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Full-Text Articles in Physical Sciences and Mathematics
A Potentiometric Method, A Convenient And Rapid Technique For Determination Of The Thermodynamics Of Ionization Reactions For Water, Weak Acids, And Some Slightly Soluble Salts In Aqueous Organic Mixed Solvents, Charanai Panichajakul
Theses and Dissertations
A potentiometric method which is devised to be rapid and convenient for determining ionization constants for water, weak acids (or bases), and certain solids in mixed solvents is described. The method has been applied to the determination of ionization for water, acetic acid, benzoic acid, and phenol and the solubility product constant for silver chloride in mixtures of water with methanol, ethanol, acetone, tetrahydrofuran, and p-dioxane containing from 0 to 70 mass percent organic co-solvent at several temperatures between 10 and 40°C. Results are used to study the thermodynamics of ionization in each mixture which is discussed relative to various …
Ionization Enhanced Diffusion, David Peak, J W. Corbett, J Bourgoin
Ionization Enhanced Diffusion, David Peak, J W. Corbett, J Bourgoin
All Physics Faculty Publications
The general three‐dimensional diffusion equations, along with the corresponding tensor diffusivities, are established for the normal ionization‐enhanced diffusion mechanism (which is equivalent to a general two‐channel diffusion mechanism) and for the Bourgoin mechanism, the latter being explicitly developed for the diamond lattice.