Physical Sciences and Mathematics Commons^™

Improve The Low Energy Sensitivity Of The Hawc Observatory, Zhixiang Ren

Optical Science and Engineering ETDs

The high altitude water cherenkov gamma-ray observatory (HAWC) has been fully operational since March of 2015 in Mexico at 4,100 meters above sea level on the hillside of the Sierra Negra Volcano. It consists of an array of 300 water cherenkov detectors, each equipped with four photo-multiplier tubes. HAWC operates 24-hours per day with a wide field-of-view (FOV, ∼ 2 sr) and a high duty cycle (∼ 95%). These make it a powerful survey and monitoring experiment for mapping the gamma ray sky at very high energies (VHE, 100 GeV to 100 TeV) and to study sources with varying intensities. …

Mineralogy, Petrology, And Geochemistry Of The Unique Silica-Rich Ungrouped Achondrite Northwest Africa 11575, Mya Ann Habermann

Earth and Planetary Sciences ETDs

We report here on a unique, newly discovered, silica-rich ungrouped achondrite Northwest Africa 11575 (NWA 11575). NWA 11575 is one of four known silica-rich ungrouped achondrites, presenting evidence for igneous processes resulting in evolved compositions early in the history of the solar system. It is unique from the other silica-rich ungrouped achondrites in that it has pyroxene compositional trends matching those of lunar samples and martian meteorites; contains quartz and potassium feldspar; and contains oxygen, hydrogen, and chromium isotopes that are similar to those of LL chondrites. Together, these four silica-rich ungrouped achondrites provide evidence for evolved compositions resulting from …

Insights Into Fluid-Rock Interactions On The Cv3 Carbonaceous Chondrite Asteroid: The Complex Record In The Allende-Like Cv3 Chondrite, Nwa 2364., Jessica Marie Johnson

Earth and Planetary Sciences ETDs

The two subgroups of the CV3 chondrites, oxidized and reduced, contain primitive solar system materials that provide many insights into early solar system processes. Both subgroups record significant evidence of secondary alteration that has modified their primary characteristics. In this work, we have studied the petrography, mineralogy, and oxygen isotopic composition of the NWA 2364 CV3_OxA chondrite and a large lithic inclusion using SEM, electron microprobe, FIB/TEM, and laser fluorination oxygen isotope analyses in order to characterize their alteration histories in detail. The NWA 2364 host and lithic inclusion consist of chondrules, Calcium-Aluminum-rich Inclusions (CAIs), and fine-grained matrix. In …

Widespread, Prolonged Microbial Limestone Deposition And Large, Rapid Sulfur Isotope Excursions: A New Perspective On The Early Triassic From The Western U.S., Brad M. Jeffrey

Earth and Planetary Sciences ETDs

The Early Triassic records a ~5 My period of marine biological recovery following the end-Permian mass extinction (EPME, ~252 My). Global oceans were characterized by warm sea-surface temperatures (SSTs), widespread anoxia, and major perturbations to the carbon cycle, the collective result of repeated massive Siberian Traps eruptions and associated global climate feedbacks. Globally widespread microbial deposits (stromatolites, thrombolites) developed in shallow marine environments. Several marine isotope records (C, O, S, U) indicate repeated, large-magnitude shifts related to paleoceanographic events during the recovery of marine ecosystems following the EPME.

Chapter 1 describes and interprets a widespread (~400 km along strike) Smithian …

Transverse Anderson Localization In Optical Fibers: High-Quality Wave Transmission And Novel Lasing Applications, Behnam Abaie

Optical Science and Engineering ETDs

In this dissertation, transverse Anderson localization (TAL) of light mediated by disordered optical fibers is exploited for high-quality optical wave transmission and novel random lasing applications. En route, we first establish a powerful numerical platform for detailed investigation of TAL optical fibers (TALOF). Our approach is based on a modal perspective as opposed to beam propagation method (BPM) which was primarily used in the previous studies of TAL in disordered optical fibers. The versatile numerical tools developed in our simulations result in a potent methodology for simulation of TALOFs; the result is a fast and effective algorithm which can be …

Control Theory: The Double Pendulum Inverted On A Cart, Ian J P Crowe-Wright

Mathematics & Statistics ETDs

In this thesis the Double Pendulum Inverted on a Cart (DPIC) system is modeled using the Euler-Lagrange equation for the chosen Lagrangian, giving a second-order nonlinear system. This system can be approximated by a linear first-order system in which linear control theory can be used. The important definitions and theorems of linear control theory are stated and proved to allow them to be utilized on a linear version of the DPIC system. Controllability and eigenvalue placement for the linear system are shown using MATLAB. Linear Optimal control theory is likewise explained in this section and its uses are applied to …

A Plausible Resolution To Hilbert’S Failed Attempt To Unify Gravitation & Electromagnetism, Florentin Smarandache, Victor Christianto, Robert Neil Boyd

Branch Mathematics and Statistics Faculty and Staff Publications

In this paper, we explore the reasons why Hilbert’s axiomatic program to unify gravitation theory and electromagnetism failed and outline a plausible resolution of this problem. The latter is based on Gödel’s incompleteness theorem and Newton’s aether stream model.

