in nutrient sequestration, flood prevention, and habitat sanctuaries. However, nutrient loading can reduce habitat effectiveness and promote harmful algae blooms. To reduce internal nutrient loads, a biological-chemical treatment strategy consisting of floating treatment wetlands (FTWs) and lanthanum were applied to two urban retention ponds, Densmore and Wilderness Ridge Ponds. To measure effectiveness, chlorophyll-a samples were collected and correlated with Sentinel-2. A novel band algorithm termed 3BR1 produced a strong correlation (R2 = 0.72) to physical chlorophyll-a …
Quantifying The Role Of Water Quality On Nitrogen Cycling In A Trophic Estuary, Kayla Gonzalez-Boy
Quantifying The Role Of Water Quality On Nitrogen Cycling In A Trophic Estuary, Kayla Gonzalez-Boy
Symposium of Student Scholars
Jobos Bay Estuary is an intertidal, tropical estuary located in southern Puerto Rico. The estuary covers about 12 km2 and has a variety of habitats, such as seagrass beds, mangroves, mud flats, and coral reefs, which play important roles in sediment trapping and water quality maintenance. Seagrasses also serve as nursery and feeding grounds and provide shelter for macrofauna. Currently, the role of seagrasses and water quality on nitrogen (N) cycling in trophic estuaries is not well constrained. Understanding variations in sediment-based effects on N cycling rates and transformations, and how they are associated with water quality, is an …
Approaches To Assessing Nutrient Coupling In Open Ocean Datasets, James M. Moore, Claire P. Till
Approaches To Assessing Nutrient Coupling In Open Ocean Datasets, James M. Moore, Claire P. Till
IdeaFest: Interdisciplinary Journal of Creative Works and Research from Cal Poly Humboldt
Nutrient coupling describes a process where the biogeochemical cycles of two elements are linked by being incorporated similarly into biomass. This paper uses data from the GEOTRACES GP16 cruise (Eastern Pacific Zonal Transect) to investigate the relationship between certain macronutrients generally coupled to trace elements in terms of their oceanic distributions with the notable exception of in an oxygen minimum zone: cadmium-phosphate and zinc-silicate. There are many methods applied to oceanographic data to correlate analyte concentrations; while they are often presented independently in literature, here we attempt to use them in conjunction for a more thorough interpretation. By compiling 1) …
Symbiotic Ucyn-A Strains Co-Occurred With El Niño, Relaxed Upwelling, And Varied Eukaryotes Over 10 Years Off Southern California, Colette Fletcher-Hoppe, Yi-Chun Yeh, Yubin Raut, J. L. Weissman, Jed A. Fuhrman
Symbiotic Ucyn-A Strains Co-Occurred With El Niño, Relaxed Upwelling, And Varied Eukaryotes Over 10 Years Off Southern California, Colette Fletcher-Hoppe, Yi-Chun Yeh, Yubin Raut, J. L. Weissman, Jed A. Fuhrman
Biology, Chemistry, and Environmental Sciences Faculty Articles and Research
Biological nitrogen fixation, the conversion of N2 gas into a bioavailable form, is vital to sustaining marine primary production. Studies have shifted beyond traditionally studied tropical diazotrophs. Candidatus Atelocyanobacterium thalassa (or UCYN-A) has emerged as a focal point due to its streamlined metabolism, intimate partnership with a haptophyte host, and broad distribution. Here, we explore the environmental parameters that govern UCYN-A’s presence at the San Pedro Ocean Time-series (SPOT), its host specificity, and statistically significant interactions with non-host eukaryotes from 2008-2018. 16S and 18S rRNA gene sequences were amplified by “universal primers” from monthly samples and resolved into Amplicon …
Small Community Water Systems Have The Highest Prevalence Of Mn In Drinking Water In California, Usa, Miranda Aiken, Samantha C. Ying
Small Community Water Systems Have The Highest Prevalence Of Mn In Drinking Water In California, Usa, Miranda Aiken, Samantha C. Ying
Biology, Chemistry, and Environmental Sciences Faculty Articles and Research
