Physical Sciences and Mathematics Commons^™

Substituting Failure Avoidance For Redundancy In Storage Fault Tolerance, Christopher David Brumgard

Doctoral Dissertations

The primary mechanism for overcoming faults in modern storage systems is to introduce redundancy in the form of replication and error correcting codes. The costs of such redundancy in hardware, system availability and overall complexity can be substantial, depending on the number and pattern of faults that are handled. This dissertation describes and analyzes, via simulation, a system that seeks to use disk failure avoidance to reduce the need for costly redundancy by using adaptive heuristics that anticipate such failures. While a number of predictive factors can be used, this research focuses on the three leading candidates of SMART errors, …

Synthesis, Reactivity, And Nmr Trends Of Early Transition Metal Compounds, Tabitha Marie Cook

Doctoral Dissertations

This dissertation focuses of three different subjects. The first is the synthesis and characterization of heptacoordinate amidinate compounds. Heptacoordinate compounds are not common, but their structures have been studied. Group 4 amidinate compounds have been used as precursors in the CVD/ ALD processes. Ancillary ligands, such as amidinates, have been used to reduce air-sensitivity of complexes. Reactions of these complexes with water have been used to make metal oxide thin films.

In the first study, the complexes Zr[MeC(NⁱPr)₂]₃Cl [zirconium trisamidinate chloride], Hf[MeC(NⁱPr)₂]₃Cl [hafnium trisamidinate chloride], Zr[MeC(NⁱPr) …

Beta-Delayed Neutron Data And Models For Scale, Kemper Dyar Talley

Doctoral Dissertations

Recent advancements in experimental and theoretical nuclear physics have yielded new data and models that more accurately describe the decay of fission products compared to historical data currently used for many applications. This work examines the effect of the adopting the Effective Density Model theory for beta-delayed neutron emission probability on calculations of delayed-neutron production and fission product nuclide concentrations after fission bursts as well as the total delayed neutron fraction in comparison with the Keepin 6-group model. We use ORIGEN within the SCALE code package for these calculations. We show quantitative changes to the isotopic concentrations for fallout nuclides …

Large Scale Brownian Dynamics Simulation Of Dilute And Semidilute Polymeric Solutions, Amir Saadat

Doctoral Dissertations

Excluded Volume (EV) and Hydrodynamic Interactions (HI) play a central role in static and dynamic properties of macromolecules in solution under equilibrium and nonequilibrium settings. The computational cost of incorporating HI in mesoscale Brownian dynamics (BD) simulations, particularly in the semidilute regime has motivated significant research aimed at development of high-fidelity and efficient techniques.

In this study, I have developed several algorithms for the mesoscale bead-spring representation of a macromolecular solution in dilute and semidilute regimes. The Krylov subspace method enables fast calculation of single chain dynamics with simulation time scaling of O(N_b²) [order N …

The Effect Of Illumination On The Conformation And Thermodynamics Of Conjugated Polymers, Brian Frank Morgan

Doctoral Dissertations

This dissertation explores the effects which illumination has on the structure and conformation of conjugated polymers, both in solution and the bulk. Conjugated polymers are an important class of optoelectronic polymeric materials which make up the active layer of key organic electronic devices such as organic photovoltaics, transistors, and light emitting diodes. Considering the strong link between polymer chain structure and device efficiency in these materials, a comprehensive understanding of certain experimental conditions which may influence this conformation and thusly alter the functionality of the devices predicated upon them is of vital importance.

The first part of this dissertation provides …

Optical Spectroscopy And The Contruction Of An Optimal Wannier Basis With Application To The Development Of Ab Initio Models, Robert Gerard Van Wesep

Doctoral Dissertations

Understanding the role of local orbital degrees of freedom in the behavior of solid state systems has long been understood as a key to unraveling the mysteries presented by complex transition metal compounds. A general approach to the many-body problem is density functional theory (DFT) and its time-dependent extension (TDDFT), which provide a realistic representation of the material-dependent symmetry and chemistry of a compound. Calculation of quantities in (TD)DFT are most often performed using the basis of Bloch states, which is not natural for investigating local degrees of freedom. The Wannier basis provides localized orbitals that retain all of the …

