Physical Sciences and Mathematics Commons^™

Nanoparticles And The Environment: Biopolymer Grafted Cellulose And Screen-Printed Carbon Nanotube Composites, Dominique Henry Porcincula

Master's Theses

A host of environmental issues will define the state of the environment in the 21^st century, with plastic pollution and water shortages among them. While solutions to these problems require large-scale, multipronged solutions, one way we can address them is through material innovation and the use of nanoparticles.

In the first project, we address the issue of plastic pollution by creating nanocomposites of biodegradable polymers (PLA and PCL) with cellulose nanofibrils. Here, PLA and PCL are grafted from the surface of cellulose nanofibrils via ring-opening polymerization of cyclic ester monomers. Polymer-grafted cellulose (PGC) is characterized with structural analysis, solubility …

Research And Review Of Polymethyl-Methacrylate Copolymers In The Development Of Enhanced Pharmaceutical Delivery Systems, Jake Dyess

Senior Honors Theses

The following thesis shall primarily explore the current research regarding the implementation of modifiable microscopic and nanoscopic polymer particles as novel pharmaceutical delivery systems. Polymethacrylate-based copolymers, such as Eudragit^TM, are sensitive to alterations in pH levels, becoming increasingly more soluble in response to an increase in pH. The selective solubility and modifiable nature of these polymers allows for greater flexibility of treatment options for patients (Patra et al., 2017). The wide range of functionality of polymethacrylate (PMA) may provide solutions to challenges relating to the current treatment and therapy of certain conditions. Research indicates that PMA based micro- …

Tunable Surface Interactions In Adsorbing Polymer Solutions, Sorour Hosseini

Open Access Theses & Dissertations

A simple formalism is suggested, to calculate the most likely configuration of a finite polymer, between two surfaces on which the monomers can adsorb. Grafted polymers typically enhance the stability of colloidal dispersions, via the long ranged steric repulsion due to the overlap of their polymer brushes, which can be thicker that the typical range of the DLVO interactions. However, if the polymers are adsorbing on the colloidal surfaces, there is the possibility of bridge formation between particles and therefore long-range attractions are induced (a procedure commonly used for the flocculation of colloidal suspensions). The two effects are competing and …

A Comparison Study Of Two Synthesis Methods For Polymer Of Intrinsic Microporosity 1 (Pim-1), Conor S. Perry

Materials Engineering

Polymers of Intrinsic Microporosity (PIMs) are an emerging polymeric material class for molecular sieving applications. This study focuses on PIM-1, an alternating copolymer of 5,5’,6,6’-tetrahydroxy-3,3’,3,3’-tetramethyl-1,1’-spirobisindane and tetrafluoroterephthalonitrile synthesized via nucleophilic aromatic substitution. PIM-1 been widely studied as a gas separating material and filtering membrane, but in this case, it is studied as a battery separator material. PIM-1’s microporous (pore diameters less than 2 nm) structure allows smaller favorable ions to transport while preventing larger ions and compounds from transporting. Two synthesis methods, round bottom flask synthesis and ball mill synthesis, of PIM-1 are compared to see any improved characteristics. The …

My Italian Connections: Otto Vogl In Italy, Otto Vogl, Gerald S. Kirshenbaum

Emeritus Faculty Author Gallery

This document describes Otto Vogl's work in Italy. From 1975, Vogl served for 3 years as the Chairman of the Scientific Advisory Committee to the President Italo Trapasso of the Plastic Materials Company of Montedison SA, Milan, Italy. He was assigned to restructure the research activities and to organize the Research Division. He was responsible for the appointment of DiDrusco as the Vice President of Research and Paolo Galli as the Director of Research at the company’s facilities in Ferrara. Within a year of Vogl’s reorganization of the research organization the high yield catalyst for the polymerization of propylene was …

Anhang: Auszüge Aus Dem Späteren Leben Von Professor Dr. Otto Vogl, Otto Vogl

Emeritus Faculty Author Gallery

No abstract provided.

My Italian Connections: Otto Vogl In Italy, Otto Vogl, Gerald S. Kirshenbaum

Otto Vogl

This document describes Otto Vogl's work in Italy. From 1975, Vogl served for 3 years as the Chairman of the Scientific Advisory Committee to the President Italo Trapasso of the Plastic Materials Company of Montedison SA, Milan, Italy. He was assigned to restructure the research activities and to organize the Research Division. He was responsible for the appointment of DiDrusco as the Vice President of Research and Paolo Galli as the Director of Research at the company’s facilities in Ferrara. Within a year of Vogl’s reorganization of the research organization the high yield catalyst for the polymerization of propylene was …

Anhang: Auszüge Aus Dem Späteren Leben Von Professor Dr. Otto Vogl, Otto Vogl

Otto Vogl

No abstract provided.