Manganese (Mn) is currently regulated as a secondary contaminant in California, USA; however, recent revisions of the World Health Organization drinking water guidelines have increased regulatory attention of Mn in drinking water due to increasing reports of neurotoxic effects in infants and children. In this study, Mn concentrations reported to California’s Safe Drinking Water Information System were used to estimate the potentially exposed population within California based on system size. We estimate that between 2011 and 2021, over 525,000 users in areas with reported Mn data are potentially exposed to Mn concentrations exceeding the WHO health-based guideline (80 μg L …
Atmospheric Input And Seasonal Inventory Of Dissolved Iron In The Sargasso Sea: Implications For Iron Dynamics In Surface Waters Of The Subtropical Ocean, Peter N. Sedwick, Bettina M. Sohst, K. N. Buck, S. Caprara, R. J. Johnson, D. C. Ohnemus, L. E. Sofen, A. Tagliabue, B. S. Twining, Tara E. Williams
Atmospheric Input And Seasonal Inventory Of Dissolved Iron In The Sargasso Sea: Implications For Iron Dynamics In Surface Waters Of The Subtropical Ocean, Peter N. Sedwick, Bettina M. Sohst, K. N. Buck, S. Caprara, R. J. Johnson, D. C. Ohnemus, L. E. Sofen, A. Tagliabue, B. S. Twining, Tara E. Williams
OES Faculty Publications
Constraining the role of dust deposition in regulating the concentration of the essential micronutrient iron in surface ocean waters requires knowledge of the flux of seawater-soluble iron in aerosols and the replacement time of dissolved iron (DFe) in the euphotic zone. Here we estimate these quantities using seasonally resolved DFe data from the Bermuda Atlantic Time-series Study region and weekly-scale measurements of iron in aerosols and rain from Bermuda during 2019. In response to seasonal changes in vertical mixing, primary production and dust deposition, surface DFe concentrations vary from ∼0.2 nM in early spring to >1 nM in late summer, …
Global Oceanic Diazotroph Database Version 2 And Elevated Estimate Of Global N2 Fixation, Zhibo Shao, Yangchun Xu, Hua Wang, Weicheng Luo, Lice Wang, Yuhong Huang, Nona Sheila R. Agawin, Ayaz Ahmed, Mar Benavides, Mikkel Bentzon-Tilia, Ilana Berman-Frank, Hugo Berthelot, Isabelle C. Biegala, Mariana B. Bif, Antonio Bode, Sophie Bonnet, Deborah A. Bronk, Mark V. Brown, Lisa Campbell, Ya-Wei Luo
Global Oceanic Diazotroph Database Version 2 And Elevated Estimate Of Global N2 Fixation, Zhibo Shao, Yangchun Xu, Hua Wang, Weicheng Luo, Lice Wang, Yuhong Huang, Nona Sheila R. Agawin, Ayaz Ahmed, Mar Benavides, Mikkel Bentzon-Tilia, Ilana Berman-Frank, Hugo Berthelot, Isabelle C. Biegala, Mariana B. Bif, Antonio Bode, Sophie Bonnet, Deborah A. Bronk, Mark V. Brown, Lisa Campbell, Ya-Wei Luo
OES Faculty Publications
Marine diazotrophs convert dinitrogen (N2) gas into bioavailable nitrogen (N), supporting life in the global ocean. In 2012, the first version of the global oceanic diazotroph database (version 1) was published. Here, we present an updated version of the database (version 2), significantly increasing the number of in situ diazotrophic measurements from 13 565 to 55 286. Data points for N2 fixation rates, diazotrophic cell abundance, and nifH gene copy abundance have increased by 184 %, 86 %, and 809 %, respectively. Version 2 includes two new data sheets for the nifH gene copy abundance of non-cyanobacterial …
Authigenic Iron Is A Significant Component Of Oceanic Labile Particulate Iron Inventories, Laura E. Sofen, Olga A. Antipova, Kristen N. Buck, Salvatore Caprara, Lauren Chacho, Rodney J. Johnson, Gabriella Kim, Peter Morton, Daniel C. Ohnemus, Sara Rauschenberg, Peter N. Sedwick, Alessandro Tagliabue, Benjamin S. Twining
Authigenic Iron Is A Significant Component Of Oceanic Labile Particulate Iron Inventories, Laura E. Sofen, Olga A. Antipova, Kristen N. Buck, Salvatore Caprara, Lauren Chacho, Rodney J. Johnson, Gabriella Kim, Peter Morton, Daniel C. Ohnemus, Sara Rauschenberg, Peter N. Sedwick, Alessandro Tagliabue, Benjamin S. Twining