Adaptive Parallelism For Coupled, Multithreaded Message-Passing Programs, Samuel K. Gutiérrez

Computer Science ETDs

Hybrid parallel programming models that combine message passing (MP) and shared- memory multithreading (MT) are becoming more popular, especially with applications requiring higher degrees of parallelism and scalability. Consequently, coupled parallel programs, those built via the integration of independently developed and optimized software libraries linked into a single application, increasingly comprise message-passing libraries with differing preferred degrees of threading, resulting in thread-level heterogeneity. Retroactively matching threading levels between independently developed and maintained libraries is difficult, and the challenge is exacerbated because contemporary middleware services provide only static scheduling policies over entire program executions, necessitating suboptimal, over-subscribed or under-subscribed, configurations. In …

Towards Scalable Characterization Of Noisy, Intermediate-Scale Quantum Information Processors, Travis Luke Scholten

Physics & Astronomy ETDs

In recent years, quantum information processors (QIPs) have grown from one or two qubits to tens of qubits. As a result, characterizing QIPs – measuring how well they work, and how they fail – has become much more challenging. The obstacles to characterizing today’s QIPs will grow even more difficult as QIPs grow from tens of qubits to hundreds, and enter what has been called the “noisy, intermediate-scale quantum” (NISQ) era. This thesis develops methods based on advanced statistics and machine learning algorithms to address the difficulties of “quantum character- ization, validation, and verification” (QCVV) of NISQ processors. In the …

Multi-Resolution Analysis Of Large Molecular Structures And Interactions, Kasra Manavi

Computer Science ETDs

Simulation of large molecular structures and their interactions has become a major component of modern biomolecular research. Methods to simulate these type of molecules span a wide array of resolutions, from all atom molecular dynamics to model interaction energetics to systems of linear equations to evaluate population kinetics. In recent years, there has been an acceleration of molecular structural information production, primarily from x-ray crystallography and electron microscopy. This data has provided modelers the ability to produce better representations of these molecular structures. The purpose of this research is to take advantage of this information to develop multi-resolution models for …

Learning Statistics Through Guided Block Play: A Pre-Curriculum In Statistical Literacy, Robert P. Giebitz

Organization, Information and Learning Sciences ETDs

Learning to use data to investigate the world and make decisions has become an essential skill for all citizens. Play and curiosity are powerful motivators for learning. Inquiry – the process of asking questions and seeking answers – can engage the natural curiosity of young learners and motivate early learning. Recent research in statistics education has shown that children as young as 4 and 5 years old can learn to collect, organize, and interpret data they acquire through observation, counting, and measuring in a process of guided inquiry. Guided block play has been used for over 100 years to enable …

Sedimentology And Stratigraphy Of Core Stl14: An Early Pleistocene-To-Present Paleoclimate Archive From Stoneman Lake, Arizona, Spencer Staley

Earth and Planetary Sciences ETDs

An 80 m lacustrine sediment core (STL14) from Stoneman Lake, Coconino County, Arizona, contains a sedimentary sequence of at least 1.5 million years, chronicling the complete history of basin infill and recording an extensive and high-resolution archive of climatic and hydrologic fluctuations. Lake levels in this small, internally-drained catchment are sensitive to changes in regional hydrologic balance. Consistent groundwater inflow, even during regionally dry episodes in the lake’s history, has prevented complete desiccation of the lake and sustained continuous lacustrine deposition except for one soil horizon. Multiproxy analysis of sedimentological indicators including lithofacies, color, wet bulk density, magnetic susceptibility, preliminary …

Use Of Sodium Dithionite For Groundwater Restoration Following Uranium In-Situ Recovery Mining At The Smith Ranch-Highalnd Site In Wyoming, Rose J. Harris

Earth and Planetary Sciences ETDs

Uranium in-situ recovery (ISR) is a subsurface aqueous mining technique used to extract uranium from sandstone roll-front deposits. After ISR mining, groundwater restoration is conducted to decrease concentrations of residual U(VI) and other contaminants leftover in the groundwater. Sodium dithionite, a strong chemical reductant, is being tested for use in groundwater restoration following uranium ISR at the Smith Ranch-Highland site in Wyoming. Sodium dithionite has been used to remediate chromium plumes by creating an in-situ permeable reactive barrier, but there has been no work using sodium dithionite for groundwater restoration following uranium ISR mining.