Book I, Otto Vogl: Papers And Patents, 1948-1970, Jane C. Vogl

Emeritus Faculty Author Gallery

Books I-XII include citations to Otto Vogl's publications and patents. Printed versions of these twelve volumes are also available in the Integrated Sciences and Engineering Library of the University of Massachusetts in Amherst. MA, Lederle Graduate Research Center. The printed volumes include the full reprints of all cited publications.

Book I, Otto Vogl: Papers And Patents, 1948-1970, Jane C. Vogl

Otto Vogl

Books I-XII include citations to Otto Vogl's publications and patents. Printed versions of these twelve volumes are also available in the Integrated Sciences and Engineering Library of the University of Massachusetts in Amherst. MA, Lederle Graduate Research Center. The printed volumes include the full reprints of all cited publications.

Book Ii, Otto Vogl: Papers And Patents, 1970-1977, Jane C. Vogl

Emeritus Faculty Author Gallery

Books I-XII include citations to Otto Vogl's publications and patents. Printed versions of these twelve volumes are also available in the Integrated Sciences and Engineering Library of the University of Massachusetts in Amherst. MA, Lederle Graduate Research Center. The printed volumes include the full reprints of all cited publications.

Book Ii, Otto Vogl: Papers And Patents, 1970-1977, Jane C. Vogl

Otto Vogl

Books I-XII include citations to Otto Vogl's publications and patents. Printed versions of these twelve volumes are also available in the Integrated Sciences and Engineering Library of the University of Massachusetts in Amherst. MA, Lederle Graduate Research Center. The printed volumes include the full reprints of all cited publications.

Book Iii, Otto Vogl: Publications, 1977-1979, Jane C. Vogl

Emeritus Faculty Author Gallery

Books I-XII include citations to Otto Vogl's publications and patents. Printed versions of these twelve volumes are also available in the Integrated Sciences and Engineering Library of the University of Massachusetts in Amherst. MA, Lederle Graduate Research Center. The printed volumes include the full reprints of all cited publications.

Book Iii, Otto Vogl: Publications, 1977-1979, Jane C. Vogl

Otto Vogl

Books I-XII include citations to Otto Vogl's publications and patents. Printed versions of these twelve volumes are also available in the Integrated Sciences and Engineering Library of the University of Massachusetts in Amherst. MA, Lederle Graduate Research Center. The printed volumes include the full reprints of all cited publications.

Book Iv, Otto Vogl: Publications, 1979-1981, Jane C. Vogl

Emeritus Faculty Author Gallery

Books I-XII include citations to Otto Vogl's publications and patents. Printed versions of these twelve volumes are also available in the Integrated Sciences and Engineering Library of the University of Massachusetts in Amherst. MA, Lederle Graduate Research Center. The printed volumes include the full reprints of all cited publications.

Book Iv, Otto Vogl: Publications, 1979-1981, Jane C. Vogl

Otto Vogl

Books I-XII include citations to Otto Vogl's publications and patents. Printed versions of these twelve volumes are also available in the Integrated Sciences and Engineering Library of the University of Massachusetts in Amherst. MA, Lederle Graduate Research Center. The printed volumes include the full reprints of all cited publications.

Book V, Otto Vogl: Publications, 1981-1984, Jane C. Vogl

Emeritus Faculty Author Gallery

Books I-XII include citations to Otto Vogl's publications and patents. Printed versions of these twelve volumes are also available in the Integrated Sciences and Engineering Library of the University of Massachusetts in Amherst. MA, Lederle Graduate Research Center. The printed volumes include the full reprints of all cited publications.

Book V, Otto Vogl: Publications, 1981-1984, Jane C. Vogl

Otto Vogl

Books I-XII include citations to Otto Vogl's publications and patents. Printed versions of these twelve volumes are also available in the Integrated Sciences and Engineering Library of the University of Massachusetts in Amherst. MA, Lederle Graduate Research Center. The printed volumes include the full reprints of all cited publications.

Book Vi, Otto Vogl: Publications, 1984-1986, Jane C. Vogl

Emeritus Faculty Author Gallery

Books I-XII include citations to Otto Vogl's publications and patents. Printed versions of these twelve volumes are also available in the Integrated Sciences and Engineering Library of the University of Massachusetts in Amherst. MA, Lederle Graduate Research Center. The printed volumes include the full reprints of all cited publications.