OES Faculty Publications
Particulate phases transport trace metals (TM) and thereby exert a major control on TM distribution in the ocean. Particulate TMs can be classified by their origin as lithogenic (crustal material), biogenic (cellular), or authigenic (formed in situ), but distinguishing these fractions analytically in field samples is a challenge often addressed using operational definitions and assumptions. These different phases require accurate characterization because they have distinct roles in the biogeochemical iron cycle. Particles collected from the upper 2,000 m of the northwest subtropical Atlantic Ocean over four seasonal cruises throughout 2019 were digested with a chemical leach to operationally distinguish labile …
Food Waste Storage Gaseous Emissions Detection And Quantification Using Infrared Spectroscopy, Ryley A. Burton-Tauzer
Food Waste Storage Gaseous Emissions Detection And Quantification Using Infrared Spectroscopy, Ryley A. Burton-Tauzer
Cal Poly Humboldt theses and projects
A growing interest in sustainable waste management and the implementation of new policies have prompted a shift towards alternative resource recovery methods for organic waste, including food waste. To effectively assess alternative food waste treatment scenarios, it is important to evaluate the life cycle impacts associated with each scenario. The storage phase of food waste, encompassing its accumulation in kitchens, and storage in bins for collection and transportation, has been overlooked as a source of greenhouse gases in previous studies. This investigation aimed to identify the greenhouse gases emitted during the initial five-day period of low-oxygen storage. An open dynamic …
Potential Interactions Between Diatoms And Bacteria Are Shaped By Trace Element Gradients In The Southern Ocean, Alexa R. Sterling, Laura Z. Holland, Randelle M. Bundy, Shannon M. Burns, Kristen N. Buck, P. Dreux Chappell, Bethany D. Jenkins
Potential Interactions Between Diatoms And Bacteria Are Shaped By Trace Element Gradients In The Southern Ocean, Alexa R. Sterling, Laura Z. Holland, Randelle M. Bundy, Shannon M. Burns, Kristen N. Buck, P. Dreux Chappell, Bethany D. Jenkins
OES Faculty Publications
The growth of diatoms in the Southern Ocean, especially the region surrounding the West Antarctic Peninsula, is frequently constrained by low dissolved iron and other trace metal concentrations. This challenge may be overcome by mutualisms between diatoms and co-occurring associated bacteria, in which diatoms produce organic carbon as a substrate for bacterial growth, and bacteria produce siderophores, metal-binding ligands that can supply diatoms with metals upon uptake as well as other useful secondary compounds for diatom growth like vitamins. To examine the relationships between diatoms and bacteria in the plankton (diatom) size class (> 3 mu m), we sampled both …
Isotopic Evidence For Sources Of Dissolved Carbon And The Role Of Organic Matter Respiration In The Fraser River Basin, Canada, Britta M. Voss, Timothy I. Eglinton, Bernhard Peucker-Ehrenbrink, Valier Galy, Susan Q. Lang, Cameron Mcintyre, Robert G.M. Spencer, Ekaterina Bulygina, Zhaohui Aleck Wang, Katherine A. Guay
Isotopic Evidence For Sources Of Dissolved Carbon And The Role Of Organic Matter Respiration In The Fraser River Basin, Canada, Britta M. Voss, Timothy I. Eglinton, Bernhard Peucker-Ehrenbrink, Valier Galy, Susan Q. Lang, Cameron Mcintyre, Robert G.M. Spencer, Ekaterina Bulygina, Zhaohui Aleck Wang, Katherine A. Guay
OES Faculty Publications
Sources of dissolved and particulate carbon to the Fraser River system vary significantly in space and time. Tributaries in the northern interior of the basin consistently deliver higher concentrations of dissolved organic carbon (DOC) to the main stem than other tributaries. Based on samples collected near the Fraser River mouth throughout 2013, the radiocarbon age of DOC exported from the Fraser River does not change significantly across seasons despite a spike in DOC concentration during the freshet, suggesting modulation of heterogeneous upstream chemical and isotopic signals during transit through the river basin. Dissolved inorganic carbon (DIC) concentrations are highest in …
