Physical Sciences and Mathematics Commons^™

Applications Of Stochastic Control In Energy Real Options And Market Illiquidity, Christian Maxwell

Electronic Thesis and Dissertation Repository

We present three interesting applications of stochastic control in finance. The first is a real option model that considers the optimal entry into and subsequent operation of a biofuel production facility. We derive the associated Hamilton Jacobi Bellman (HJB) equation for the entry and operating decisions along with the econometric analysis of the stochastic price inputs. We follow with a Monte Carlo analysis of the risk profile for the facility. The second application expands on the analysis of the biofuel facility to account for the associated regulatory and taxation uncertainty experienced by players in the renewables and energy industries. A …

Computing Intersection Multiplicity Via Triangular Decomposition, Paul Vrbik

Electronic Thesis and Dissertation Repository

Fulton’s algorithm is used to calculate the intersection multiplicity of two plane curves about a rational point. This work extends Fulton’s algorithm first to algebraic points (encoded by triangular sets) and then, with some generic assumptions, to l many hypersurfaces.

Out of necessity, we give a standard-basis free method (i.e. practically efficient method) for calculating tangent cones at points on curves.

Production And Applications Of Formaldehyde-Free Phenolic Resins Using 5-Hydroxymethylfurfural Derived From Glucose In-Situ, Yongsheng Zhang

Electronic Thesis and Dissertation Repository

The phenol-formaldehyde (PF) resin manufacturing industry is facing a growing challenge with respect to concerns over human health, due to the use of carcinogenic formaldehyde and sustainability due to the use of petroleum-based phenol in PF resin manufacture. Glucose and its derivative, 5-hydroxymethylfurfural (5-HMF), have proven to be potential substitutes for formaldehyde in the synthesis of phenolic novolac resins.

This thesis investigated a number of glucose and 5-HMF resin systems including the curing of phenol-glucose novolac resin (PG) with a bis-phenol-A type epoxy. The curing process was modeled according to the Sestak-Berggren equation (S, B) using Málek methods. This was …

Star Cluster Populations In Compact Groups Of Galaxies, Konstantin Fedotov

Electronic Thesis and Dissertation Repository

In this thesis, I have explored the star cluster populations of several compact groups of galaxies, based on observations with the Advanced Camera for Surveys and the Wide Field Camera 3 on the Hubble Space Telescope. Low velocity dispersions and high galaxy number densities, the conditions of compact groups (in particular Hickson Compact Groups), represent an environment with frequent and prolonged interactions. Such environment can trigger the formation of star cluster populations associated with specific events. The BVI study has shown that star clusters can be used as a powerful tool for studying such events triggered by mergers and …

Protein-Protein Interaction Network Alignment, Yu Qian

Electronic Thesis and Dissertation Repository

Proteins are some of the building blocks of organisms. They usually perform their functions by interacting with each other and forming protein complexes. A protein -protein interaction network is a graph that consists of proteins as vertices and their interactions as edges. Protein-protein interaction network alignment is very important in identifying protein complexes and predicting protein functions. Many algorithms based on graph theory have been developed to improve the accuracy of alignment, but due to the sparsity of protein-protein interactions, the result is far from satisfactory.

We propose to improve the network alignment through adding protein interactions to existing PPI …

Response Of Soil Nitrification To The Veterinary Pharmaceuticals Monensin, Ivermectin And Zinc Bacitracin, Magda A. Konopka

Electronic Thesis and Dissertation Repository

Pharmaceutical residues can reach agricultural land through amendment with animal or human waste. Since 2010, a series of replicated plots received annual applications of ivermectin, monensin and zinc bacitracin, either singly or in a mixture, at 0.1 mg/kg and 10 mg/kg concentrations. I collected soil samples before and after the fourth annual application of pharmaceuticals and assayed them for functional changes and amoA gene abundance, a gene needed for ammonia oxidation. In 2013, I exposed the soils to 100 mg/kg in a laboratory experiment which resulted in acceleration of nitrification. Under 10 mg/kg treatments in the field the abundance of …

