Physical Sciences and Mathematics Commons^™

Geochemical And Petrological Characterization Of The Back Forty Volcanogenic Massive Sulfide Deposit, Anthony Robert Boxleiter

Masters Theses

The Back Forty Zn-Au deposit is the eastern-most Volcanogenic Massive Sulfide (VMS) deposit in the Penokean Volcanic Belt (PVB). It is the only VMS deposit found in Michigan, and is located along the east side of the Menominee River in Menominee County (45°26'57.5"N, 87°49'43.2"W). The Back Forty is the most zinc-enriched, copper depleted deposit among the major VMS deposits within the PVB that include Flambeau, Crandon, Bend, and Lynne. This work constitutes the first sulfur isotope study on the Back Forty VMS deposit.

The Back Forty is characterized by massive, semi-massive, disseminated and stringer sulfide mineralization hosted within felsic-dominated volcanic …

Depositional Facies And Sequence Stratigraphy Of Niagaran-Lower Salina Reef Complex Reservoirs Of The Guelph Formation, Michigan Basin, Matthew J. Rine

Masters Theses

Hydrocarbon reservoirs in the Niagara-Lower Salina Reef Complex in the Michigan Basin have been extensively studied since the early 1960’s. These reservoirs host an immense hydrocarbon resource, existing as closely-spaced, highly-compartmentalized reservoirs that have produced >500 million barrels of oil and 2.9 trillion cubic feet of natural gas. Previous studies depict these “pinnacle reefs” as tall, symmetrical towers with a random distribution of facies. This study utilizes abundant core data (32 cores, 20-acre spacing), thin-section petrography, and petrophysical wire-line logs to reconstruct the geometry, facies distributions, depositional history, and sequence stratigraphy of the Columbus III Reef Complex within the Southern …

Petrological And Geochemical Evaluation Of The Sturgeon Falls Intrusive Body, Jonathan Michael Haynes

Masters Theses

The Sturgeon Falls Intrusive Body (SFIB) is a gabbroic intrusion located along the Michigan-Wisconsin border just south of the town of Norway, MI. The SFIB is bounded to the north by the Niagara Shear Zone and the Michigamme Formation (Schulz and Cannon, 2006) and to the south by an unnamed thrust fault zone and the Quinnesec Formation (Sims and Schulz, 1993). Field mapping has shown that the SFIB is composed almost entirely of metagabbro metamorphosed to greenschist facies, with isolated outcrops of clinopyroxenite, which are thought to be xenoliths.

The origin of the SFIB is controversial. Schulz and LeBerge (2003) …

Rare Occurrences Of Free-Living Bacteria Belonging To Sedimenticola From Subtidal Seagrass Beds Associated With The Lucinid Clam, Stewartia Floridana, Aaron M. Goemann

Masters Theses

Lucinid clams and their sulfur-oxidizing endosymbionts comprise two compartments of a three-stage, biogeochemical relationship among the clams, seagrasses, and microbial communities in marine sediments. A population of the lucinid clam, Stewartia floridana, was sampled from a subtidal seagrass bed at Bokeelia Island Seaport in Florida to test the hypotheses: (1) S. floridana, like other lucinids, are more abundant in seagrass beds than bare sediments; (2) S. floridana gill microbiomes are dominated by one bacterial operational taxonomic unit (OTU) at a sequence similarity threshold level of 97% (a common cutoff for species level taxonomy) from 16S rRNA genes; …

Preparation And Characterization Of Thermodynamically Controlled Polymer Nanocomposites, Jiadi Hou

Masters Theses

The mechanical and physical properties of polymeric materials can be greatly improved by adding nanoscale additives. To mediate the dispersion of nanoparticles in polymers, it is often necessary to modify their surfaces to prevent aggregation. While polymer nanocomposites system consisting of homopolymer-grafted nanoparticles are well understood, copolymer-functionalized nanoparticles are less well understood but provide additional ways to alter dispersion through the use of chemically different comonomers. In this thesis, polystyrene nanocomposites blended with copolymer-grafted nanoparticles were prepared and studied. The particular comonomers used were methyl methacrylate and cyclohexyl methacrylate, which provides miscibility with polystyrene. Polymers with varying comonomer ratios were …

Neutrino Signatures In Terrestrial Detectors From Two- And Three-Dimensional Core-Collapse Supernovae Simulations, Tanner Brooks Devotie