Possible Overestimation Of Nitrogen Dioxide Outgassing During The Beirut 2020 Explosion, Ashraf Farahat, Nayla El-Kork, Ramesh P. Singh, Feng Jing
Possible Overestimation Of Nitrogen Dioxide Outgassing During The Beirut 2020 Explosion, Ashraf Farahat, Nayla El-Kork, Ramesh P. Singh, Feng Jing
Biology, Chemistry, and Environmental Sciences Faculty Articles and Research
On 4 August 2020, a strong explosion occurred near the Beirut seaport, Lebanon and killed more than 200 people and damaged numerous buildings in the vicinity. As Amonium Nitrate (AN) caused the explosion, many studies claimed the release of large amounts of NO2 in the atmosphere may have resulted in a health hazard in Beirut and the vicinity. In order to reasonably evaluate the significance of NO2 amounts released in the atmosphere, it is important to investigate the spatio-temporal distribution of NO2 during and after the blast and compare it to the average day-to-day background emissions from …
Wrack Lines Volume 22, Number 2, Fall-Winter 2022-2023, Nancy C. Balcom, Juliana Barrett, Judy Benson, Ben Crnic, Sto Len
Wrack Lines Volume 22, Number 2, Fall-Winter 2022-2023, Nancy C. Balcom, Juliana Barrett, Judy Benson, Ben Crnic, Sto Len
Wrack Lines
With the theme, "Looking Ahead: People and Projects Shaping the Future," the Fall-Winter 2022-2023 leads with the first in what will be a series of articles about offshore wind development impacting Connecticut. That is followed by the inspiring story of how a dying forest was replanted for climate resilience. Next, a profile of longtime marine educator Tim Visel tells about his lasting impact on Connecticut schools and students. Lastly, the complex challenge of dealing with Contaminants of Emerging Concern is examined, with descriptions of how Sea Grant is involved and the particularly troublesome group of substances called PFAS.
Tools For Predicting Emulsification Capacity Of Crude Oil Exposed To Sunlight: Impact Of Photoproduced Carboxylic Acids On Emulsion Stability, Chaka Nacaya Brown
Tools For Predicting Emulsification Capacity Of Crude Oil Exposed To Sunlight: Impact Of Photoproduced Carboxylic Acids On Emulsion Stability, Chaka Nacaya Brown
University of New Orleans Theses and Dissertations
The role of acids in the formation of emulsions from sunlight exposed petroleum is not well understood. To elucidate the impact of sunlight on the formation of emulsions from petroleum, Macondo, its surrogate and NIST 1619b and 2717a were separately exposed to simulated sunlight for up to 48 hours as a film dispersed into a quartz dish, or a film spread on water. Emulsion stability was scored from 0-5. All exposures demonstrated a correlation between emulsion stability and sunlight exposure with no observable emulsification in absence of photoproduction due to sunlight exposure. Aqueous studies of DOCHC (dissolved organic carbon …
Chromophoric Dissolved Organic Matter And Dissolved Organic Carbon In Lakes Across An Elevational Gradient From The Mountains To The Sea, Kyle Juetten, Angela L. Strecker, Aaron Harrison, Zachary Landram, Warren J. De Bruyn, Catherine D. Clark
Chromophoric Dissolved Organic Matter And Dissolved Organic Carbon In Lakes Across An Elevational Gradient From The Mountains To The Sea, Kyle Juetten, Angela L. Strecker, Aaron Harrison, Zachary Landram, Warren J. De Bruyn, Catherine D. Clark
Biology, Chemistry, and Environmental Sciences Faculty Articles and Research