Polyglyoxylates: A New Class Of Triggerable Self-Immolative Polymers, Bo Fan

Electronic Thesis and Dissertation Repository

Self-immolative polymers, which degrade by an end-to-end depolymerization mechanism in response to the cleavage of a stabilizing end-cap from the polymer terminus, are of increasing interest for a wide variety of applications ranging from sensors to controlled release. However, the preparation of these materials often requires expensive, multi-step monomer syntheses and the degradation products such as quinone methides or phthalaldehydes are potentially toxic to humans and the environment. We demonstrate here that polyglyxoylates can serve as a new and versatile class of self-immolative polymers. Polymerization of the commercially available monomer ethyl glyoxylate, followed by end-capping with a 6-nitroveratryl carbonate provides …

Exploring The Reactivity Of Donor-Acceptor Cyclopropanes And The Synthesis Of (+/-)-Quebrachamine, Huck K. Grover

Electronic Thesis and Dissertation Repository

The development and utility of cyclopropanes is an ever-growing field within organic chemistry. In particular, donor-acceptor cyclopropanes have been used in a vast array of methods to access a variety of different hetero and carbocyclic molecular scaffolds. Recently, we have developed a Zn(NTf2)2 catalyzed tandem reaction consisting of a nucleophilic ringopening of 1,1-cyclopropanediesters by 2-alkynyl indoles followed by a Conia-ene ring closure, resulting in the efficient one-step synthesis of tetrahydrocarbazoles. These adducts may be further elaborated to carbazoles. The scope and limitations of this method were determined along with a mechanistic study into the function of the zinc catalyst. In …

The Effects Of Dissolution On The Silicon And Oxygen Isotope Compositions Of Silica Phytoliths, Andrea Prentice

Electronic Thesis and Dissertation Repository

The δ³⁰Si and δ¹⁸O values of silica phytoliths have applications for reconstructing paleoenvironmental conditions. This study examines the effect of partial dissolution and burning of phytoliths on their isotopic compositions, dissolution behaviour, and physical characteristics (specific surface area, mean particle size, and visual appearance) and discusses problems with the use of phytolith δ¹⁸O and δ³⁰Si values that have been modified in soils in paleoclimate reconstruction. Dissolution experiments were conducted in batch reactors under a range of pH (4-10) and temperature (4-44˚C) conditions. The δ¹⁸O and δ³⁰Si values of …

Land Use Interactions Drive Southwestern Ontario Stream Nutrient Concentrations, Renee L. Lazor

Electronic Thesis and Dissertation Repository

Human activities have transformed the landscape and altered natural habitats through intensive land uses including agriculture and urbanization. Identifying land use drivers of tributary nutrient concentrations and describing the magnitude and direction of their relationship are critical activities to improvement management of water quality in basins draining into the Great Lakes. The overarching goal of my thesis was to quantify the cumulative influence of spatial patterns in land use and land cover on variation of nutrient concentrations in tributaries of the Great Lakes. Biweekly water chemistry samples were collected in 29 streams located in southern Ontario between May and November, …

Poly(Ester Amide) And Poly(Ethyl Glyoxylate) Nanoparticles For Controlled Drug Release, Amira Mohamed Moustafa

Electronic Thesis and Dissertation Repository

The objective of this research was to develop polymeric nanoparticles (NPs) having improved drug release properties for drug delivery. Poly(ester amide)s (PEAs) are promising biodegradable polymers. PEA NPs were prepared via emulsification-evaporation and salting-out methods and optimized through by varying different processing parameters. Polymer-model drug conjugates based on PEAs containing L-aspartic acid and rhodamine B were synthesized and used for NP preparation. Release behavior was studied and compared to a control system with physically encapsulated rhodamine B. It was shown that the release of rhodamine B from the covalent system did not show the burst effect and exhibited a slower …

Fragmentation And Wake Formation In Faint Meteors: Implications For The Structure And Ablation Of Small Meteoroids, Edward Stokan

Electronic Thesis and Dissertation Repository

Meteors with peak magnitudes fainter than +2 are typically called faint meteors, resulting from the atmospheric entry and ablation of meteoroids less massive than 10^-4 kg. The processes of luminous wake formation and fragmentation, which occur during ablation, are poorly understood for faint meteors, and are important constraints for models of meteoroid structure. The goal of this work is to improve understanding of these processes through analysis of high-resolution intensified video observations, and creation of a detailed meteoroid ablation model.

