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2008

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Full-Text Articles in Physical Sciences and Mathematics

Quad General Tree Drawing Algorithm And General Trees Characterization: Towards An Environment For The Experimental Study On General Tree Drawing Algorithms, Chu Yao Dec 2008

Quad General Tree Drawing Algorithm And General Trees Characterization: Towards An Environment For The Experimental Study On General Tree Drawing Algorithms, Chu Yao

Theses and Dissertations

Information visualization produces (interactive) visual representations of abstract data to reinforce human cognition and perception; thus enabling the viewer to gain knowledge about the internal structure of the data and causal relationships in it. The visualization of information hierarchies is concerned with the presentation of abstract hierarchical information about relationships between various entities. It has many applications in diverse domains such as software engineering, information systems, biology, and chemistry. Information hierarchies are typically modeled by an abstract tree, where vertices are entities and edges represent relationships between entities. The aim of visualizing tree drawings is to automatically produce drawings of …


Sub-Circuit Selection And Replacement Algorithms Modeled As Term Rewriting Systems, Eric D. Simonaire Dec 2008

Sub-Circuit Selection And Replacement Algorithms Modeled As Term Rewriting Systems, Eric D. Simonaire

Theses and Dissertations

Intent protection is a model of software obfuscation which, among other criteria, prevents an adversary from understanding the program’s function for use with contextual information. Relating this framework for obfuscation to malware detection, if a malware detector can perfectly normalize a program P and any obfuscation (variant) of the program O(P), the program is not intent protected. The problem of intent protection on programs can also be modeled as intent protection on combinational logic circuits. If a malware detector can perfectly normalize a circuit C and any obfuscation (variant) O(C) of the circuit, the circuit is not intent protected. In …


Nondestructive Evaluation Of Aircraft Composites Using Terahertz Time Domain Spectroscopy, Christopher D. Stoik Dec 2008

Nondestructive Evaluation Of Aircraft Composites Using Terahertz Time Domain Spectroscopy, Christopher D. Stoik

Theses and Dissertations

Terahertz (THz) time domain spectroscopy (TDS) was assessed as a nondestructive evaluation technique for aircraft composites. Material properties of glass fiber composite were measured using both transmission and reflection configuration. The interaction of THz with a glass fiber composite was then analyzed, including the effects of scattering, absorption, and the index of refraction, as well as effective medium approximations. THz TDS, in both transmission and reflection configuration, was used to study composite damage, including voids, delaminations, mechanical damage, and heat damage. Measurement of the material properties on samples with localized heat damage showed that burning did not change the refractive …


Book I, Otto Vogl: Papers And Patents, 1948-1970, Jane C. Vogl Dec 2008

Book I, Otto Vogl: Papers And Patents, 1948-1970, Jane C. Vogl

Emeritus Faculty Author Gallery

Books I-XII include citations to Otto Vogl's publications and patents. Printed versions of these twelve volumes are also available in the Integrated Sciences and Engineering Library of the University of Massachusetts in Amherst. MA, Lederle Graduate Research Center. The printed volumes include the full reprints of all cited publications.


Centers Of Polymer Science: Introduction, Otto Vogl Dec 2008

Centers Of Polymer Science: Introduction, Otto Vogl

Emeritus Faculty Author Gallery

Centers of Polymer Science describes polymer research activities taking place in Europe, Asia, and Australia primarily during the years between 1980 and 2000. This series of articles shows and records the activity in Polymer Science in this part of polymer history.


Green Roofs For A Green Town: Possibilities Of Green Roof Implementation In The Town Of Normal, Lindsey Sihau, '09 Dec 2008

Green Roofs For A Green Town: Possibilities Of Green Roof Implementation In The Town Of Normal, Lindsey Sihau, '09

Outstanding Senior Seminar Papers

Green roofs have been growing in popularity throughout the world. Scientists have been studying them since the 1980’s. This research project reviews the literature regarding both the benefits and barriers to green roof construction and management. Policies around the nation are then examined and analyzed. Suggestions are made regarding possible additions to the local Stormwater Management Policy that would emphasize the importance of sustainable building techniques such as green roofs, and hopefully offer incentive to their implementation.