Dissolved organic matter (DOM) in lakes across elevation gradients is a complex function of topography, climate, vegetation coverage, land use, and lake properties. To examine sources and processing of DOM from sea level to mountain lakes (3–1,574 m), we measured dissolved organic carbon (DOC) concentrations and chromophoric dissolved organic matter (CDOM) optical properties, lake characteristics, and water quality parameters in 62 freshwater lakes in the Pacific Northwest, USA. Higher elevation lakes had lower DOC concentrations and absorbance. These lakes had higher forest cover and minimal wetlands in their watershed, in addition to low nutrients, water temperatures, and chlorophyll a in …
Evaluating The Impact Of Submarine Groundwater Discharge On Nutrients And Trace Elements In Coastal Systems: The Examples Of The Tuckean Swamp (Australia) And The Mississippi Sound (Usa), Amy Moody
Dissertations
Submarine groundwater discharge (SGD) is the advective flow of both fresh terrestrial groundwater and recirculating seawater through aquifer sediments, which is released into the coastal ocean. In this dissertation, I evaluated the impact of SGD on the distributions and input of trace metals and nutrients. In the Tuckean Swamp, an estuary in Australia dominated by coastal acid sulfate soils, I determined the impact of groundwater on Ba and U during the flood season, when the local aquifer is flushed out after a rapid increase in water table elevation. For Ba and U, groundwater contributed up to 18 and 66 % …
Kinetics, Products, And Brown Carbon Formation By Aqueous-Phase Reactions Of Glycolaldehyde With Atmospheric Amines And Ammonium Sulfate (Raw Data), David O. De Haan, Alyssa A. Rodriguez, Michael A. Rafla, Hannah G. Welsh, Elyse A. Pennington, Jason R. Casar, Lelia N. Hawkins, Natalie G. Jimenez, Alexia De Loera, Devoun R. Stewart, Antonio Rojas, Matthew-Khoa Tran, Peng Lin, Alexander Laskin, Paola Formenti, Mathieu Cazaunau, Edouard Pangui, Jean-François Doussin
Kinetics, Products, And Brown Carbon Formation By Aqueous-Phase Reactions Of Glycolaldehyde With Atmospheric Amines And Ammonium Sulfate (Raw Data), David O. De Haan, Alyssa A. Rodriguez, Michael A. Rafla, Hannah G. Welsh, Elyse A. Pennington, Jason R. Casar, Lelia N. Hawkins, Natalie G. Jimenez, Alexia De Loera, Devoun R. Stewart, Antonio Rojas, Matthew-Khoa Tran, Peng Lin, Alexander Laskin, Paola Formenti, Mathieu Cazaunau, Edouard Pangui, Jean-François Doussin
Chemistry and Biochemistry: Faculty Scholarship
The zipped data files are in the following formats: Metadata: Word documents (.docx), Chamber data: Excel spreadsheets (.xlsx) and European Data Format files (.edf), organized by experiment number and instrumentation. “CAPS” files contain cavity attenuated phase shift (CAPS) extinction and scattering data; “SMPS” files contain scanning mobility particle sizing aerosol number and aerosol mass data.
Understanding Biogeochemical And Physical Controls On Methane Air-Sea Exchange Fluxes In The Pacific Ocean, Sarah Raney
Understanding Biogeochemical And Physical Controls On Methane Air-Sea Exchange Fluxes In The Pacific Ocean, Sarah Raney
Master's Theses
Methane and trace element samples were collected on GEOTRACES GP15 Pacific Meridional Transect (PMT) cruise conducted between the Aleutian Islands (57 °N) and Tahiti (20 °S) from September to November 2018. Uncertainty in methane air-sea exchange fluxes was determined using a propagation of errors approach. Fluxes ranged from -0.88 to 4.9 µmol CH4 m-2 d-1. Average CH4 flux along the Alaskan margin was 2.2 ± 2.9 µmol CH4 m-2 d-1. Methane fluxes decreased moving southward and increased to their open ocean maximum around 20 °N before declining in equatorial waters. Near …
Evaluating Alternative Ebullition Models For Predicting Peatland Methane Emission And Its Pathways Via Data–Model Fusion, Shuang Ma, Lifen Jiang, Rachel M. Wilson, Jeff P. Chanton, Scott Bridgham, Shuli Niu, Colleen M. Iversen, Avni Malhotra, Jiang Jiang, Xingjie Lu, Yuanyuan Huang, Jason Keller, Xiaofeng Xu, Daniel M. Ricciuto, Paul J. Hanson, Yiqi Luo
Evaluating Alternative Ebullition Models For Predicting Peatland Methane Emission And Its Pathways Via Data–Model Fusion, Shuang Ma, Lifen Jiang, Rachel M. Wilson, Jeff P. Chanton, Scott Bridgham, Shuli Niu, Colleen M. Iversen, Avni Malhotra, Jiang Jiang, Xingjie Lu, Yuanyuan Huang, Jason Keller, Xiaofeng Xu, Daniel M. Ricciuto, Paul J. Hanson, Yiqi Luo