In the first part of this work, thirty faint meteors observed with the Canadian Automated Meteor Observatory (CAMO) are …

Bidentate Ferrocenyl-Dithiol Reagents For Nanocluster Surface Functionalization, Yiyi Liu

Electronic Thesis and Dissertation Repository

Previous work using monodentate ferrocenyl-chalcogen reagents for nanocluster surface functionalization has indicated an effective way to involve ferrocene moieties onto the surface of these frameworks. However, the abilities of the large polynuclear nanocluster with ferrocene rich surface to form crystalline materials suitable for single crystal X-ray analysis proved to be limited. New bidentate ferrocenyl-chalcogen reagents have been synthesized and characterized in order to probe their ability in this case.

The preparation of new bidentate ferrocenyl chalcogen reagents 1,1’-fc(C{O}OCH₂CH₂SH)₂ (fc = ferrocenyl) and 1,1’-fc(C{O}NHCH₂CH₂SH)₂ are presented. Furthermore, the preparation of silylated …

Topographic Controls On N2o And N2 Efflux In A Temperate Forest, Eric M. Enanga

Electronic Thesis and Dissertation Repository

The release of greenhouse gases into the atmosphere is becoming an increasingly important problem due to the overwhelming evidence of the relationship between rising greenhouse gas concentrations and increased global temperatures. It is important that we gain a better understanding of the processes controlling the release of N₂O, a powerful greenhouse gas. Topographic influences on soil temperature, moisture, reduction-oxidation (redox) potential, dissolved organic carbon, and nitrate conditions, which in turn influence N₂O release, were investigated in a natural temperate forest ecosystem in Ontario, Canada. Wetland positions were observed to have the conditions most suited for N …

Morphological And Structural Mapping Of The Oudemans Impact Crater Layered Central Uplift, Mars, Bahareh Kasmai

Electronic Thesis and Dissertation Repository

Central uplifts in large meteorite impact craters provide valuable information about the subsurface geology of planetary bodies. Compared to impact craters on Earth, Martian central uplifts can be well exposed and can be mapped in detail by using satellite imagery. Central uplifts preserve morphological and structural features formed as result of the combination of emplacement during the impact process, post impact modification, and erosion over time. In this study, the Oudemans Crater central uplift (the largest central uplift with layers on Mars) was investigated. Oudemans (9.89 S, 268.1 E) is 124 km in diameter and is located in the Sinai …

Cohomology Of Absolute Galois Groups, Claudio Quadrelli

Electronic Thesis and Dissertation Repository

The main problem this thesis deals with is the characterization of profinite groups which are realizable as absolute Galois groups of fields: this is currently one of the major problems in Galois theory. Usually one reduces the problem to the pro-p case, i.e., one would like to know which pro-p groups occur as maximal pro-p Galois groups, i.e., maximal pro-p quotients of absolute Galois groups. Indeed, pro-p groups are easier to deal with than general profinite groups, yet they carry a lot of information on the whole absolute Galois group.

We define a new class of pro-p groups, called Bloch-Kato …

Environmental Health Effects Of Multiple Exposures: Systemic Risks And The Detroit River International Crossing Study, Tor H. Oiamo

Electronic Thesis and Dissertation Repository

This thesis examines cumulative exposures to traffic noise and outdoor air pollution on environmental and health related quality of life in Windsor, Ontario, and provides a critical analysis of the environmental assessment process for the Detroit River International Crossing (DRIC) Study. The research utilizes a systemic risk framework to understand environmental health and stress effects of cumulative exposures. The significance of this research is based on a relative absence of literature on the systemic health risks of cumulative exposures and the need to elucidate environmental annoyance as a health outcome for risk assessment. The objectives of the research were to …

Scale-Up Methodology For Bench-Scale Slurry Photocatalytic Reactors Using Combined Irradiation And Kinetic Modelling, Patricio J. Valades Pelayo

Electronic Thesis and Dissertation Repository

The present study focuses on developing a predictive methodology to scale-up a slurry annular photoreactor using a TiO₂ Degussa P25 from the bench-scale to a pilot-plant scale. The bench-scale photoreactor is a Photo-CREC-Water II, a 2.65 L internally-irradiated slurry annular photocatalytic reactor. The pilot-plant scale photoreactor is a Photo-CREC Water Solar Simulator, a 9.8 L pilot-plant photoreactor, externally irradiated by eight lamps.

