Physical Sciences and Mathematics Commons^™

Assessing Tennessee Landowners' Attitudes Toward Wild Hogs And Support For Control Options, Carlotta Anne Caplenor

Masters Theses

Wild hogs (Sus scrofa) are an invasive species with destructive habits, particularly rooting and wallowing, which can directly impact agricultural crops, pasture land, and water quality. Considering wild hogs are widely dispersed across the landscape, it is extremely difficult to control them. Moreover, disagreements can arise among different stakeholders over whether and how their population should be managed. The purpose of this study was to examine Tennessee landowners’ attitudes toward wild hogs, to compare acceptability of control methods, and to evaluate the factors significantly influencing public support for wild hog control regulations. Logistic regression was used to analyze …

Preliminary Investigation For The Development Of Surrogate Debris From Nuclear Detonations In Marine-Urban Environments, Adam G. Seybert

Masters Theses

No nuclear weapon has ever been detonated in a United States city. However, this also means the nuclear forensic community has no actual debris from which to develop analytical methods for source attribution, making the development of surrogate nuclear debris a vital undertaking. Moreover, the development of marine-urban debris presents an unusual challenge because unlike soil and urban structures, which remain compositionally consistent, the elemental composition of harbor and port waters fluctuates considerably due to natural phenomenon and human activity. Additionally, marine vessel composition and cargo can vary dramatically. While early US nuclear tests were carried out in shallow-water coastal …

Tagamajig: Image Recognition Via Crowdsourcing, Gregory Martin Simpson

Masters Theses

The University of Tennessee, Knoxville (UTK) Library possesses thousands of unlabeled gray-scale photographs from the Smoky Mountains circa the 1920s - 1940s. Their current method of identifying and labeling attributes of the photographs is to do so manually. This is problematic both because of the scale of the collection as well as the reliance on an individual's limited knowledge of the area's numerous landmarks.

In the past few years, similar dilemmas have been tackled via an approach known as crowd computing. Some examples include Floating Forests, in which users are asked to identify and mark kelp forests in satellite images, …

Three Body Interactions Of Rare Gas Solids Calculated Within The Einstein Model, Dan D'Andrea

Masters Theses

Three body interactions can become important in solids at higher pressures and densities as the molecules can come into close contact. At low temperatures, accurate studies of three body interactions in solids require averaging the three-body terms over the molecules' zero point motions. An efficient, but approximate, averaging approach is based on a polynomial approximation of the three-body term. The polynomial approximation can be developed as a function of the symmetry coordinates of a triangle displaced from its average geometry and also as a function of the Cartesian zero point displacements from each atom’s average position. The polynomial approximation approach …

Synthesis And Characterization Of Novel Ligand For Use On Rhodium Paddlewheel Complexes, Gavin J. Rustin

Masters Theses

Dirhodium (II) paddlewheel complexes have proven to be useful catalysts in many transformations including C-H insertions, cyclopropanation, and silane insertion reactions. One deficiency of these catalysts is the inability to modulate the enantioselectivity with reactive diazo compounds. One avenue for potential improvement of paddlewheel complexes is coordinating ligands in the axial site to increase enantioselectivity. The axial site has been occupied by various ligands including Nheterocyclic carbenes, nitrogen compounds, and phosphorous compounds. This work examines compounds that can be used as ligands on dirhodium complexes that have a pendant chain containing a dibenzyl phosphite and dibenzyl phosphate, both of which …

Mathematics Education From A Mathematicians Point Of View, Nan Woodson Simpson

Masters Theses

This study has been written to illustrate the development from early mathematical learning (grades 3-8) to secondary education regarding the Fundamental Theorem of Arithmetic and the Fundamental Theorem of Algebra. It investigates the progression of the mathematics presented to the students by the current curriculum adopted by the Rhea County School System and the mathematics academic standards set forth by the State of Tennessee.

