Physical Sciences and Mathematics Commons^™

Carbon Cycling And Critical Zone Dynamics In An Urbanized Karst Groundwater System, Amy Hourigan

Masters Theses & Specialist Projects

Increasing atmospheric CO₂ concentrations are correlated to rising global temperatures. Investigating the cumulative global carbon cycling processes is important to understand and quantify the global carbon cycle. By investigating basic geochemical parameters, EpCO₂, DIC, and δ¹³C_DIC, at four sites along Lost River Cave (LRC), in Bowling Green, Kentucky, concentrations, fluxes and sources of C dissolved in groundwater were determined. Urban karst groundwater systems, compared to more natural karst landscapes, typically exhibit widespread impervious, heat-absorbing surfaces, urban heat island effects, and increased anthropogenic groundwater inputs and localized CO₂ emissions. Carbonate hydrogeochemical …

An Adaptive Hazard Planning And Mitigation Framework For Responding To Urban Contamination In Karst Aquifer Systems, James Edward Troxell

Masters Theses & Specialist Projects

Environmental hazards in karst regions are damaging and often go unnoticed until an issue has escalated to a point of affecting life or property. The field of emergency and environmental contamination response lacks planning or preparedness focused on remediating groundwater contamination in karst systems. A lack of preplanning before an incident can lead to confusion, delayed response, and the inability to remediate the contaminant. Due to the rapid movement of contaminants through urban karst groundwater aquifers, an efficient response plan that leverages localized data in a GIS should be developed and maintained in order to adequately respond. The objective of …

Hydrogeochemical Characterization And Speleogenesis Of Sistema Huautla In Oaxaca, Mexico, Fernando Hernandez

Masters Theses & Specialist Projects

Sierra Mazateca, Mexico is home to Sistema Huautla, the deepest cave in the Western hemisphere with 1,560 meters of depth and 90 kilometers of passage, including 26 entrances distributed in a high-relief, karstified terrain, within the Sistema Huautla Karst Groundwater Basin. Exploration of the cave has generated research questions about its evolution and geomorphology given the different vadose and phreatic zones impacted by tectonic and incision processes. Dye traces during this study of Cueva de La Peña Colorada confirmed it is a fossil resurgence of the cave system. An additional cave, Cueva Elysium, was connected hydrologically in 2019, expanding the …

Monitoring And Evaluating The Influences Of Class V Injection Wells On Urban Karst Hydrology, James Adam Shelley

Masters Theses & Specialist Projects

The response of a karst aquifer to storm events is often faster and more severe than that of a non-karst aquifer. This distinction is often problematic for planners and municipalities, because karst flooding does not typically occur along perennial water courses; thus, traditional flood management strategies are usually ineffective. The City of Bowling Green (CoBG), Kentucky is a representative example of an area plagued by karst flooding. The CoBG, is an urban karst area (UKA), that uses Class V Injection Wells to lessen the severity of flooding. The overall effectiveness, siting, and flooding impact of Injection Wells in UKA’s is …

Evaluating The Influences Of Karst Hydrogeology On Freshwater Harmful Algal Blooms In Kentucky Lakes, Robert T. Schaefer

Masters Theses & Specialist Projects

A problem exists in Nolin River Lake and Rough River Lake in Kentucky, due to the increasing prevalence of cyanobacterial-based harmful algal blooms (CyanoHABs) and the threats they pose to local communities. These lakes were developed as artificial reservoirs from embankment. Further complicating the issue, the lakes are located within a heavily karstified region and there exists no plan or method currently for monitoring or managing CyanoHABs in a karst region with regard to groundwater inputs to the lake systems or their tributaries. A mixture of techniques and analysis methods was used to determine the best way to monitor and …

Carbon Cycling Dynamics Inferred From Carbon Isotope Sourcing In A Mid-Latitude Karst-Influenced River, Kegan N. Mcclanahan

Masters Theses & Specialist Projects

As ever-increasing levels of carbon dioxide alter the chemistry of the Earth’s atmosphere, understanding the global carbon cycle becomes increasingly important. A particularly important component is the riverine carbon cycle, as rivers are the primary conduits for dissolved inorganic carbon from terrestrial watersheds to ocean basins. Stable carbon isotopes (13C/12C) were collected weekly and input into the mixing model IsoSource to delineate seasonal carbon sourcing along two nested basins in the upper Green River System, Kentucky. In the more siliciclastic upstream catchment, dissolved inorganic carbon (DIC) was primarily derived from soil respiration (34%). Groundwater dissolving carbonate bedrock and carbonate dissolution/precipitation …

Addressing Water Resource Issues In Barbados Through An Isotopic And Atmospheric Characterization Of Precipitation Variability, Veronica Hall

Masters Theses & Specialist Projects

Numerous studies have analyzed isotopic variation of meteoric and dripwater in karst environments for paleoclimate reconstructions or aquifer recharge capacity. What is poorly understood is how the isotopic signal of δ¹⁸O and δ²H is transferred through the hydrologic cycle based upon storm type, frequency, intensity, and teleconnection activity in the tropical karst areas. At Harrison’s Cave, Barbados, a Hobo Onset event data logger was attached to a tipping bucket rain gauge to count the tips and record the total rainfall every 10 minutes. In the cave a Hobo data logger was used to record relative humidity …

The Hydrology Of The Carroll Cave-Toronto Springs System: Identifying And Examining Source Mixing Through Dye Tracing, Geochemical Monitoring, Seepage Runs, And Statistical Methods, Benjamin Verlinden Miller

Masters Theses & Specialist Projects

In karst areas relationships between activities occurring on the surface and the overall health of the subsurface environment are often highly interconnected. However, the complex nature of karst flow systems can often make identification of these connections difficult. Carroll Cave, a large stream cave system located in the central Missouri Ozarks, is known for its biological and speleological significance. A dye tracing project to delineate a Carroll Cave recharge area through dye tracing has identified an area of 18.5 km2 which contributes water to the cave. The water from Thunder River within Carroll Cave was positively traced to eight springs …

Vadose Zone Hydrology Near The Vicinity Of Edna's Dome, Mammoth Cave, Kentucky, Johnny Merideth

Masters Theses & Specialist Projects

This study examines the differences in key physical aqueous parameters at two different cave sites separated by only a few tens of meters. One site (FF) has a freefalling water component where water descends nearly 30 meters from the ceiling of a vertical shaft. The other location (WW) appears to have continuous water to rock contact as it descends to near the same level in the cave.

Water samples were collected at the two sites in two week intervals from May to August 2002. While both sites were proximal, they demonstrated very different behaviors, particularly during storm events. Differences in …

Simulation Modeling Of Karst Aquifer Conduit Evolution And Relations To Climate, John D. Broome

Masters Theses & Specialist Projects

ABSTRACT Karst regions of the world that receive relatively similar amounts of precipitation display a wide variety of landscapes. It has been suggested (Groves and Meiman, 2005) that climates exhibiting larger discrete storm events have more dissolving power and consequently higher rates of conduit growth than climates with more uniform precipitation distributions. To study this concept, a computer program “Cave Growth” was developed that modeled the growth of a cross-section of a cave passage under dynamic flow and chemical conditions. A series of 46 simulation datasets were created to represent different climatic conditions. These simulations had the same total annual …