Masters Theses

Core-collapse supernovae (CCSNe) are driven by neutrino emission and are the most prodigious sources of neutrinos in the Universe. Importantly, the neutrino radiation from CCSNe is emitted from deep in the explosion and can provide information about physical processes taking place in the newly-born neutron star at the heart of the event. We examine the four-flavor (i.e. ν_e, ν_e, ν_x and ν_x) [electron, muon and tau neutrinos along with their anti-matter counterparts] signature of CCSNe neutrino emission in various neutrino detector types. We use data from the multidimensional Chimera (Lentz et al., 2015) …

Strontium Monoxide Measurements In Methane-Air Flames, Bobby J. Wimberly

Masters Theses

The spectroscopy of alkaline earth metal compounds has been an area of active research for several decades. This is at least in part stimulated by the application of these compounds to practical areas ranging from technology to medicine. The use of these compounds in the field of pyrotechnics was the motivation for a series of flame emission spectroscopy (FES) experiments with strontium containing compounds. Specifically, strontium monoxide (SrO) is studied as a candidate radiator for the diagnostic of methane-air flames.

SrO emissions have been observed in flames with temperatures in the range of 1200-1600-K for two compounds: strontium hydroxide and …

Chemical Investigations Of Diabetes Mellitus, Malaria, And Castrate-Resistant Prostate Cancer, Maggie Sparks Lookadoo

Masters Theses

This work studies a variety of molecules and the systems they are involved in to further understand disease and treatment of diabetes mellitus, malaria, and castrate resistant prostate cancer. The first system studied, diabetes mellitus, involves synthesis of 5 different steroidal compounds, while the other two systems, malaria and castrate-resistant prostate cancer, apply mass spectrometric-based untargeted metabolomics to study both known metabolites and unknown spectral features.

Diabetes mellitus is a result of the dysfunction and death of islet beta cells caused by the transcription of pro-inflammatory cytokines resulting in reduced insulin secretion and uncontrollable blood glucose levels. Glucocorticoids can reduce …

Determination Of Dispersal Patterns And Characterization Of Important Habitats For Lake Sturgeon Restoration In The Upper Tennessee River System, Christina Grace Saidak

Masters Theses

Lake Sturgeon, Acipenser fulvescens, are one of the slowest to reach sexual maturity and longest-lived freshwater fish species in North America. These fish are a species of special concern by the U.S. Fish and Wildlife Service, a vulnerable species by the American Fisheries Society (Jelks et al. 2008), and a threatened species in Tennessee (Chiasson et al. 1997; Williams et al. 1989). They have been reintroduced into the Upper Tennessee River system since 2000.

Since December 2013, 49 Lake Sturgeon have been implanted with ultrasonic acoustic transmitters, and 26 fixed-station receivers installed throughout the Upper Tennessee River System to …

Environmental Controls On The Diversity And Distribution Of Endosymbionts Associated With Phacoides Pectinatus (Bivalvia: Lucinidae) From Shallow Mangrove And Seagrass Sediments, St. Lucie County, Florida, Thomas Walters Doty

Masters Theses

Lucinid bivalves are capable of colonizing traditionally inhospitable shallow marine sediments due to metabolic functions of bacterial endosymbionts located within their gills. Because lucinids can often be the dominant sediment infauna, defining their roles in sediment and pore fluid geochemical cycling is necessary to address concerns related to changes in coastal biological diversity and to understanding the sensitivity of threatened coastal ecosystems over time. However, there has been limited research done to understand the diversity and distribution of many lucinid chemosymbiotic systems. Therefore, the goals of this thesis were to evaluate the distribution of Phacoides pectinatus and its endosymbiont communities …

Experimental Limestone Dissolution And Changes In Multiscale Structure Using Small- And Ultra Small- Angle Neutron Scattering, Chad Alan Novack

Masters Theses

Small angle neutron scattering (SANS), ultra-small angle neutron scattering (USANS), and backscatter electron (BSE) imaging, along with neutron computed tomography (NCT) were used in this study to experimentally quantify pore size, distribution, and connectivity of dissolved limestone geometries. Eight samples of Indiana limestone of two different initial permeabilities (2-4 mD and 70 mD ) [millidarcy] were reacted with HCl [hydrochloric acid] solutions at differing pH (2 and 4), and flow rates (0.1 and 10 cm³/min) [cubic centimeters per minute] to describe a broad range of parameters that affect limestone dissolution. NCT was first used to image the dissolution …

Long-Term Impacts Of Conservation Management Practices On Soil Carbon Storage, Stability, And Utilization Under Cotton Production In West Tennessee, Candace Brooke Wilson