A Three-Dimensional Pattern-Space Representation For Volumetric Arrays, William C. Barott, Paul G. Steffes Dec 2008

A Three-Dimensional Pattern-Space Representation For Volumetric Arrays, William C. Barott, Paul G. Steffes

Publications

A three-dimensional pattern-space representation is presented for volumetric arrays. In this representation, the radiation pattern of an array is formed by the evaluation of the three-dimensional pattern-space on a spherical surface. The scan angle of the array determines the position of this surface within the pattern-space. This pattern-space representation is used in conjunction with a genetic algorithm to minimize the sidelobe levels exhibited by a thinned volumetric array during scanning.


Minerva 2008, The Honors College Dec 2008

Minerva 2008, The Honors College

Minerva

This issue of Minerva includes an article on the completion of the restoration of Colvin Hall; a reflection by Ruth Nadelhaft, former UMaine Honors program director; and an article on Honors alumnus and Nobel Peace Prize winner Bernard Lown and his 2008 Rezendes Visiting Scholar in Ethics Lecture/Distinguished Honors Graduate Lecture.


Detection Of An So2 Plume Over Sapporo, Japan From The Eruption Of Mt. Kasatochi Using A Balloon Sounding Technique, Gary A. Morris, Jun Hirokawa, Masatomo Fujiwara, Fumio Hasebe, Keisuke Ishida, Nicholay Krotkov, Mark R. Schoeberl, Walter Komhyr, Barry Lefer, James Flynn Dec 2008

Detection Of An So2 Plume Over Sapporo, Japan From The Eruption Of Mt. Kasatochi Using A Balloon Sounding Technique, Gary A. Morris, Jun Hirokawa, Masatomo Fujiwara, Fumio Hasebe, Keisuke Ishida, Nicholay Krotkov, Mark R. Schoeberl, Walter Komhyr, Barry Lefer, James Flynn

Physics and Astronomy Faculty Presentations

During the month of August 2008, 10 ozonesondes were launched from Hokkaido University in Sapporo, Japan as part of a study to examine regional pollution during the Olympic period. Seven of these soundings included a second instrument with a filter designed to remove SO2 from the intake air stream. SO2 interferes with the normal chemistry of the electrochemical cell (ECC) method for ozone detection, with the net result being that each molecule of SO2 registers as minus one molecule of O3. Thus the unfiltered sonde reports [O3] - [SO2] while the filtered sonde reports [O3]. Laboratory tests prior to launch …


Detection Of An So2 Plume Over Sapporo, Japan From The Eruption Of Mt. Kasatochi Using A Balloon Sounding Technique, Gary A. Morris, Jun Hirokawa, Masatomo Fujiwara, Fumio Hasebe, Keisuke Ishida, Nicholay Krotkov, Mark R. Schoeberl, Walter Komhyr, Barry Lefer, James Flynn Dec 2008

Detection Of An So2 Plume Over Sapporo, Japan From The Eruption Of Mt. Kasatochi Using A Balloon Sounding Technique, Gary A. Morris, Jun Hirokawa, Masatomo Fujiwara, Fumio Hasebe, Keisuke Ishida, Nicholay Krotkov, Mark R. Schoeberl, Walter Komhyr, Barry Lefer, James Flynn

Gary A. Morris

During the month of August 2008, 10 ozonesondes were launched from Hokkaido University in Sapporo, Japan as part of a study to examine regional pollution during the Olympic period. Seven of these soundings included a second instrument with a filter designed to remove SO2 from the intake air stream. SO2 interferes with the normal chemistry of the electrochemical cell (ECC) method for ozone detection, with the net result being that each molecule of SO2 registers as minus one molecule of O3. Thus the unfiltered sonde reports [O3] - [SO2] while the filtered sonde reports [O3]. Laboratory tests prior to launch …


Centers Of Polymer Science: Introduction, Otto Vogl Dec 2008

Centers Of Polymer Science: Introduction, Otto Vogl

Otto Vogl

Centers of Polymer Science describes polymer research activities taking place in Europe, Asia, and Australia primarily during the years between 1980 and 2000. This series of articles shows and records the activity in Polymer Science in this part of polymer history.


Book I, Otto Vogl: Papers And Patents, 1948-1970, Jane C. Vogl Dec 2008

Book I, Otto Vogl: Papers And Patents, 1948-1970, Jane C. Vogl

Otto Vogl

Books I-XII include citations to Otto Vogl's publications and patents. Printed versions of these twelve volumes are also available in the Integrated Sciences and Engineering Library of the University of Massachusetts in Amherst. MA, Lederle Graduate Research Center. The printed volumes include the full reprints of all cited publications.