Development, Analysis, And Optimization Of A Swirl-Promoting Mean Flow Solution For Solid Rocket Motors, Andrew Steven Fist

Masters Theses

This work demonstrates and analyses a new flow candidate for describing the internal gaseous motion in simulated rocket motors. The fundamental features of this solution include the conservation of key system properties also incorporated in the classic Taylor-Culick (TC) system (i.e. inviscid, axisymmetric, steady and rotational properties), while allowing for the development of a swirling velocity component. The work compares the new solution to the development and formulation of the classic TC system, ultimately identifying that both the new and classic solutions are special cases of the Bragg-Hawthorne equation. Following this development, the text then explores the development of energy-optimized …

Understanding Stakeholder Attitudes And Involvement In Habitat Conservation Plans And The Endangered Species Act, Kyle Andrew Rodgers

Masters Theses

The Endangered Species Act (ESA), established in 1973, was a landmark piece of environmental legislation and remains the standard for endangered species conservation. Implementation of the ESA has often been framed as pitting economic development against species conservation, inciting passions for and against endangered species conservation. The strength of opposing public opinions is highlighted by high-profile controversies such as those around the snail darter, northern spotted owl and the greater sage grouse. In an attempt to reduce conflict, the US Fish and Wildlife Service (USFWS) increasingly seeks to utilize collaborative, stakeholder-based processes that address stakeholder interests, attitudes, and values.

In …

Experimental Study On The Production Of Negative Ion Copper Clusters And Applications, Ran Chu

Masters Theses

At the Holifield Radioactive Ion Beam Facility (HRIBF) at Oak Ridge National Laboratories (ORNL), we investigated the formation, production and potential application of negative-ion copper clusters using mass distributions of negative-ion copper clusters obtained by bombarding various copper samples with Cs ions. The Cu samples – in very large mass-selected clusters Cu (e.g. n=54) – included natural Cu, isotopically enriched copper-63 and copper-65, and electroformed ultra-clean Cu. Mass spectra of negative copper cluster produced by Cs sputter source size up to 50 are shown for the first time.

Three main features were observed for all four copper samples: the intensity …

Correction To Luminosity Measurement For The Pixel Luminosity Telescope At Cms, Krishna Thapa

Masters Theses

The search for and detailed study of new particles and forces with the Compact Muon Solenoid (CMS) detector at the Large Hadron Collider (LHC) of CERN is fundamentally dependent on the precise measurement of the rate at which proton-proton collisions produce any particles, the so-called luminosity. Therefore, a new detector, the Pixel Luminosity Telescope (PLT), dedicated to measure the luminosity at high precision was added to the CMS experiment in 2015. It measures the inclusive charged particle production from each collision of proton bunches in the LHC. Additional charged particles which are observed by the instrument but produced from sources …

Specific Phosphate Sorption Mechanisms Of Unaltered And Altered Biochar, Kathryn D. Szerlag

Masters Theses

Biochar has been shown to act as an effective sorbent for many organic and inorganic contaminants (including phosphate) and can help to improve the quality of our fresh water resources by preventing eutrophication. Most of the high efficiency biochar phosphate-adsorbent feedstocks are modified with chemical pretreatment, phytoremediation or anaerobic digestion to accumulate desired elements. The main objectives of this project were to first engineer magnesium (Mg) and calcium (Ca) altered biochar by chemical pretreatment followed by pyrolysis at either 350 or 550°C and evaluate their phosphate adsorption rate and potential as compared to their unaltered counterparts. Determination of surface physiochemical …

Fault Interaction Within Restraining Bend Fault Systems, Aviel Rachel Stern

Masters Theses

Numerical simulations of a 15° restraining bend analog claybox experiment include considering the fault geometry, rheology, and boundary conditions. The numerical models show that a growing fault from an analog experiment propagates at depth rather than at the surface and is exposed in later stages of the experiment, and that the wet kaolin clay from the analog experiment is partially decoupled from the steel plate. The numerical models provide the stresses to predict accurate fault growth from the analog experiment and provide the evolution of external work within the fault system. The external work from the numerical models decrease as …

Ecological Consequences Of Lost Anadromous Forage Fish In Freshwater Ecosystems, Steven R. Mattocks

Masters Theses

Beginning in the early 1600s, dam construction in New England obstructed anadromous fish access to spawning grounds during migration. As a result, anadromous forage fish populations have declined, which has impacted freshwater, marine, and terrestrial ecosystems. To determine the impacts of dams on anadromous forage fish and freshwater ecosystems, I used historical and current data to estimate population changes in alewives (Alosa pseudoharengus) from 1600-1900. A significant reduction in spawning habitat occurred in New England as a result of 1,642 dams constructed between 1600 and 1900, resulting in 14.8% and 16.6% lake and stream habitat remaining by 1900, …