Book Vi, Otto Vogl: Publications, 1984-1986, Jane C. Vogl

Otto Vogl

Books I-XII include citations to Otto Vogl's publications and patents. Printed versions of these twelve volumes are also available in the Integrated Sciences and Engineering Library of the University of Massachusetts in Amherst. MA, Lederle Graduate Research Center. The printed volumes include the full reprints of all cited publications.

Book Vii, Otto Vogl: Publications, 1987-1989, Jane C. Vogl

Emeritus Faculty Author Gallery

Books I-XII include citations to Otto Vogl's publications and patents. Printed versions of these twelve volumes are also available in the Integrated Sciences and Engineering Library of the University of Massachusetts in Amherst. MA, Lederle Graduate Research Center. The printed volumes include the full reprints of all cited publications.

Book Vii, Otto Vogl: Publications, 1987-1989, Jane C. Vogl

Otto Vogl

Books I-XII include citations to Otto Vogl's publications and patents. Printed versions of these twelve volumes are also available in the Integrated Sciences and Engineering Library of the University of Massachusetts in Amherst. MA, Lederle Graduate Research Center. The printed volumes include the full reprints of all cited publications.

Book Viii, Otto Vogl: Publications, 1989-1992, Jane C. Vogl

Emeritus Faculty Author Gallery

Books I-XII include citations to Otto Vogl's publications and patents. Printed versions of these twelve volumes are also available in the Integrated Sciences and Engineering Library of the University of Massachusetts in Amherst. MA, Lederle Graduate Research Center. The printed volumes include the full reprints of all cited publications.

Book Viii, Otto Vogl: Publications, 1989-1992, Jane C. Vogl

Otto Vogl

Books I-XII include citations to Otto Vogl's publications and patents. Printed versions of these twelve volumes are also available in the Integrated Sciences and Engineering Library of the University of Massachusetts in Amherst. MA, Lederle Graduate Research Center. The printed volumes include the full reprints of all cited publications.

Book Ix, Otto Vogl: Publications, 1993-1995, Jane C. Vogl

Emeritus Faculty Author Gallery

Books I-XII include citations to Otto Vogl's publications and patents. Printed versions of these twelve volumes are also available in the Integrated Sciences and Engineering Library of the University of Massachusetts in Amherst. MA, Lederle Graduate Research Center. The printed volumes include the full reprints of all cited publications.

Book Ix, Otto Vogl: Publications, 1993-1995, Jane C. Vogl

Otto Vogl

Books I-XII include citations to Otto Vogl's publications and patents. Printed versions of these twelve volumes are also available in the Integrated Sciences and Engineering Library of the University of Massachusetts in Amherst. MA, Lederle Graduate Research Center. The printed volumes include the full reprints of all cited publications.

Book X, Otto Vogl: Publications, 1996-1998, Jane C. Vogl

Emeritus Faculty Author Gallery

Books I-XII include citations to Otto Vogl's publications and patents. Printed versions of these twelve volumes are also available in the Integrated Sciences and Engineering Library of the University of Massachusetts in Amherst. MA, Lederle Graduate Research Center. The printed volumes include the full reprints of all cited publications.

Book X, Otto Vogl: Publications, 1996-1998, Jane C. Vogl

Otto Vogl

Books I-XII include citations to Otto Vogl's publications and patents. Printed versions of these twelve volumes are also available in the Integrated Sciences and Engineering Library of the University of Massachusetts in Amherst. MA, Lederle Graduate Research Center. The printed volumes include the full reprints of all cited publications.

Book Xi, Otto Vogl: Publications, 1999-2000, Jane C. Vogl

Emeritus Faculty Author Gallery

Books I-XII include citations to Otto Vogl's publications and patents. Printed versions of these twelve volumes are also available in the Integrated Sciences and Engineering Library of the University of Massachusetts in Amherst. MA, Lederle Graduate Research Center. The printed volumes include the full reprints of all cited publications.

Book Xi, Otto Vogl: Publications, 1999-2000, Jane C. Vogl

Otto Vogl

Books I-XII include citations to Otto Vogl's publications and patents. Printed versions of these twelve volumes are also available in the Integrated Sciences and Engineering Library of the University of Massachusetts in Amherst. MA, Lederle Graduate Research Center. The printed volumes include the full reprints of all cited publications.