A Model Based Fault Detection And Prognostic Scheme For Uncertain Nonlinear Discrete-Time Systems, Balaje T. Thumati, Jagannathan Sarangapani Dec 2008

A Model Based Fault Detection And Prognostic Scheme For Uncertain Nonlinear Discrete-Time Systems, Balaje T. Thumati, Jagannathan Sarangapani

Electrical and Computer Engineering Faculty Research & Creative Works

A new fault detection and prognostics (FDP) framework is introduced for uncertain nonlinear discrete time system by using a discrete-time nonlinear estimator which consists of an online approximator. A fault is detected by monitoring the deviation of the system output with that of the estimator output. Prior to the occurrence of the fault, this online approximator learns the system uncertainty. In the event of a fault, the online approximator learns both the system uncertainty and the fault dynamics. A stable parameter update law in discrete-time is developed to tune the parameters of the online approximator. This update law is also …


Neural Network Output Feedback Control Of A Quadrotor Uav, Jagannathan Sarangapani, Travis Alan Dierks Dec 2008

Neural Network Output Feedback Control Of A Quadrotor Uav, Jagannathan Sarangapani, Travis Alan Dierks

Electrical and Computer Engineering Faculty Research & Creative Works

A neural network (NN) based output feedback controller for a quadrotor unmanned aerial vehicle (UAV) is proposed. The NNs are utilized in the observer and for generating virtual and actual control inputs, respectively, where the NNs learn the nonlinear dynamics of the UAV online including uncertain nonlinear terms like aerodynamic friction and blade flapping. It is shown using Lyapunov theory that the position, orientation, and velocity tracking errors, the virtual control and observer estimation errors, and the NN weight estimation errors for each NN are all semi-globally uniformly ultimately bounded (SGUUB) in the presence of bounded disturbances and NN functional …


Mapping Reality Into Virtual Worlds, Josh Mcfarlane Dec 2008

Mapping Reality Into Virtual Worlds, Josh Mcfarlane

Computer Science and Computer Engineering Undergraduate Honors Theses

As virtual worlds become more prevalent, they become increasingly useful as a means of information dissemination. This thesis examines the possible connections between real world objects and their virtual world counterparts. We look at how, by attaching sensors to an object, or by using a smart object with embedded sensors, the information can be relayed to a server. From this information, it will be possible to create a duplicate object in the virtual world and have it mirror the real world object in terms of state and movement. Almost all current solutions for remotely viewing a room or area are …


Steganography In Ipv6, Barret Miller Dec 2008

Steganography In Ipv6, Barret Miller

Computer Science and Computer Engineering Undergraduate Honors Theses

Steganography is the process of hiding a secret message within another message such that it is difficult to detect the presence of the secret message. In other words, the existence of the secret message is hidden. A covert channel refers to the actual medium that is used to communicate the information such as a message, image, or file. This honors thesis uses steganography within the source address fields of Internet Protocol Version 6 (IPv6) packets to create a covert channel through which clandestine messages are passed from one party to another. A fully functional computer program was designed and written …


Neural-Network-Based State Feedback Control Of A Nonlinear Discrete-Time System In Nonstrict Feedback Form, Pingan He, Jagannathan Sarangapani Dec 2008

Neural-Network-Based State Feedback Control Of A Nonlinear Discrete-Time System In Nonstrict Feedback Form, Pingan He, Jagannathan Sarangapani

Electrical and Computer Engineering Faculty Research & Creative Works

In this paper, a suite of adaptive neural network (NN) controllers is designed to deliver a desired tracking performance for the control of an unknown, second-order, nonlinear discrete-time system expressed in nonstrict feedback form. In the first approach, two feedforward NNs are employed in the controller with tracking error as the feedback variable whereas in the adaptive critic NN architecture, three feedforward NNs are used. In the adaptive critic architecture, two action NNs produce virtual and actual control inputs, respectively, whereas the third critic NN approximates certain strategic utility function and its output is employed for tuning action NN weights …


A Three-Dimensional, Time-Dependent Circulation Model Of Utah Lake, Eric V. Callister Dec 2008

A Three-Dimensional, Time-Dependent Circulation Model Of Utah Lake, Eric V. Callister