Development Of Filter-Based Surface Enhanced Raman Spectroscopic Assays For Rapid Detection Of Chemical And Biological Contaminants In Water, Siyue Gao

Masters Theses

Surface enhanced Raman spectroscopy (SERS) has been widely applied for rapid and sensitive detection of various chemical and biological targets. Here, we incorporated a syringe filter system into the SERS method to detect pesticides, protein toxins and bacteria in water. For the detection of chemical and protein targets, silver nanoparticles (Ag NPs) were aggregated by sodium chloride (NaCl) to form nanoclusters that could be trapped in the pores of the filter membrane to from the SERS-active membrane. Then a coating of capture (e.g. aptamer) was integrated on the nanoparticle substrate if needed. Then samples were filtered through the membrane. After …

A Comparison Of Techniques For Handling Missing Data In Longitudinal Studies, Alexander R. Bogdan

Masters Theses

Missing data are a common problem in virtually all epidemiological research, especially when conducting longitudinal studies. In these settings, clinicians may collect biological samples to analyze changes in biomarkers, which often do not conform to parametric distributions and may be censored due to limits of detection. Using complete data from the BioCycle Study (2005-2007), which followed 259 premenopausal women over two menstrual cycles, we compared four techniques for handling missing biomarker data with non-Normal distributions. We imposed increasing degrees of missing data on two non-Normally distributed biomarkers under conditions of missing completely at random, missing at random, and missing not …

Factors Affecting Habitat Quality For Wintering Wood Thrushes In A Coffee Growing Region In Honduras, Brett A. Bailey

Masters Theses

Amongst the diversity of taxa that occur in the Neotropics, 200 migratory bird species that breed in temperate North America can be found. Many of these populations have seen significant declines since the 1960s. The Wood Thrush, Hylocichla mustelina, is one such species. Shade coffee and other agroforestry practices show potential for benefiting migratory species, but the quality of coffee habitat and optimal habitat characteristics for Wood Thrushes remain unknown.

I surveyed a spatially complex, agricultural landscape in Honduras outside the recognized winter range of the Wood Thrush and radio-tagged 46 individuals within rustic coffee farms during the winters …

Testing The Temporal Stability Of The Climate Response Of Tree Species At Norris Dam State Park, Tennessee, U.S.A., Allison Elizabeth Ingram

Masters Theses

Temporal stability of the climate-tree growth relationship means that over time, tree species were responding to a specific climate variable and continue to respond to that variable into the present. The stability of this response is important to test prior to attempting to reconstruct past climate. In this study, I sampled oaks (white oak = Quercus alba L. and chestnut oak = Quercus montana Willd.) and pines (Virginia pine = Pinus virginiana Mill. and shortleaf pine = Pinus echinata Mill.) growing in Norris Dam State Park in eastern Tennessee and tested the temporal stability of these species and their potential …

A Computational Geometric And Graph Theoretic Approach To Reducing Dimensionality On Raster Data Problems, Matthew James Robert Bachstein

Masters Theses

Large scale mathematical models often involve a trade off between computational length and detail. In general, the more detailed the data, the more time it takes for the model to process. Models that use geographic scale data are particularly susceptible to this inflation; fine resolution data (on the order of m2 [meters squared]) brings great benefits, but demolishes the computation time. This thesis presents a method for reducing the dimensionality of large scale data in a systematic manner to maximize the benefits of fine resolution data while minimizing the computational time increase, then applying the method to a simulated invasive …

Pore Characterizations And Distributions Within Niagaran – Lower Salina Reef Complex Reservoirs In The Silurian Northern Niagaran Pinnacle Reef Trend, Michigan Basin, Agam Arief Suhaimi