Development And Validation Of The Statistics Assessment Of Graduate Students, Dammika Lakmal Walpitage

Doctoral Dissertations

This study developed the Statistics Assessment of Graduate Students (SAGS) instrument, and established its preliminary item characteristics, reliability, and validity evidence. Even though there are limited number of assessments available for measuring different aspects of statistical cognition, these previously available assessments have numerous limitations. The SAGS instrument was developed using Rasch modeling approach to create a new measure of statistical research methodology knowledge of graduate students in education and other behavioral and social sciences. Thirty-five multiple-choice questions were written with stems representing applied research situations and response options distinguishing between appropriate use of various statistical tests or procedures. A focus …

Design And Synthesis Of Lipid Probes Used For Membrane Derivatization And Fusion, Stuart Allen Whitehead

Doctoral Dissertations

Lipids control a variety of complex biological processes. Bulk lipids such as phosphatidylcholine (PC), phosphatidylserine (PS), and phosphatidylethanolamine (PE) represent the major components of cellular membranes. In addition, unilamellar vesicles composed of lipids (liposomes) are valuable for delivery applications since they can encapsulate and transport drugs and other agents. In order to maximize delivery efficiency and target specific membranes, the ability to trigger and control vesicle-vesicle fusion is desirable. Such approaches generally seek to mimic the membrane fusion machinery present in nature while imparting specificity in the membranes that undergo fusion. The goal of this work is selective drug delivery …

Development Of An F-Element Separation Chemistry Using Solid Electrolytes, Kristian Guy Myhre

Doctoral Dissertations

The f‒elements (lanthanides and actinides) have numerous applications and are critically important to many industries, including the energy, security, and medical industries. One of the barriers to increased use and availability of the f‒elements is the difficulty in separating them from each other due to their similar chemistries. This is especially true of the trivalent f‒elements (lanthanides and minor actinides). The development of separation techniques that maximize the differences in the physicochemical properties of the f‒elements is therefore an important area of research. For these reasons, an effort was undertaken to explore the use of solid …

Catalytic Aziridination With A Borate-Containing N-Heterocyclic Tetracarbene Iron Complex, Preeti Pradip Chandrachud

Doctoral Dissertations

Aziridines, the nitrogen analog of epoxides, are an important class of compounds. They are present in many biologically active compounds having antibacterial and antitumor properties. Along with biological significance, it can also be considered as a synthetic tool for various functional group transformations. Being an important functional group we focused on the development of synthetic methodology using alkenes as substrates and organic azides as the nitrene source [C₂ (carbon2)+ N₁ (nitrogen1) addition reaction].

For the potential use as an aziridination catalyst a macrocyclic N-heterocyclic tetracarbene (NHC) ligand system was developed. First, the neutral NHC ligand was used …

Kinematic, Metamorphic, And Geochronologic Constraints On The Evolution Of The Lhagoi Kangri Gneiss Dome, Southern Tibet: Insight Into Mid-Crustal Processes During Himalayan Orogenesis, Timothy Francis Diedesch

Doctoral Dissertations

The north Himalayan gneiss domes are a series of isolated structures in southern-central Tibet that expose middle crust and record an early history of deformation, metamorphism, and partial melting. The domes are windows into the processes and physical conditions that promoted growth and uplift of the Himalaya during the early stage of collision (Eocene to Miocene) between India and Asia. Mechanisms responsible for creating the north Himalayan gneiss domes are crucial to understanding the early tectonic evolution of large orogens, such as the Himalaya, particularly with respect to crustal rheology and how middle crust is exhumed in collisional settings. Models …

Synthesis And Behavior Of Stimuli-Responsive Shape-Changing Linear Molecular Bottlebrushes, Daniel Mark Henn

Doctoral Dissertations

Molecular bottlebrushes are composed of polymer side chains densely grafted to a macromolecular backbone. The main focus of this dissertation work is the synthesis and behavior of linear molecular brushes that can undergo unimolecular size and shape changes in response to environmental stimuli in dilute aqueous solution. Chapter 1 provides an introduction to molecular bottlebrushes and stimuli-responsive polymers.