Masters Theses

Biogeochemical cycling of soil carbon (C) is heavily influenced by conservation agricultural (CA) practices. This study examined SOC stability under three CA practices: reduced nitrogen (N) fertilizer application rate, cover cropping, and zero-tillage implemented for 31 years. Respiration rates measured from a 602-day incubation period were fitted to a double-pool first order exponential model of SOC decomposition. The active [respired] SOC pool showed distinct differences between applications of reduced (34N kg ha^-1 [-1]) and high fertilization rates (101N kg ha^-1) combined with tillage, and suggest that high fertilizer applications with conventional tillage allocated more C into a …

Testing For The Effects Of Sediment Sorting On Detrital-Zircon Age Spectra By Sampling Multiple Bedforms In Single Fluvial Channels: Case Studies From The Wood Canyon Formation (Terreneuvian) And Stirling Quartzite (Ediacaran), Southeastern Ca, Jason Gerhard Muhlbauer

Masters Theses

Multiple bedforms were sampled from single fluvial channels in the Neoproterozoic (Ediacaran) upper member of the Stirling Quartzite and the Cambrian (Terreneuvian) middle member of the Wood Canyon Formation, southeastern California. Sampling strategy was designed to determine if sorting of detrital zircon populations by their textural properties can affect detrital-zircon age spectra in fluvial sandstones. Four samples derive from the middle member Wood Canyon Formation and two samples come from the upper member Stirling Quartzite. Sandstone samples vary in textural characteristics: grain sizes sampled range from fine to coarse sand, sorting ranges from moderately well to poorly sorted, and sampled …

Late Tertiary Tectonic Uplift In The Southern And Central Appalachians, Mary Sheela Biswal

Masters Theses

The exposed Appalachian Mountains extend about 2500 km from Newfoundland to Alabama with the highest peaks >2000 m above sea level. The last orogeny that affected Appalachian crust was the 325-260 Ma Alleghanian. Even with minimal erosion rates, it is highly unlikely that the Appalachians could have sustained such elevations for over 200 m.y., suggesting that recent tectonic uplift has produced today’s mountainous topography. The multiple phases of Tertiary uplift are related to poorly understood processes, but a large amount of data from today’s mountain chain and the adjacent Coastal Plain indicate the present high topography is anomalous and clearly …

Hsp-Wrap: The Design And Evaluation Of Reusable Parallelism For A Subclass Of Data-Intensive Applications, Paul R. Giblock

Masters Theses

There is an increasing gap between the rate at which data is generated by scientific and non-scientific fields and the rate at which data can be processed by available computing resources. In this paper, we introduce the fields of Bioinformatics and Cheminformatics; two fields where big data has become a problem due to continuing advances in the technologies that drives these fields: such as gene sequencing and small ligand exploration. We introduce high performance computing as a means to process this growing base of data in order to facilitate knowledge discovery. We enumerate goals of the project including reusability, efficiency, …

Rapid Dissolution For Destructive Assay Of Nuclear Melt Glass, Jonathan Allen Gill

Masters Theses

This study evaluates four methods for dissolving complex glassy debris resulting from nuclear detonations. The samples of interest simulate the glassy debris generated from a nuclear detonation’s fireball coming in contact with solid masses. Each method attempts to achieve dissolution through different approaches involving either acid digestion, alkaline digestion, or molten salt fusion. Two of the four methods were modified to retain all elements of the debris or surrogate debris. This retention is critical to the proportional relationships used in identifying fuel types and designs of nuclear weapons. Analysis is conducted with an inductively coupled time of flight mass spectrometer …

Siloxane And Silane-Functionalized Polynorbornenes As Membranes For Passive Carbon Dioxide Separation, Eunice Koheun Hong

Masters Theses

In 2012, carbon dioxide (CO₂) [carbon dioxide] accounted for approximately 82% [percent] of all U.S greenhouse gas emissions.¹ These excessive CO2 levels have been attributed to climate changes that have a range of negative effects on human health and welfare.1 In an effort to decrease these emissions, polymeric membranes consisting of silane- and siloxane-functionalized norbornene units have been targeted as a potential solution for the passive separation of CO2 from other non-greenhouse gases. These substituted norbornene-based polymers were synthesized via vinyl-addition polymerization. Through a series of catalyst trials, commercially available palladium and nickel catalysts were compared along …

Border-Collision Bifurcations Of Cardiac Calcium Cycling, Jacob Michael Kahle

Masters Theses

In this thesis, we study the nonlinear dynamics of calcium cycling within a cardiac cell. We develop piecewise smooth mapping models to describe intracellular calcium cycling in cardiac myocyte. Then, border-collision bifurcations that arise in these piecewise maps are investigated. These studies are carried out using both one-dimensional and two-dimensional models. Studies in this work lead to interesting insights on the stability of cardiac dynamics, suggesting possible mechanisms for cardiac alternans. Alternans is the precursor of sudden cardiac arrests, a leading cause of death in the United States.