Masters Theses

The Northern Niagaran Pinnacle Reef Trend (NNPRT) has generated significant oil and gas production in Michigan. The best reservoir rock in the Reef Trend reservoirs are from porous and permeable dolomite of the Guelph Dolomite. Low-to-non reservoir limestone occurs interstratified with reservoir dolomite in many locations. This study utilizes available cores data, thin section Petrographic Image Analysis (PIA), Mercury Injection Capillary Pressure (MICP) and a newly developed Niagaran Reef depositional model (Rine, 2015) to characterize the distribution of pore geometry within each dolomitized Niagaran Reef Complex (Brown Niagaran – Lower Salina Group) reservoir facies and lithofacies. This study shows that …

A Textural Image Analysis Study Of Mars-Analog Sediment: Comparisons Of 2d And 3d Textural Analysis Methods, Image Resolution, And The Effects Of Shadows, Mary Agnes Eibl

Masters Theses

Sediments from Mars-analog, basaltic, aeolian (Moses Lake dunes, WA) and fluvial (Death Valley region, CA) environments were analyzed for textural properties (grain size, roundness, sphericity) to understand how well image-based analyses compare with actual sediment characteristics. Three interrelated studies determined: (1) how well high-resolution, two-dimensional (2D) image analysis compares with three-dimensional (3D) sediment textures, (2) the extent to which decreasing image resolution affects textural analyses by comparison with high-resolution images, and (3) the extent to which shadows at different incident solar angles has on textural measurements. In both aeolian and fluvial environments, 2D grain-size distributions and statistics closely match 3D …

Pdroid, Joe Larry Allen

Masters Theses

When an end user attempts to download an app on the Google Play Store they receive two related items that can be used to assess the potential threats of an application, the list of permissions used by the application and the textual description of the application. However, this raises several concerns. First, applications tend to use more permissions than they need and end users are not tech-savvy enough to fully understand the security risks. Therefore, it is challenging to assess the threats of an application fully by only seeing the permissions. On the other hand, most textual descriptions do not …

Regional Dynamic Price Relationships Of Distillers Dried Grains In U.S. Feed Markets, Matthew Fulton Johnson

Masters Theses

Distillers dried grains with solubles (DDGS) is now a mainstream substitute in U.S. animal feed rations. DDGS is rich in fat and protein content and serves as a competitive feed source in livestock markets. The objective of this study is to identify dynamic price relationships among DDGS, corn, soybean meal, and livestock outputs in context of specific livestock sectors and their geographic location. Four locations associated with a predominant livestock sector are selected for analysis by measuring density and relative proportion of a livestock sector’s grain consumption at the county level. A vector error correction model is applied to post-mandate …

Petrology Of The Paired Dominion Range 2010 Howardites: Indications Of Magmatic Complexity On Asteroid Vesta, Timothy Michael Hahn Jr.

Masters Theses

A comprehensive petrologic and geochemical characterization of six paired howardites collected from the Dominion Range, Antarctica was conducted. These howardites are megaregolith samples from the asteroid 4 Vesta. Collectively, they contain an assortment of igneous rock fragments that indicate magmatic processes were capable of producing a variety of rock types; 22 chemically and texturally discrete basaltic eucrite, cumulate eucrite, and diogenite lithologies are recognized. The implications for remote-sensing observations of Vesta are discussed. The petrogenesis of two previously unrecognized lithologies are described in further detail: an evolved dacite that we propose is a residual melt from extensive crystallization, and a …

Microbial Extracellular Enzymes In Marine Sediments: Methods Development And Potential Activities In The Baltic Sea Deep Biosphere, Jenna Marie Schmidt

Masters Theses

The deep biosphere is defined as the subsurface ecosystem in which little energy is available to microorganisms and microorganisms can live for thousands of years. Heterotrophic microbes survive in the deep biosphere even though organic matter is limited and highly recalcitrant in nature. Measuring microbial extracellular enzyme activity provides a potential means to evaluate the rate at which microorganisms are performing carbon remineralization in the energy limited sediment beneath the seafloor. Extracellular enzymes breakdown organic compounds so that the nutrients can move inside the cell and be used for energy. This study explored the role extracellular enzymes play in the …

The Use Of Sodium Persulfate In Hydraulic Fracturing Fluids: A Degradation Study Based On Furfural, Katherine Elizabeth Manz