All Graduate Theses and Dissertations, Spring 1920 to Summer 2023

Spatial and temporal variations of Utah Lake’s flow field were modeled using the Estuary Lake and Computer Model from the Centre for Water Research (CWR-ELCOM) at the University of Western Australia as part of an effort to increase understanding of the lake’s natural processes in order to restore the lake to its pristine, clear-water state and preserve the habitat of the June sucker, an endangered species. The model was validated using temperature measurements taken by sensors in 2007. The water temperature was a strong function of air temperature and incident short wave radiation, and was influenced to a lesser degree …


Intergranular Phases In Cyclically Annealed Yba2cu3o7-X And Their Implications For Critical Current Densities, Andrew Peter Clarke Dec 2008

Intergranular Phases In Cyclically Annealed Yba2cu3o7-X And Their Implications For Critical Current Densities, Andrew Peter Clarke

All Graduate Theses and Dissertations, Spring 1920 to Summer 2023

We report changes in the intergranular material and grain morphology of YBa2Cu3O7-x during cyclic anneals between 780 and 980 ºC in oxygen at atmospheric pressure. Two endothermic reactions were detected: (a) the eutectic reaction of YBa2Cu3O7-x with CuO and BaCuO2 at 900 ºC (enthalpy ∆Ha) and (b) the peritectic reaction of YBa2Cu3O7-x with CuO at 950 ºC (∆Hb). During the first anneal, only reaction (b) is detected, and although it should only occur if there is an excess of CuO, …


A C To Register Transfer Level Algorithm Using Structured Circuit Templates: A Case Study With Simulated Annealing, Jonathan D. Phillips Dec 2008

A C To Register Transfer Level Algorithm Using Structured Circuit Templates: A Case Study With Simulated Annealing, Jonathan D. Phillips

All Graduate Theses and Dissertations, Spring 1920 to Summer 2023

A tool flow is presented for deriving simulated annealing accelerator circuits on a field programmable gate array (FPGA) from C source code by exploring architecture solutions that conform to a preset template through scheduling and mapping algorithms. A case study carried out on simulated annealing-based Autonomous Mission Planning and Scheduling (AMPS) software used for autonomous spacecraft systems is explained. The goal of the research is an automated method for the derivation of a hardware design that maximizes performance while minimizing the FPGA footprint. Results obtained are compared with a peer C to register transfer level (RTL) logic tool, a state-of-the-art …


Distributing Complementary Resources Across Multiple Periods With Stochastic Demand, Shih-Fen Cheng, John Tajan, Hoong Chuin Lau Dec 2008

Distributing Complementary Resources Across Multiple Periods With Stochastic Demand, Shih-Fen Cheng, John Tajan, Hoong Chuin Lau

Research Collection School Of Computing and Information Systems

In this paper, we evaluate whether the robustness of a market mechanism that allocates complementary resources could be improved through the aggregation of time periods in which resources are consumed. In particular, we study a multi-round combinatorial auction that is built on a general equilibrium framework. We adopt the general equilibrium framework and the particular combinatorial auction design from the literature, and we investigate the benefits and the limitation of time-period aggregation when demand-side uncertainties are introduced. By using simulation experiments, we show that under stochastic conditions the performance variation of the process decreases as the time frame length (time …


Study On The Texturization Of C-Si Wafers By Different Kinds Of Alkaline For Heterojunction Solar Cells, Yu-Hua Dou, Yu-Qin Zhou, Mei-Fang Zhu, Shuang Song, Feng-Zhen Liu, Jin-Long Liu, Zhan-Jun Zhang Nov 2008

Study On The Texturization Of C-Si Wafers By Different Kinds Of Alkaline For Heterojunction Solar Cells, Yu-Hua Dou, Yu-Qin Zhou, Mei-Fang Zhu, Shuang Song, Feng-Zhen Liu, Jin-Long Liu, Zhan-Jun Zhang

Journal of Electrochemistry

The texturization of(100) crystalline silicon(c-Si) wafer was studied by field-emission scanning electron microscope using different kinds of etchant: sodium hydroxide,sodium carbonate and tribasic sodium phosphate.By optimizing the etching parameters,the lowest values of averaged reflectance(Rav) were obtained to be 9.70% for NaOH,9.76% for Na2CO3 and 8.63% for Na3PO4·12H2O,which is comparable to that of the wafer with textured surface covered with an anti-reflection coating of either silicon nitride or thermally grown silicon dioxide.The relation of Rav and surface morphology of textured wafer was analyzed.Moreover,special emphasis was put on the role of isopropyl alcohol(IPA) and sodium bicarbonate for texturization.It is proved that IPA …