Installation And Alignment Of The N3he Experiment, Eric Lee Plemons

Masters Theses

The n3He experiment is designed to probe the hadronic weak interaction by measuring the parity violating asymmetry between the spin of incoming neutrons and the momentum of outgoing protons following the nuclear break up of a helium three upon absorbing a neutron. Cold neutrons from the SNS are first polarized then allowed to impact a target chamber filled with helium three where the reaction occurs. Energetic particles resulting from the nuclear breakup ionize the helium three gas and are thereby detected as currents by an array of signal wires within the target chamber. In order to make a statistics limited …

Validation Of Argon From Underground Sources For Use In The Darkside-50 Detector, Thomas R. Alexander

Masters Theses

Liquid argon is an attractive target for dark matter searches due to its low cost and exemplary event discrimination. However, atmospherically derived argon contains the beta-emitter 39Ar which confounds the growth of dual-phase time projection chamber (TPC) style detectors to the ton-scale. The DarkSide Collaboration seeks to bypass this limitation by extracting argon from deep underground, from a location known to contain significantly less 39Ar than atmospherically derived argon. This thesis will summarize the e orts taken to produce the first batch of underground argon, focusing on the first operation of the underground argon in a dual-phase TPC to validate …

Impacts Of Land Cover And Climate Change On Water Resources In Suasco River Watershed, Ammara Talib

Masters Theses

Hydrological balance and biogeochemical processes in watershed are significantly influenced by changes in land use land cover (LULC) and climate change. Those changes can influence interception, evapotranspiration (ET), infiltration, soil moisture, water balance and biogeochemical cycling of carbon, nitrogen and other elements at regional to global scales. The impacts of these hydrological disturbances are generally reflected in form of increasing runoff rate and volume, more intense and frequent floods, decreasing groundwater recharge and base flow, elevated levels of sediments and increase in concentration of nutrients in both streams and shallow groundwater. Water quality of Sudbury, Assabet and Concord (SuAsCo) watershed …

Using Digital Elevation Models Derived From Airborne Lidar And Other Remote Sensing Data To Model Channel Networks And Estimate Fluvial Geomorphological Metrics, Noah Slovin

Masters Theses

Recent advances in remote-sensing technologies and analysis methods, specifically airborne-LiDAR elevation data and corresponding geographical information system (GIS) tools, present new opportunities for automated and rapid fluvial geomorphic (FGM) assessments that can cover entire watersheds. In this thesis, semi-automated GIS tools are used to extract channel centerlines and bankfull width values from digital elevation models (DEM) for five New England watersheds. For each study site, four centerlines are mapped. LiDAR and NED lines are delineated using ArcGIS spatial analyst tools with high-resolution (1-m to 2-m) LiDAR DEMs or USGS National Elevation Dataset (NED) DEMs, respectively. Resampled LiDAR decreases LiDAR DEM …

Impacts Of Three-Dimensional Non-Uniform Groundwater Flows For Quantifying Groundwater-Surface Water Interactions Using Heat As A Tracer, Jonathan M. Reeves

Masters Theses

Heat-as-a-tracer has become a common method to quantify surface water-groundwater interactions (SW/GW). However, the method relies on a number of assumptions that are likely violated in natural systems. Numerical studies have explored the effects of violating these fundamental assumptions to various degrees, such as heterogeneous streambed properties, two-dimensional groundwater flow fields and uncertainty in thermal parameters for the 1-dimensional heat-as-a-tracer method. No work to date has addressed the impacts of non-uniform, three-dimensional groundwater flows on the use of heat-as-a-tracer to quantify SW/GW interactions. Synthetic temperature time series were generated using COMSOL Multiphysics for a three-dimensional cube designed to represent a …

A High-Resolution Paleoenvironmental And Paleoclimatic History Of Extreme Events On The Laminated Sediment Record From Basin Pond, Fayette, Maine, U.S.A., Daniel R. Miller

Masters Theses

Future impacts from climate change can be better understood by placing modern climate trends into perspective through extension of the short instrumental records of climate variability. This is especially true for extreme climatic events, such as extreme precipitation and wildfires, as the period of instrumental records provides only a few examples and these have likely have been influenced by anthropogenic warming. Multi-parameter records showing the past range of climate variability can be obtained from lakes. Lakes are particularly good recorders of climate variability because sediment from the surrounding environment accumulates in lakes, making them sensitive recorders of climate variability and …