Chapter 2 presents the development of a robust method for the synthesis of well-defined molecular brushes by a “grafting to” approach using copper-catalyzed azide-alkyne cycloaddition “click” reactions. Well-defined, new azide-containing backbone polymers with different lengths and high degrees of azide functionality were …

Geomorphology, Stratigraphy, And Paleohydrology Of The Aeolis Dorsa Region, Mars, With Insights From Modern And Ancient Terrestrial Analogs, Robert Eric Jacobsen Ii

Doctoral Dissertations

Ancient fluvial features on Mars evidence past episodes of hydrologic activity and paleoclimate conditions suitable for liquid water. The Aeolis Dorsa region preserves the most numerous and diverse assemblage of fluvial features yet observed on Mars and many of these features have experienced a history of burial, exhumation, and topographic inversion. This dissertation describes analyses of visual images and topography of Mars and complementary analyses of fluvial analogs on Earth. These analyses provide information about the styles of fluvial activity, magnitudes of paleodischarge, changes in slope, and inferences about Martian paleoclimate conditions. Results indicate that the Aeolis Dorsa deposits encapsulate …

On The Quantification Of Complexity And Diversity From Phenotypes To Ecosystems, Zachary Harrison Marion

Doctoral Dissertations

A cornerstone of ecology and evolution is comparing and explaining the complexity of natural systems, be they genomes, phenotypes, communities, or entire ecosystems. These comparisons and explanations then beget questions about how complexity should be quantified in theory and estimated in practice. Here I embrace diversity partitioning using Hill or effective numbers to move the empirical side of the field regarding the quantification of biological complexity.

First, at the level of phenotypes, I show that traditional multivariate analyses ignore individual complexity and provide relatively abstract representations of variation among individuals. I then suggest using well-known diversity indices from community ecology …

Applications Of Sampling And Estimation On Networks, Fabricio Murai Ferreira

Doctoral Dissertations

Networks or graphs are fundamental abstractions that allow us to study many important real systems, such as the Web, social networks and scientific collaboration. It is impossible to completely understand these systems and answer fundamental questions related to them without considering the way their components are connected, i.e., their topology. However, topology is not the only relevant aspect of networks. Nodes often have information associated with them, which can be regarded as node attributes or labels. An important problem is then how to characterize a network w.r.t. topology and node label distributions. Another important problem is how to design efficient …

Detecting Anomalously Similar Entities In Unlabeled Data, Lisa D. Friedland

Doctoral Dissertations

In this work, the goal is to detect closely-linked entities within a data set. The entities of interest have a tie causing them to be similar, such as a shared origin or a channel of influence. Given a collection of people or other entities with their attributes or behavior, we identify unusually similar pairs, and we pose the question: Are these two people linked, or can their similarity be explained by chance? Computing similarities is a core operation in many domains, but two constraints differentiate our version of the problem. First, the score assigned to a pair should account for …

Chasing New Physics: From Electroweak Baryogenesis To Dark Matter, Huaike Guo

Doctoral Dissertations

The origin of the baryon asymmetry in the universe and the nature of the dark matter remain mysteries and addressing these cosmological puzzles requires physics beyond the standard model. Electroweak baryogenesis remains a highly testable framework for explaining the baryon asymmetry and is employed in this work to study the capability of baryon generation for beyond standard model physics models and to explore new physics discovery potential in high energy and precision frontier. Weakly interacting massive particles as cold dark matter are also studied in this work featuring loop induced direct detection signals and novel nuclear responses within the recently …

Application-Aware Resource Management For Cloud Platforms, Xin He

Doctoral Dissertations

Cloud computing has become increasingly popular in recent years. The benefits of cloud platforms include ease of application deployment, a pay-as-you-go model, and the ability to scale resources up or down based on an application's workload. Today's cloud platforms are being used to host increasingly complex distributed and parallel applications. The main premise of this thesis is that application-aware resource management techniques are better suited for distributed cloud applications over a systems-level one-size-fits-all approach. In this thesis, I study the cloud-based resource management techniques with a particular emphasis on how application-aware approaches can be used to improve system resource utilization …