The adopted methodology allows the independent validation of radiative and kinetic models avoiding cross-correlation issues. The proposed approach involves two Monte Carlo methods, to model the Radiative Transfer Equation (RTE) inside each photoreactor. With this end, a …

Kelvin Probe Force Microscopy On Graphene Thin Films For Solar Cell And Biosensing Applications, Faranak Sharifi

Electronic Thesis and Dissertation Repository

Graphene, a one atom thick planer sheet of carbon atoms, has attracted much attention in scientific and technological communities due to its remarkable electronic and physical properties. Graphene has been widely studied as an alternative to transparent conducting Indium Tin Oxide (ITO) electrodes in organic photovoltaics fabrication. Graphene platforms have also attracted interest in biological applications. However, large area graphene films are not yet widely commercialized because the fabrication techniques needed to prepare high quality graphene are expensive and non-scalable. More importantly, most of the low cost fabrication techniques require using toxic materials, which are not biocompatible for using graphene …

The Hα Spectroscopy Of Classical B-Emission Stars, Jessie M. Silaj

Electronic Thesis and Dissertation Repository

Classical B-emission (Be) stars are rapidly-rotating, massive stars that possess a dense, equatorial, gaseous disk. The presence of a disk was first inferred from the Balmer series emission that these stars exhibit, and Hα emission lines remain both a hallmark observational feature and one of the key diagnostics in determining the physical conditions within the disk.

In the first chapter of this thesis, we investigate the possible role of line-driven winds in disk formation. To test if line-driven winds could supply enough material to account for the equatorial disk, we check for the presence of Hα emission in the models …

Organic Solar Cells: Electrodes, Performance Enhancement And Degradation Mechanisms, Reginald J. Bauld

Electronic Thesis and Dissertation Repository

In this thesis I focus on a number of aspects associated with the fabrication and characterization of organic photovoltaics. Specifically, my work focuses on evaluating solution processed graphene electrodes for use in organic photovoltaics, improving the performance of indium tin oxide transparent contacts by coating them with Au nanoparticles, and understanding the degradation pathways of Poly(3-hexylthiophene-2,5-diyl): Phenyl-C61-butyric acid methyl ester (P3HT:PCBM) organic solar cells. In my work on graphene electrodes for organic solar cells I worked out a relationship between the sheet resistance and the film transmittance that is useful to optimize such electrodes. Investigation of organic solar cell degradation …

Bm3d Image Denoising Using Ssim Optimized Wiener Filter, Mahmud Hasan

Electronic Thesis and Dissertation Repository

Image denoising is considered as a salient pre-processing in sophisticated imaging applications. Over decades, numerous studies have been conducted in denoising. Recently proposed Block Matching and 3D (BM3D) Filtering added a new dimension to the study of denoising. BM3D is the current state-of-the-art of denoising and is capable of achieving better denoising as compared to any other existing method. However, the performance is not yet on the bound for image denoising. Therefore, there is scope to improve BM3D to achieve high quality denoising. In this thesis, to improve BM3D, we first attempted to improve Wiener filter (the core of BM3D) …

Controls On Syenite-Hosted Gold Mineralization In The Western Timmins Camp, Robert A. Campbell

Electronic Thesis and Dissertation Repository

The Abitibi granite-greenstone belt has long been known for its’ world-class Archean

lode gold deposits. With exploration and production commencing in the early nineteen

hundreds and continuing into the twenty-first century, this prolific mining camp is rich

in history, research and precious/base metals. The Thunder Creek deposit and Hwy-144 gold prospect are two recently discovered and exploited syenite associated gold plays in the Timmins Camp. The research compares the Thunder Creek and Hwy-144 properties providing new observations on the variable mechanisms for gold mineralization that can change over a short strike distance (0.5-1.5 km’s) hosted in a geologically similar environment. …

Allostratigraphy Of The Upper Ordovician Blue Mountain Formation, Southwestern Ontario, Canada, Sarah N. Sweeney

Electronic Thesis and Dissertation Repository

The Upper Ordovician units in Southwestern Ontario record the distal response to the development of the Taconic Appalachian foreland basin. The proximal representation in Ohio and Pennsylvania, contain the Utica/Point Pleasant Play (!). The relationship between the proximal and distal portions of the Taconic Appalachian foreland basin is not clearly defined due to limited chronostratigraphic data and only lithostratigraphic correlations in southwestern Ontario. The first step in evaluating the relationship between the Upper Ordovician succession in Ontario and that in the United States is to develop a high frequency allostratigraphic framework that can be integrated and compared to the frameworks …