Bayesian Model Selection And Parameter Estimation For Gravitational Wave Signals From Binary Black Hole Coalescences, Alexander L. Lombardi

Masters Theses

In his theory of General Relativity, Einstein describes gravity as a geometric property of spacetime, which deforms in the presence of mass and energy. The accelerated motion of masses produces deformations, which propagate outward from their source at the speed of light. We refer to these radiated deformations as gravitational waves. Over the past several decades, the goal of the Laser Interferometer Gravitational-wave Observatory (LIGO) has been the search for direct evidence of gravitational waves from astrophysical sources, using ground based laser interferometers. As LIGO moves into its Advanced era (aLIGO), the direct detection of gravitational waves is inevitable. With …

Studying Nanoparticle/Cell And Nanoparticle/Biosurface Interaction With Mass Spectrometry, Singyuk Hou

Masters Theses

Nanoparticles (NPs) have been used widely in various fields ranging from biomedical applications to life science due to their highly tunable properties. It is essential to understanding how NPs interact with biological systems of interest, therefore, analytical platforms to efficiently track NPs from cell to animal level are essential. In this thesis, laser desorption ionization mass spectrometry (LDI-MS) and inductively-coupled plasma mass spectrometry (ICP-MS) has been developed and applied to quantify NP/cell and NP/biological surface interactions. These two methods provide fast, label-free and quantitative analysis. New capability of LDI-MS to differentiate cell surface-bound and internalized NPs were established and ICP-MS …

Examining The Mid- Brunhes Event In The Terrestrial Arctic: An Organic Geochemical Record From Lake El’Gygytgyn, Russia, Mary Helen Habicht

Masters Theses

The characteristic glacial and interglacial cycles of the Pleistocene underwent a climatic transition at ~430 ka known as the Mid- Brunhes Event (MBE). Many studies, particularly from the Southern Hemisphere have noted that after this transition, the amplitude of the climatic cycles increased. Despite the indication of an MBE signal in many globally distributed paleoclimate records, the geographic extent of the climatic transition remains unknown and its presence in northern hemisphere and terrestrial records is debated. Lake El’gygytgyn is located in the far- east Russian Arctic and provides the longest, most continuous record of Arctic climate (3.6 Ma). This study …

Urban Agriculture And Ecosystem Services: A Typology And Toolkit For Planners, Kathleen Doherty

Masters Theses

This thesis makes the connection between urban agriculture and a specific suite of ecosystem services and lays out a typology and toolkit for planners to take advantage of these ecosystem services. The services investigated here are: food production, water management, soil health, biodiversity, climate mitigation, and community development benefits. Research from a variety of fields was aggregated and synthesized to prove that urban agriculture can be beneficial for human as well as environmental health.

A set of urban agriculture typologies was generated to illustrate best practices to maximize a particular set of ecosystem services. The typologies are: production farm, stormwater …

Molecular Interpretation Of A Trigger For Controlling An Amine Isocyanate Polyurethane Reaction, Katherine V. Carrasquillo

Masters Theses

The temperature profile needed to complete the reaction between the sodium-diamine complex and the isocyanate terminated prepolymer has been established. The sodium diamine complex has the advantage of blocking the nearly instantaneous reaction between the diamine and isocyanate from taking place until it is released at elevated temperatures. Because of its low melting temperature (~40 °C) and its low molecular weight (low viscosity), this chain extension reaction is not dependent on the participation of the prepolymer. Instead, the rate of reaction is dependent on the dissolution of the 4,4’-methylenedianiline (MDA) complex into the system. The dissolution of the MDA complex …

Niche-Based Modeling Of Japanese Stiltgrass (Microstegium Vimineum) Using Presence-Only Information, Nathan Bush

Masters Theses

The Connecticut River watershed is experiencing a rapid invasion of aggressive non-native plant species, which threaten watershed function and structure. Volunteer-based monitoring programs such as the University of Massachusetts’ OutSmart Invasives Species Project, Early Detection Distribution Mapping System (EDDMapS) and the Invasive Plant Atlas of New England (IPANE) have gathered valuable invasive plant data. These programs provide a unique opportunity for researchers to model invasive plant species utilizing citizen-sourced data. This study took advantage of these large data sources to model invasive plant distribution and to determine environmental and biophysical predictors that are most influential in dispersion, and to identify …