Study Of Charge Transport Mechanism In Microbial Nanowires, Ramesh Adhikari

Doctoral Dissertations

Conductivity of an individual proteinaceous filaments, called pili or microbial nanowires, produced by wild type Geobacter sulfurreducens was measured using a low-noise electrical transport technique. It was shown that the conductivity is diminished if aromatic amino acid residues are removed from the pili. It was demonstrated that the conductivity of G. sulfurreducens pili is similar to that of synthetic organic polymers and is related to the respiration rate of the bacteria. Conductivity measurements were performed on microbial nanowires produced by other species of Geobacter with a different aromatic amino acid distribution along the wire. Also, measurements on a mutated pili …

Elastic Resource Management In Distributed Clouds, Tian Guo

Doctoral Dissertations

The ubiquitous nature of computing devices and their increasing reliance on remote resources have driven and shaped public cloud platforms into unprecedented large-scale, distributed data centers. Concurrently, a plethora of cloud-based applications are experiencing multi-dimensional workload dynamics---workload volumes that vary along both time and space axes and with higher frequency. The interplay of diverse workload characteristics and distributed clouds raises several key challenges for efficiently and dynamically managing server resources. First, current cloud platforms impose certain restrictions that might hinder some resource management tasks. Second, an application-agnostic approach might not entail appropriate performance goals, therefore, requires numerous specific methods. Third, …

A Period Examination Through Contemporary Energy Analysis Of Kevin Roche’S Fine Arts Center At University Of Massachusetts-Amherst, L Carl Fiocchi Jr

Doctoral Dissertations

Studies of buildings belonging to a subset of Modernist architecture, Brutalism, have included discussions pertaining to social and architectural history, critical reception, tectonic form and geometry inspirations, material property selections, period technology limitations, and migration of public perceptions. Evaluations of Brutalist buildings’ energy related performances have been restricted to anecdotal observations with particular focus on the building type’s poor thermal performance, a result of the preferred construction method, i.e. monolithic reinforced concrete used as structure, interior finish and exterior finish. A valid criticism, but one that served to dismiss discussion that the possibility of other positive design strategies limiting energy …

X-Ray Characterization Of Mesophases And Phase Transitions Of Dna Analogues In Solutions, Mustafa Selcuk Yasar

Doctoral Dissertations

We think of DNA as double-stranded helices (duplex), but the polymer exists in many conformations. Several triplex and quadruplex DNA structures can be formed in laboratory settings and exist in nature. This thesis first provides a brief description of the nature of the order in arrays of duplex DNA under biologically relevant molecular crowding conditions. Then we compare the duplex DNA mesophases with the corresponding liquid crystalline phase behavior of the triplex and quadruplex DNA analogues. In particular, we focus on G-quadruplexes. Observed in the folds of guanine-rich oligonucleotides, G-quadruplex structures are based on G-quartets formed by hydrogen bonding and …

Evaporation Induced Self-Assembly And Characterization Of Nanoparticulate Films: A New Route To Bulk Heterojunctions, Yipeng Yang

Doctoral Dissertations

Polymer-based semiconducting materials are promising candidates for large-scale, low-cost photovoltaic devices. To date, the efficiency of these devices has been low in part because of the challenge of optimizing molecular packing while also obtaining a bicontinuous structure with a characteristic length comparable to the exciton diffusion length of 10 to 20 nm. In this dissertation we developed an innovative evaporation-induced nanoparticle self-assembly technique, which could be an effective approach to fabricate uniform, densely packed, smooth thin films with cm-scale area from home-made P3HT nanoparticles. Unlike the previous reports of nanoparticle-based film formation, we use a mixture of two solvents so …

Intrinsic Functions For Securing Cmos Computation: Variability, Modeling And Noise Sensitivity, Xiaolin Xu

