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Full-Text Articles in Physical Sciences and Mathematics
Coil-To-Bridge Transitions Of Self-Assembled Water Chains Observed In A Nanoscopic Meniscus, Byung I. Kim, Ryan D. Boehm, Harrison Agrusa
Coil-To-Bridge Transitions Of Self-Assembled Water Chains Observed In A Nanoscopic Meniscus, Byung I. Kim, Ryan D. Boehm, Harrison Agrusa
Physics Faculty Publications and Presentations
Ten downward portions in the large oscillatory force–distance curve reported earlier are analyzed to understand a nanoscale water meniscus confined between a sharp probe and a flat substrate in air. The sigmoidal shape of each portion leads to the assumption that the meniscus is made up of n independent transitions of two states: one for a coil state and the other for a bridge state. The analysis reveals that each downward portion occurs due to a coil-to-bridge transition of n self-assembled water chains whose length ranges between 197 and 383 chain units. The transition provides novel insights into water’s unique …
Mxenes As Flow Electrodes For Capacitive Deionization Of Wastewater, Naqsh E. Mansoor
Mxenes As Flow Electrodes For Capacitive Deionization Of Wastewater, Naqsh E. Mansoor
Boise State University Theses and Dissertations
The energy-water nexus poses an integrated research challenge, while opening up an opportunity space for the development of energy efficient technologies for water remediation. Capacitive Deionization (CDI) is an upcoming reclamation technology that uses a small applied voltage applied across electrodes to electrophoretically remove dissolved ionic impurities from wastewater streams. Similar to a supercapacitor, the ions are stored in the electric double layer of the electrodes. Reversing the polarity of applied voltage enables recovery of the removed ionic impurities, allowing for recycling and reuse. Simultaneous materials recovery and water reclamation makes CDI energy efficient and resource conservative, with potential to …
Continuous Snow Water Equivalent Measurements With Ultra-Wideband Radar: Towards A New Generation Of Real-Time Automated Snow Sensor Arrays, Mark Edward Robertson
Continuous Snow Water Equivalent Measurements With Ultra-Wideband Radar: Towards A New Generation Of Real-Time Automated Snow Sensor Arrays, Mark Edward Robertson
Boise State University Theses and Dissertations
Snow accounts for the majority of precipitation in many areas of the Western United States, and accurate measurements of the amount of water contained in the snowpack, known as snow water equivalent (SWE), are therefore important for water resource managers. The National Resources Conservation Service Snow Telemetry (SNOTEL) sites are the current standard remote measurement of SWE, with approximately 800 sites across the Western United States. Measurements at these sites are made by snow pillows, which weigh the overburden pressure of a snowpack, and are relatively expensive to install and maintain. Spring runoff is modeled using a 30-year average of …
Direct Observation Of Self-Assembled Chain-Like Water Structures In A Nanoscopic Water Meniscus, Byung I. Kim, Ryan D. Boehm, Jeremy R. Bonander
Direct Observation Of Self-Assembled Chain-Like Water Structures In A Nanoscopic Water Meniscus, Byung I. Kim, Ryan D. Boehm, Jeremy R. Bonander
Physics Faculty Publications and Presentations
Sawtooth-like oscillatory forces generated by water molecules confined between two oxidized silicon surfaces were observed using a cantilever-based optical interfacial force microscope when the two surfaces approached each other in ambient environments. The humidity-dependent oscillatory amplitude and periodicity were 3-12 nN and 3-4 water diameters, respectively. Half of each period was matched with a freely jointed chain model, possibly suggesting that the confined water behaved like a bundle of water chains. The analysis also indicated that water molecules self-assembled to form chain-like structures in a nanoscopic meniscus between two hydrophilic surfaces in air. From the friction force data measured simultaneously, …