Laboratory batch and column experiments, and …

Criticality Assessments For Improving Algorithmic Robustness, Thomas B. Jones

Computer Science ETDs

Though computational models typically assume all program steps execute flawlessly, that does not imply all steps are equally important if a failure should occur. In the "Constrained Reliability Allocation" problem, sufficient resources are guaranteed for operations that prompt eventual program termination on failure, but those operations that only cause output errors are given a limited budget of some vital resource, insufficient to ensure correct operation for each of them.

In this dissertation, I present a novel representation of failures based on a combination of their timing and location combined with criticality assessments---a method used to predict the behavior of systems …

Development Of Copper-Catalyzed Suzuki-Miyaura Coupling Using Alkylboron Reagents And Nickel-Catalyzed Alkene Dicarbofunctionalization Reactions, Prakash Basnet

Chemistry and Chemical Biology ETDs

This thesis is divided into two parts. The first part deals with the development of copper-catalyzed Suzuki-Miyaura coupling of alkylboron reagents for the first time. In the second part, we will discuss the development of novel nickel-catalyzed alkene dicarbofunctionalization reactions.

Part I. Cross-coupling reactions are versatile tools to form new carbon-carbon bonds and are widely used in the synthesis of various drug molecules, natural products and materials. However, these reactions are typically catalyzed by palladium, an expensive and rare metal which makes the reaction unsustainable in long-terms. Additionally, palladium-catalyzed cross-coupling reactions with alkylorganometallic reagents suffer from side reactions due to …

Mantle-To-Surface Neotectonic Connections In The San Juan Mountains Documented By 3he/4he, Co2 Flux Meaurements, And Hydrochemical Analysis Of The Geothermal System Near Rico, Colorado, Benjamin D. Holt

Earth and Planetary Sciences ETDs

This project investigates the controls on geothermal fluids and their conduit systems which may account for high mantle helium components of geothermal fluids in intracratonic continental regions. The field laboratory is the western San Juan Mountains of southwestern Colorado where the structural setting and hydrochemistry of carbonic springs suggest potential connections among surface hot springs, fault networks, CO2 degassing, significant geothermal potential, young volcanic and plutonic rocks (< 7 Ma), and low-velocity upper mantle. The Rico Hot Springs have the highest mantle volatile component of any spring in Colorado with air-corrected values of 3He/4He = 5.88 RA indicating 73% mantle helium component. This near-MORB mantle helium value at Rico indicates that volatiles degassing from the mantle must be rapidly transmitted into the groundwater system along deep-seated faults such that accumulation of 4He from radiogenic crust has not swamped mantle-derived primordial 3He. Geologic features that are important for volatile transport and spring chemistry controls include a complex conduit system and fault network involving the Precambrian-cored Rico Dome, ~4 Ma intrusive rocks at Calico Peak and Priest Gulch, and a low-velocity upper mantle. Therefore, Rico and the surrounding region is a natural laboratory for studying geothermal fluid and mantle volatile pathways. Additional noble gas analyses and hydrochemistry data were gathered from regional springs and modeled via chemical geothermometers. New noble gas measurements from this study, paired with literature values, reveal highest air corrected 3He/4He at Rico (4.09-5.88 RA), Dunton (3.11-4.54 RA), Geyser Warm Spring (3.39 RA), and Paradise Warm Spring (2.72 RA). Water volume is dominated by meteoric fluids as shown by stable isotope data but hydrochemistry indicates high TDS, high CO2, and high He come from a geothermal fluid endmember. Variable mixing and water-rock interactions are processes that can explain chemistry variations between spatially proximal springs. CO2 flux measurements (up to 36.2 g/m2/hr) vary across structural features and demonstrate that the faults act as pathways for CO2 flux suggesting ongoing degassing. Overall, we find that local high mantle helium signature is localized directly above regions of lowest upper mantle velocity in the San Juan mantle anomaly and is derived from neotectonic mantle melts in those regions.