Combustion Product Characterization Of The Iron-Heated Powders In Thermal Batteries, Jin Chong, Xue-Ping Gao, Ji-Qiang Wang Nov 2008

Combustion Product Characterization Of The Iron-Heated Powders In Thermal Batteries, Jin Chong, Xue-Ping Gao, Ji-Qiang Wang

Journal of Electrochemistry

The combustion products of thermal battery used iron-heated powders have been studied.It is identified by X-ray diffraction(XRD) analysis that the main compositions of the combustion products are Fe、FeO and KCl.The transmission electron microscopy(TEM) shows a typical core-shell structure with un-reacted Fe particle core coated by FeO shell with a shell thickness of around 200 nm.The combusted iron-heated powders exhibit no metal property,which is contrast to previous assumption.Further measurement indicates that at the ambient temperature the combustion products show semiconductor property of the p-type with conductivity in the order of 103 S·cm-1,which is five order lower than that of the iron …


Studies Of Surface Diffusion In Pemfc Electrodes, Jiang-Shui Luo, Jian Chen, Bao-Lian Yi, Chuan-Sin Cha, Hua-Min Zhang Nov 2008

Studies Of Surface Diffusion In Pemfc Electrodes, Jiang-Shui Luo, Jian Chen, Bao-Lian Yi, Chuan-Sin Cha, Hua-Min Zhang

Journal of Electrochemistry

A PEMFC electrode consisting of dual-layer catalyst layer(CL) was fabricated in this work.The outer CL was Nafion-free,while the inner CL was Nafion-bonded.The effects of Pt/C catalyst in the outer CL that did not contact with Nafion on the current generation in PEMFC electrodes were investigated.Cyclic voltammetric studies indicated that the Pt/C catalyst in the outer CL without direct contact with Nafion was still electrochemically active in taking part in the adsorption/desorption of hydrogen and the electrochemical oxidation/reduction of the oxygen-containing species occurring at the interface of "Pt/Nafion" in the inner CL.The polarization curves showed that the output voltage of the …


Direct Electrochemistry Of Chloroperoxidase At Gc Electrode Modified With Swnts, Hong-Xia Zhang, Xia-Qin Wu, Wen-Jing Hou, Wen Xie, Zhong-Qing Lu, Rong Wang, He-Xing Li Nov 2008

Direct Electrochemistry Of Chloroperoxidase At Gc Electrode Modified With Swnts, Hong-Xia Zhang, Xia-Qin Wu, Wen-Jing Hou, Wen Xie, Zhong-Qing Lu, Rong Wang, He-Xing Li

Journal of Electrochemistry

The chloroperoxidase(CPO) was immobilized onto the surface of SWNTs modified electrodes.The electrochemical behaviors of modified electrode have been investigated by cyclic voltammetry.The appearance of a pair of well-defined redox peaks in the CV curve indicated that SWNTs can promote the electron transfer reaction of CPO.The results of cyclic voltammetry in PBS of different pH,from 3~9,showed that the reaction of CPO on the modified electrode was with equal numbers of electron and protein.This readily prepared SWNTs modified electrode showed excellent stability and good catalysis to O2.


Synthesis Of The Lifepo_4 By Co Reduction:Reaction Mechanism And Kinetics, Yun-Hua Chen, Yong Yang Nov 2008

Synthesis Of The Lifepo_4 By Co Reduction:Reaction Mechanism And Kinetics, Yun-Hua Chen, Yong Yang

Journal of Electrochemistry

LiFePO4 cathode material was synthesized by CO reducing FePO4 and LiOH precursors.The structure,morphology and electrochemical performances of such LiFePO4 material were characterized by XRD,SEM and charge-discharge tests.It was shown that the particle size of the LiFePO4 synthesized with 5% excess of LiOH in the precursor was about 200 nm.By carbon coating,the LiFePO4 electrode was able to deliver a reversible capacity of 158 mAh·g-1 at 0.1C discharge rate.Temperature-programmed X-ray diffraction was employed to monitor the reaction during the formation of LiFePO4,and Li3Fe2(PO4)3 was found to be an intermediate by analyzing the time-resolved XRD patterns.Kinetic study indicates that nucleation and their growth …