Dynamic Resource Management In Virtualized Data Centres, Gaston Keller

Electronic Thesis and Dissertation Repository

In the last decade, Cloud Computing has become a disruptive force in the computing landscape, changing the way in which software is designed, deployed and used over the world. Its adoption has been substantial and it is only expected to continue growing. The growth of this new model is supported by the proliferation of large-scale data centres, built for the express purpose of hosting cloud workloads. These data centres rely on systems virtualization to host multiple workloads per physical server, thus increasing their infrastructures' utilization and decreasing their power consumption. However, the owners of the cloud workloads expect their applications' …

Diffusion And Adsorption Coefficients Of Aromatic Hydrocarbons In Gas Chromatography Capillary Columns, Gabriela Navarro Tovar

Electronic Thesis and Dissertation Repository

This study focuses on a mathematical description of aromatic species elution peaks from a gas chromatographic BPX5 capillary column. Using the chromatographic peaks, statistical moments are calculated for toluene, naphthalene, phenol and 2-naphthol. This thesis reports two modelling approaches involving laminar gas flow, distribution coefficients (K_s) and diffusion coefficients in the stationary phase (D_s).

Firstly, a model with equilibrium adsorption is considered to describe symmetric peaks for toluene and naphthalene. Moreover, a model with non-equilibrium adsorption is proposed to describe asymmetric peaks of phenol and 2-napthol. In addition to the K_s and D …

Runoff Generation In A Tropical Dry Forest Watershed: Processes, Patterns And Connectivity, Kegan K. Farrick

Electronic Thesis and Dissertation Repository

The lack of understanding regarding the controls that govern runoff generation in tropical dry forests represent a critical gap in the hillslope and catchment hydrology literature. Tropical dry forests account for approximately 42% of the global tropical forests, but represent less than 1% of the forest hydrology literature. Three complementary studies were undertaken in a small tropical dry forest watershed, Mexico, to assess the controls that govern the retention and release of a rainfall in the catchment as runoff. In the first study, the high soil surface hydraulic conductivities, absence of a water repellent surface and low rainfall intensities during …

Potential Effects Of Changing Climate On The Physical, Chemical, And Biological Characteristics Of Alpine Lakes, Uinta Mountains, Utah, Usa, Shirley Ngai

Electronic Thesis and Dissertation Repository

Relationships between climate variables, lake characteristics and diatom community composition were determined for five lakes in the Uinta Mountains, Utah (USA) from spring 2010 to autumn 2013 to provide information to help predict the effects of climate change on lake ecosystems. Surface water temperatures increased with decreasing elevation although microclimates affected this relationship. Deeper water temperatures increased or stayed the same with increasing elevation, probably due to greater transparency or convective heating. Total phosphorus (TP) and chl a concentrations decreased in the spring/summer with warmer fall/winter temperatures, and nitrates in the spring increased with increased fall/winter precipitation. A significant correlation …

Censored Time Series Analysis, Nagham Muslim Mohammad

Electronic Thesis and Dissertation Repository

Environmental data is frequently left or right censored. This is due to the fact that the correct value for observed values that are below or above some threshold or detection point are inaccurate so that it is only known for sure that the true value is below or above that threshold. This is frequently important with water quality and air quality time series data. Interval censoring occurs when the correct values of the data are known only for those values falling above some lower threshold and below some upper threshold. Censoring threshold values may change over time, so multiple censor …

Photochromic Molecular Materials For The Controlled Organization Of Nanoparticles, Kristen Elise Snell

Electronic Thesis and Dissertation Repository

The displacement of polystyrene nanoparticles promoted by bulk azo mass transfer using interferential light illumination will be discussed. For this a variety of different push pull small azo molecules were synthesis and characterized, changing the polarity, hydrophobicity and bulky groups around the azo moiety. These small dyes appear to orientate quicker than similarly report azo polymers, of entanglement of the azobenzene group in the polymeric backbone. These dyes were used to form surface relief grating on the thin films due to the bulk mass transfer. This mass transfer was exploited to align polystyrene nanoparticles in the crests and troughs of …