Post-Impact Light Vapor Incorporation During Lunar Formation Based On Triple Oxygen Isotopes, Erick J. Cano

Earth and Planetary Sciences ETDs

Initial triple oxygen isotope analyses of lunar samples showed them to be indistinguishable from Earth, which led to numerous papers aimed at explaining the similarities. Recent high-precision analyses suggested either a subtle enrichment in Δ'¹⁷O or virtually no difference between the Earth and Moon. Herein we expand on previous studies by correlating the triple oxygen isotope measurements with different lunar lithologies. We show that these data can be explained by mixing between a light vapor phase, generated during the Giant Impact, and the residual material from the proto-lunar impactor ‘Theia’. There is a general decrease in Δ'^{17 …}

Radionuclides In Rainwater And Their Impact On Background Radiation, Damien M. Milazzo

Earth and Planetary Sciences ETDs

Radioactive waste has accrued throughout the continental United States and in the Oceans surrounding the country. Significant quantities of the waste are poorly documented regarding their location and the radioisotopes contained in the waste. Locating the waste is not an easy matter, as its locations are not well documented, and its method of disposal may be covered with plants, soils, and sediments. A common tool used to locate the waste is a gamma spectrometer, which measure the gamma emissions spectrum of radionuclides. The effectiveness of this tool when utilized to locate gamma emitting waste may be reduced due to the …

Development Of Functional Chemical Probes For The Study Of Viscosity, Fe(Ii), And Ferroptosis And Photo-Triggered Drug Delivery, Yongyi Wei

Chemistry and Chemical Biology ETDs

Small molecule probes are useful tools for the study of biology. In particular, the dye derived fluorescence probes enable to spatiotemporally monitor the events of analytes of interest. The noninvasive feature is particularly attractive for the biological studies in live cells. The challenge is to develop chemical probes capable of detection of the analyte of interest with high specificity.

Toward this end, my Ph. D. study centers on the development of novel chemical probes for the study and understanding of the alternation of important cellar contents and substances and their functions and relationship between normal and disease states. In the …

The Compensation For Few Clusters In Clustered Randomized Trials With Binary Outcomes, Lily Stalter

Mathematics & Statistics ETDs

Cluster randomized trials are increasingly popular in epidemiological and medical research. When analyzing the data from such studies it is imperative that the hierarchical structure of the data be taken into account. Multilevel logistic regression is used to analyze clustered data with binary outcomes. Previous literature shows that a greater number of clusters is more important than a large number of subjects per cluster. This paper investigates if it is possible to compensate for the increased bias found for parameter estimates when the number of clusters is decreased. A simulation study was conducted where the absolute percent relative bias for …

Quantum Algorithms, Architecture, And Error Correction, Ciarán Ryan-Anderson

Physics & Astronomy ETDs

Quantum algorithms have the potential to provide exponential speedups over some of the best known classical algorithms. These speedups may enable quantum devices to solve currently intractable problems such as those in the fields of optimization, material science, chemistry, and biology. Thus, the realization of large-scale, reliable quantum-computers will likely have a significant impact on the world. For this reason, the focus of this dissertation is on the development of quantum-computing applications and robust, scalable quantum-architectures. I begin by presenting an overview of the language of quantum computation. I then, in joint work with Ojas Parekh, analyze the performance of …

How Hilbert’S Attempt To Unify Gravitation And Electromagnetism Failed Completely, And A Plausible Resolution, Victor Christianto, Florentin Smarandache, Robert N. Boyd

Branch Mathematics and Statistics Faculty and Staff Publications

In the present paper, these authors argue on actual reasons why Hilbert’s axiomatic program to unify gravitation theory and electromagnetism failed completely. An outline of plausible resolution of this problem is given here, based on: a) Gödel’s incompleteness theorem, b) Newton’s aether stream model. And in another paper we will present our calculation of receding Moon from Earth based on such a matter creation hypothesis. More experiments and observations are called to verify this new hypothesis, albeit it is inspired from Newton’s theory himself.

Dance Of Two Supermassive Binary Black Holes, Karishma Bansal

Shared Knowledge Conference

Black holes exist in a various range of masses ranging from stellar mass (~ 10 Solar Mass) to Supermassive black holes (SMBHs, million to billion Solar Mass). It is expected that as the separation between the black holes decreases, emission of gravitational waves will grow stronger, which makes binary black holes one of the most promising sources for gravitational radiation detection. Gravitational waves from merging stellar-mass black holes have recently been discovered by LIGO; however, we are yet to detect them from binary SMBHs. These massive black holes reside at the heart of most of the galaxies and when two …

High-Resolution Digital Surface Characterization Of The Rio Chama In New Mexico, Rowan L. Converse

