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Full-Text Articles in Physical Sciences and Mathematics

Investigation Of Peptide-Dna Interactions: Synthesis, Characterization And Applications Of Lysyl-Fluorophenylalaninamides, Teresita T. Ortega Dec 1998

Investigation Of Peptide-Dna Interactions: Synthesis, Characterization And Applications Of Lysyl-Fluorophenylalaninamides, Teresita T. Ortega

Seton Hall University Dissertations and Theses (ETDs)

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Correlation Function Formulation For The State Selected Total Reaction Probability, Sophya Garashchuk, David J. Tannor Aug 1998

Correlation Function Formulation For The State Selected Total Reaction Probability, Sophya Garashchuk, David J. Tannor

Faculty Publications

Investigates the correlation function formulation for the state selected total reaction probability. Discussion of the wave packet propagation; Derivation of the correlation function expression for the N[sub alpha](E); Application of quantum-mechanical and Herman-Kluk propagation methods.


Role Of The Maillard Reaction In Aging Of Tissue Proteins: Advanced Glycation End Product-Dependent Increase In Imidazolium Cross-Links In Human Lens Proteins, Elisabeth Brinkmann Frye, Thorsten P. Degenhardt, Suzanne R. Thorpe, John W. Baynes Jul 1998

Role Of The Maillard Reaction In Aging Of Tissue Proteins: Advanced Glycation End Product-Dependent Increase In Imidazolium Cross-Links In Human Lens Proteins, Elisabeth Brinkmann Frye, Thorsten P. Degenhardt, Suzanne R. Thorpe, John W. Baynes

Faculty Publications

Dicarbonyl compounds such as glyoxal and methylglyoxal are reactive dicarbonyl intermediates in the nonenzymatic browning and cross-linking of proteins during the Maillard reaction. We describe here the quantification of glyoxal and methylglyoxal-derived imidazolium cross-links in tissue proteins. The imidazolium salt cross-links, glyoxal-lysine dimer (GOLD) and methylglyoxal-lysine dimer (MOLD), were measured by liquid chromatography/mass spectrometry and were present in lens protein at concentrations of 0. 02-0.2 and 0.1-0.8 mmol/mol of lysine, respectively. The lens concentrations of GOLD and MOLD correlated significantly with one another and also increased with lens age. GOLD and MOLD were present at significantly higher concentrations than the …


Quadratic Electro-Optic Effects In Bacteriorhodopsin: Measurement Of Γ(-Ω;0,0,Ω) In Dried Gelatin Thin Films, Mikio Yamazaki, Jerry Goodisman, Robert R. Birge Apr 1998

Quadratic Electro-Optic Effects In Bacteriorhodopsin: Measurement Of Γ(-Ω;0,0,Ω) In Dried Gelatin Thin Films, Mikio Yamazaki, Jerry Goodisman, Robert R. Birge

Chemistry - All Scholarship

Quadratic electro-optic effects (dc or low frequency Kerr effect) of bacteriorhodopsin dispersed in dried gelatin thin films are examined in the near resonance region at three wavelengths: 633, 647, and 676 nm. The films show relatively large quadratic electro-optic effects compared to other molecular dispersed systems. The purple membrane is fixed within the polymerized gelatin matrix, and we show that the electronic contribution to γ dominates over possible orientational contributions. At 676 nm. the quadratic electro-optic coefficient s1133( - ω;0,0,ω) is 6.7 × 10-20 m2/V2 and the third order nonlinear susceptibility X1133(3) …