Masters Theses

Hydraulic fracturing has allowed natural gas to become a viable energy source via extraction of unconventional shale reserves, but this process requires an enormous amount of water. To ensure a productive fracture, a proprietary blend of chemical additives is added to the water. In this research, a hydraulic fracturing chemical additive – an enzyme breaking agent – is analyzed for organic components using gas chromatography mass spectrometry. The chemical changes that occur over the course of a fracture are also investigated using one model chemical found in the additive, furfural, in order to help assess the environmental risk that hydraulic …

Role Of Sorting On The Composition Of Siliciclastic Sediment: Implications For Interpreting Provenance After Limited Transport In An Arid Climate, Forrest Christopher Driscoll

Masters Theses

This study tested whether transport distances (< 500 m) have the capacity to shape the geochemistry of sediments across multiple grain-size populations due to sorting derived from a single source. In the Stepladder Mountains, Mojave Desert, CA, a < 1 km² [square kilometers] watershed allows for a controlled study to understand how modern sediments acquire their composition from a single granodioritic source in an arid climate where there is no chemical weathering. Sediments are naturally sorted into distinct grain-size populations, with modes ranging from very fine sand to gravel within a single, alluvial channel. Sediment samples representative of each population were petrographically and geochemically analyzed in order to test the effectiveness of commonly used discrimination diagrams. Sediments became proportionally enriched in plagioclase and biotite and depleted in K-feldspar and quartz with decreasing grain …

Stratigraphy Of The Upper Devonian-Lower Mississippian Michigan Basin: Review And Revision With An Emphasis On The Ellsworth Petroleum System, Bryan J. Currie

Masters Theses

Compression associated with the formation of the Transcontinental Arch and the Acadian Mountains initiated subsidence in the Michigan Basin and lead to a depositional switch in the Michigan Basin from an oxic shallow-water carbonate platform (Traverse Group and Squaw Bay Limestone) to a deep anaerobic sea floor and the beginning of Upper Devonian Antrim Shale. The vertical distribution of the different Upper Devonian-Lower Mississippian formations and members demonstrates large scale cycles of anaerobic-dysaerobic transitions attributed fluctuations in sea-level, different rates of subsidence and sediment influx triggered by different orogenic events to.

The regional understanding and the distribution of the different …

Restoration: Bridging The Gaps A Graphic Translation Of Ecological Restoration, Alyssandra Black

Masters Theses

The terms restoration ecology and ecological restoration are used interchangeably confusing the definition and work of ecological restoration and its many components. Restoration ecology is a type of scientific practice whose work will be a component of a restoration project while ecological restoration is the sum of practices, social, historical and ecological that constitute the field of restoration (Higgs, 2005). Within our rapidly urbanizing society the role of ecological restoration and restoring ecosystem services is increasingly important, especially within our coastal cities. The goals of restoration differ when the classification of restoration techniques is by ecosystem service, not ecological function, …

Sleep Patterns, Urinary Levels Of Melatonin And Subsequent Weight Change In The Women’S Health Initiative Observational Study, Nicole M. Barron

Masters Theses

Results from prospective studies examining associations between sleep duration and weight gain have been mixed. Melatonin has been hypothesized to mediate the association between sleep duration and weight/body composition. In cross-sectional studies, aMT6s has been shown to be inversely associated with weight/body fat percentage. We examined associations between baseline sleep duration, insomnia status, aMT6s levels with weight/body fat percentage through 6 years, utilizing a subset 690 women who participated in a breast cancer case-control study nested within the WHI-OS. Multi-variable and mixed-effects regression was used to calculate beta-coefficients and 95% confidence intervals. Cross-sectional analyses showed urinary aMT6s levels were inversely …

A Haptic Surface Robot Interface For Large-Format Touchscreen Displays, Mark Price

Masters Theses

This thesis presents the design for a novel haptic interface for large-format touchscreens. Techniques such as electrovibration, ultrasonic vibration, and external braked devices have been developed by other researchers to deliver haptic feedback to touchscreen users. However, these methods do not address the need for spatial constraints that only restrict user motion in the direction of the constraint. This technology gap contributes to the lack of haptic technology available for touchscreen-based upper-limb rehabilitation, despite the prevalent use of haptics in other forms of robotic rehabilitation. The goal of this thesis is to display kinesthetic haptic constraints to the touchscreen user …