Shared Knowledge Conference

Over the past eighty years, the Rio Chama, a major tributary of the Rio Grande in New Mexico, has been subject to significant disruption of historic hydrological flow regimes due to water use demands. In recent years, a multiagency management effort has been initiated to restore some measure of historic flow regimes in the 39.6 km congressionally designated Wild and Scenic stretch through the Rio Chama Canyon Wilderness. We collaborated with managers at the US Army Corps of Engineers to collect approximately 15,870 frames of 10cm resolution multispectral imagery of the 82 km stretch of the river between El Vado …

Are The Oxygen Isotope Values Of The Late Cretaceous Western Interior Seaway Different From The Open Ocean?, Camille H. Dwyer, Corinne Myers, Viorel Atudorei

Shared Knowledge Conference

The Western Interior Seaway (WIS) was a North American epicontinental sea that was connected to the open ocean through the passage of the northern Boreal Sea and the southern Tethys Sea from the early Albian (~113 million years ago) to the early Paleogene (~65 million years ago). The WIS began to recced and lost its connection to the southern Tethys Sea in the late Campanian (~72 million years ago). In the early Paleogene, the WIS dried up completely. The oxygen isotopic composition (δ18O) of benthic bivalves was measured from the upper Campanian and lower Maastrichtian (75 million years ago to …

Assessing Water Policy Implications Of The Changing Agriculture In New Mexico, Trevor A. Birt

Shared Knowledge Conference

Agriculture is the dominant water sector in New Mexico, responsible for more than 80% of water withdrawals in 2015 (USGS 2018). Water policy needs to be extremely adaptive and informed to meet the needs of not only farmers, but cities, industry and riparian uses. Since 1840, the U.S. Department of Agriculture (USDA) has conducted census surveys assessing all levels of agriculture. These data are physically published at the county, state, and national level on a 5-year cycle, detailing various material counts such as acreage, yields, and water usage, as well as socioeconomic estimates of farm costs, revenues, and hired workers. …

Plasmon-Enhanced Quadrupolar Transitions With Nanostructured Graphene, Stephen Sanders

Shared Knowledge Conference

Many important molecules have quadrupolar excitations which occur at much slower rates than the competing dipolar transitions and hence are termed forbidden. In this work, we propose a new approach to enhance quadrupolar transitions using graphene nanostructures. We provide a detailed investigation of the enhanced transition rate in the vicinity of graphene nanoislands and use rigorous computational methods to analyze how this quantity changes with the geometrical and material parameters of the nanoisland. To support these calculations we also provide a semi-analytic approach. Finally, we investigate the performance of arrays of graphene nanoribbons, which constitutes a suitable platform for the …

Genetic Algorithm Design Of Photonic Crystals For Energy-Efficient Ultrafast Laser Transmitters, Troy A. Hutchins-Delgado

Shared Knowledge Conference

Photonic crystals allow light to be controlled and manipulated such that novel photonic devices can be created. We are interested in using photonic crystals to increase the energy efficiency of our semiconductor whistle-geometry ring lasers. A photonic crystal will enable us to reduce the ring size, while maintaining confinement, thereby reducing its operating power. Photonic crystals can also exhibit slow light that will increase the interaction with the material. This will increase the gain, and therefore, lower the threshold for lasing to occur. Designing a photonic crystal for a particular application can be a challenge due to its number of …

Nonthermal Dark Matter From Early Matter Domination, Jacek Ksawery Osinski

Shared Knowledge Conference

Dark matter (DM) production in the early universe traditionally assumes a standard thermal history where the universe is in a radiation-dominated phase after the end of inflation until matter-radiation equality. However, the presence of additional scalar fields (which is a generic prediction of explicit string constructions) can lead to an epoch of early matter domination (EMD) that ends before the onset of big bang nucleosynthesis. Such an EMD phase has important cosmological consequences and renders thermal production of DM irrelevant. We present three scenarios for DM production involving an era of EMD: evaporation of primordial black holes into DM, DM …

Combined High-Speed Single Particle Tracking Of Membrane Proteins And Super-Resolution Of Membrane-Associated Structures, Hanieh Mazloom Farsibaf, Keith A. Lidke

Shared Knowledge Conference

Many experiments have shown that the diffusive motion of lipids and membrane proteins are slower on the cell surface than those in artificial lipid bilayers or blebs. One hypothesis that may partially explain this mystery is the effect of the cytoskeleton structures on the protein dynamics. A model proposed by Kusumi [1] is the Fence-Picket Model which describes the cell membrane as a set of compartment regions, each ~ 10 to 200 nm in size, created by direct or indirect interaction of lipids and proteins with actin filaments just below the membrane. To test this hypothesis, we have assembled a …