Biology, Chemistry, and Environmental Sciences Faculty Articles and Research
Understanding the dynamics of peatland methane (CH4) emissions and quantifying sources of uncertainty in estimating peatland CH4 emissions are critical for mitigating climate change. The relative contributions of CH4 emission pathways through ebullition, plant-mediated transport, and diffusion, together with their different transport rates and vulnerability to oxidation, determine the quantity of CH4 to be oxidized before leaving the soil. Notwithstanding their importance, the relative contributions of the emission pathways are highly uncertain. In particular, the ebullition process is more uncertain and can lead to large uncertainties in modeled CH4 emissions. To improve model simulations of CH4 emission and its pathways, …
Odu’S Peter Bernath Participates In Study That Reveals Damage To Ozone Layer From Extreme Wildfires, Tiffany Whitfield
Odu’S Peter Bernath Participates In Study That Reveals Damage To Ozone Layer From Extreme Wildfires, Tiffany Whitfield
News Items
No abstract provided.
Insights Into The Deglacial Variability Of Phytoplankton Community Structure In The Eastern Equatorial Pacific Ocean Using [231Pa/230Th]Xs And Opal-Carbonate Fluxes, Danielle Schimmenti, Franco Marcantonio, Christopher T. Hayes, Jennifer Hertzberg, Matthew Schmidt, John Sarao
Insights Into The Deglacial Variability Of Phytoplankton Community Structure In The Eastern Equatorial Pacific Ocean Using [231Pa/230Th]Xs And Opal-Carbonate Fluxes, Danielle Schimmenti, Franco Marcantonio, Christopher T. Hayes, Jennifer Hertzberg, Matthew Schmidt, John Sarao
OES Faculty Publications
Fully and accurately reconstructing changes in oceanic productivity and carbon export and their controls is critical to determining the efficiency of the biological pump and its role in the global carbon cycle through time, particularly in modern CO2 source regions like the eastern equatorial Pacific (EEP). Here we present new high-resolution records of sedimentary 230Th-normalized opal and nannofossil carbonate fluxes and [231Pa/230Th]xs ratios from site MV1014-02-17JC in the Panama Basin. We find that, across the last deglaciation, phytoplankton community structure is driven by changing patterns of nutrient (nitrate, iron, and silica) availability which, in …
Calcification, Dissolution And Test Properties Of Modern Planktonic Foraminifera From The Central Atlantic Ocean, Stergios D. Zarkogiannis, Shinya Iwasaki, James William Buchanan Rae, Matthew W. Schmidt, P. Graham Mortyn, George Kontakiotis, Jennifer E. Hertzberg, Rosalind E.M. Rickaby
Calcification, Dissolution And Test Properties Of Modern Planktonic Foraminifera From The Central Atlantic Ocean, Stergios D. Zarkogiannis, Shinya Iwasaki, James William Buchanan Rae, Matthew W. Schmidt, P. Graham Mortyn, George Kontakiotis, Jennifer E. Hertzberg, Rosalind E.M. Rickaby
OES Faculty Publications
The mass of well-preserved calcite in planktonic foraminifera shells provides an indication of the calcification potential of the surface ocean. Here we report the shell weight of 8 different abundant planktonic foraminifera species from a set of core-top sediments along the Mid-Atlantic Ridge. The analyses showed that near the equator, foraminifera shells of equivalent size weigh on average 1/3 less than those from the middle latitudes. The carbonate preservation state of the samples was assessed by high resolution X-ray microcomputed tomographic analyses of Globigerinoides ruber and Globorotalia truncatulinoides specimens. The specimen preservation was deemed good and does not overall explain …
Indoor Air Quality Through The Lens Of Outdoor Atmospheric Chemistry, Jonathan P.D. Abbatt, Douglas B. Collins
Indoor Air Quality Through The Lens Of Outdoor Atmospheric Chemistry, Jonathan P.D. Abbatt, Douglas B. Collins