Doctoral Dissertations

A basic premise behind modern secure computation is the demand for lightweight cryptographic primitives, like identifier or key generator. From a circuit perspective, the development of cryptographic modules has also been driven by the aggressive scalability of complementary metal-oxide-semiconductor (CMOS) technology. While advancing into nano-meter regime, one significant characteristic of today's CMOS design is the random nature of process variability, which limits the nominal circuit design. With the continuous scaling of CMOS technology, instead of mitigating the physical variability, leveraging such properties becomes a promising way. One of the famous products adhering to this double-edged sword philosophy is the Physically …

Studies On Lattice Systems Motivated By Pt-Symmetry And Granular Crystals, Haitao Xu

Doctoral Dissertations

This dissertation aims to study some nonlinear lattice dynamical systems arising in various areas, especially in nonlinear optics and in granular crystals. At first, we study the 2-dimensional PT-symmetric square lattices (of the discrete non-linear Schr¨odinger (dNLS) type) and identify the existence, stability and dynamical evolu- tion of stationary states, including discrete solitons and vortex configurations. To enable the analytical study, we consider the so-called anti-continuum (AC) limit of lattices with uncoupled sites and apply the Lyapunov–Schmidt reduction. Numerical experiments will also be provided accordingly. Secondly, we investigate the nonlinear waves in the granular chains of elastically inter- acting (through …

Stochastic Network Design: Models And Scalable Algorithms, Xiaojian Wu

Doctoral Dissertations

Many natural and social phenomena occur in networks. Examples include the spread of information, ideas, and opinions through a social network, the propagation of an infectious disease among people, and the spread of species within an interconnected habitat network. The ability to modify a phenomenon towards some desired outcomes has widely recognized benefits to our society and the economy. The outcome of a phenomenon is largely determined by the topology or properties of its underlying network. A decision maker can take management actions to modify a network and, therefore, change the outcome of the phenomenon. A management action is an …

Metamorphic And Structural Control Of Magnetism Within The Lower Continental Crust, Northern Saskatchewan, Canada, Jeffrey R. Webber

Doctoral Dissertations

The linking of geophysical information to tectonometamorphic processes holds great potential for the surveying of vast remote areas of the planet and may allow for the transcendence of observational scales. Investigations concerning magnetic properties of the lower continental crust can reveal an incredible wealth of information concerning the conditions of metamorphism, regional extent of deformation, and controls on the magnetic architecture of the lithosphere. This dissertation presents three contributions aimed at the integration of petrology, structural geology, and rock magnetism in order to investigate the magnetic nature of the lower continental crust, constrain tectonometamorphic processes at the regional scale in …

Spherical Tropicalization, Anastasios Vogiannou

Doctoral Dissertations

In this thesis, I extend tropicalization of subvarieties of algebraic tori over a trivially valued algebraically closed field to subvarieties of spherical homogeneous spaces. I show the existence of tropical compactifications in a general setting. Given a tropical compactification of a closed subvariety of a spherical homogeneous space, I show that the support of the colored fan of the ambient spherical variety agrees with the tropicalization of the closed subvariety. I provide examples of tropicalization of subvarieties of GL(n), SL(n), and PGL(n).

Specification And Analysis Of Resource Utilization Policies For Human-Intensive Systems, Seung Yeob Shin

Doctoral Dissertations

Contemporary systems often require the effective support of many types of resources, each governed by complex utilization policies. Sound management of these resources plays a key role in assuring that these systems achieve their key goals. To help system developers make sound resource management decisions, I provide a resource utilization policy specification and analysis framework for (1) specifying very diverse kinds of resources and their potentially complex resource utilization policies, (2) dynamically evaluating the policies’ effects on the outcomes achieved by systems utilizing the resources, and (3) formally verifying various kinds of properties of these systems. Resource utilization policies range …

Skein Theory And Algebraic Geometry For The Two-Variable Kauffman Invariant Of Links, Thomas Shelly

Doctoral Dissertations

We conjecture a relationship between the Hilbert schemes of points on a singular plane curve and the Kauffman invariant of the link associated to the singularity. Specifcally, we conjecture that the generating function of certain weighted Euler characteristics of the Hilbert schemes is given by a normalized specialization of the difference between the Kauffman and HOMFLY polynomials of the link. We prove the conjecture for torus knots. We also develop some skein theory for computing the Kauffman polynomial of links associated to singular points on plane curves.