Faculty Contributions to Books
Outdoor atmospheric chemistry and air quality have been the topic of research that intensified in earnest around the mid-20th century, while indoor air quality research has only been a key focus of chemical researchers over the last 30 years. Examining practices and approaches employed in the outdoor atmospheric chemistry research enterprise provides an additional viewpoint from which we can chart new paths to increase scientific understanding of indoor chemistry. This chapter explores our understanding of primary chemical sources, homogeneous and multiphase reactivity, gas-surface partitioning, and the coupling between the chemistry and dynamics of indoor air through the lens of …
The Significance Of A New 11,000-Year Volcanic Record From The South Pole And Inferences From Comparisons With Other Volcanic Records, Derek Lee Brandis
The Significance Of A New 11,000-Year Volcanic Record From The South Pole And Inferences From Comparisons With Other Volcanic Records, Derek Lee Brandis
Electronic Theses and Dissertations
Snow accumulation at the polar regions of the planet preserves chemical substances from the atmosphere creating natural archives. Records of the atmospheric environment including atmospheric chemical composition and the climate can be reconstructed from ice cores from the polar ice sheets. Sulfur emitted by explosive volcanic eruptions is preserved as sulfate in polar snow and can be used to reconstruct the record of volcanic eruptions. Since large volcanic eruptions impact the environment and climate, records of volcanic eruptions from ice cores can help us to study and understand climate change and model the future climate environment. A 1750-m ice core …
The Influence Of Hydrogen Peroxide On The Enrichment Of Fe(Iii) Reducing Bacteria From Acid Mine Drainage, Susami Seth
The Influence Of Hydrogen Peroxide On The Enrichment Of Fe(Iii) Reducing Bacteria From Acid Mine Drainage, Susami Seth
Williams Honors College, Honors Research Projects
It is hypothesized that the ocean of Europa, a Jupiter moon, hosts bacteria on its oceanic floor. Understanding how Fe(III) reducing bacteria (FeRB) from AMD utilize organic materials within its surrounding environment outlines how FeRB could thrive and tolerate extreme conditions. FeRB are known to tolerate metals and highly reactive oxidants species (ROS), but in this experiment, H2O2 was the experimental factor to further test FeRB tolerance. H2O2 is a common ROS and is damaging to living material such as proteins, DNA, and RNA. A range of H2O2 concentrations were fed …
On The Stratospheric Chemistry Of Midlatitude Wildfire Smoke, Susan Soloman, Kimberlee Dube, Kane Stone, Pengfei Yu, Doug Kinnison, Owen B. Toon, Susan E. Strahan, Karen H. Rosenlof, Robert Portmann, Sean Davis, William Randel, Peter Bernath, Chris Boone, Charles G. Bardeen, Adam Bourassa, Daniel Zawada, Doug Degenstein
On The Stratospheric Chemistry Of Midlatitude Wildfire Smoke, Susan Soloman, Kimberlee Dube, Kane Stone, Pengfei Yu, Doug Kinnison, Owen B. Toon, Susan E. Strahan, Karen H. Rosenlof, Robert Portmann, Sean Davis, William Randel, Peter Bernath, Chris Boone, Charles G. Bardeen, Adam Bourassa, Daniel Zawada, Doug Degenstein
Chemistry & Biochemistry Faculty Publications
Massive Australian wildfires lofted smoke directly into the stratosphere in the austral summer of 2019/20. The smoke led to increases in optical extinction throughout the midlatitudes of the southern hemisphere that rivalled substantial volcanic perturbations. Previous studies have assumed that the smoke became coated with sulfuric acid and water and would deplete the ozone layer through heterogeneous chemistry on those surfaces, as is routinely observed following volcanic enhancements of the stratospheric sulfate layer. Here, observations of extinction and reactive nitrogen species from multiple independent satellites that sampled the smoke region are compared to one another and to model calculations. The …