High Performance Fuel Cell Catalyst And 5kw Pemfc Stack Without Humidification At Room Temperature And Atmosphere, Xin-Fa Hu, Min Chen, Shi-Jun Liao Nov 2008

High Performance Fuel Cell Catalyst And 5kw Pemfc Stack Without Humidification At Room Temperature And Atmosphere, Xin-Fa Hu, Min Chen, Shi-Jun Liao

Journal of Electrochemistry

The Pt/C catalyst with high dispersion and high performance was prepared successfully by an organic colloidal method and small batch production(10g) of Pt/C catalyst has been realized.The particle sizes of the active components in the catalyst could be as small as 2.8 nm and the active surface area was up to 450 m2/g.A high performance membrane-electrode assembly(MEA) with surface area of 275 cm2 has been prepared by using the home-made catalyst with a catalyst coated membrane method invented in the lab,and a 5 kW stack has been assembled.The stack showed working 10 h at room temperature,atmosphere and without humidification.


Ceo_2/Pt Composite Electrodes And Their Catalytic Performance, Ying Fu, Zi-Dong Wei, Yong-Chao Feng, Xin-Li Ma, Ming-Jia Liao, Chao Liao, Jie Zhang, Huan Zhang Nov 2008

Ceo_2/Pt Composite Electrodes And Their Catalytic Performance, Ying Fu, Zi-Dong Wei, Yong-Chao Feng, Xin-Li Ma, Ming-Jia Liao, Chao Liao, Jie Zhang, Huan Zhang

Journal of Electrochemistry

In this paper,the cerium oxide(CeO2) nanoparticles were electrochemically deposited on a Pt electrode by potentiostatic deposition(psd) and potential pulse deposition(ppd) to form CeO2/Pt composite electrodes,CeO2/Pt(psd) and CeO2/Pt(ppd).The properties of the CeO2 were characterized by field emission scanning electron microscope(FESEM) and X-ray diffraction(XRD).The results showed that the CeO2 nanoparticles prepared by psd and ppd were homogeneous and dense.The methanol oxidation reaction(MOR) and oxygen reduction reaction(ORR) on the Pt electrode were enhanced with the introduction of CeO2 into Pt.In addition,the catalytic capability of the CeO2/Pt electrode can be further improved after dissolution of part of CeO2 on the composite electrode in H2SO4.The …


Corrosion Inhibition Of Magnesium Alloy In 3.5% Nacl Medium By Tungstate, Ling-Jie Li, Zhi-Ming Yao, Jing-Lei Lei, Dong-Hai He, Sheng-Tao Zhang, Fu-Sheng Pan Nov 2008

Corrosion Inhibition Of Magnesium Alloy In 3.5% Nacl Medium By Tungstate, Ling-Jie Li, Zhi-Ming Yao, Jing-Lei Lei, Dong-Hai He, Sheng-Tao Zhang, Fu-Sheng Pan

Journal of Electrochemistry

Electrochemical impedance spectroscopy(EIS),Tafel polarization curves and scanning electron microscopy(SEM) were used to study the corrosion inhibition of AZ61 magnesium alloy in 3.5% NaCl medium with tungstate.Results showed that tungstate demonstrates strong inhibition to the corrosion of AZ61 magnesium alloy.At the concentration of 0.01 mol/L,tungstate has a high inhibition efficiency 75.5%.Tungstate is an anodic inhibitor that mainly inhibited the anodic reactions of magnesium alloy through forming a compact protective layer that covered the magnesium alloy surface active sites.


Voltammetric Determination Of L-Cysteine At Bipyrine Bridged Copper(Ⅱ) Complex Modified Glassy Carbon Electrode, Ming-Yan Wang, Fan Yang, Sheng-Yu Zhang, Xing-You Xu, Xu-Jie Yang Nov 2008

Voltammetric Determination Of L-Cysteine At Bipyrine Bridged Copper(Ⅱ) Complex Modified Glassy Carbon Electrode, Ming-Yan Wang, Fan Yang, Sheng-Yu Zhang, Xing-You Xu, Xu-Jie Yang

Journal of Electrochemistry

A modified electrode has been constructed by depositing a novel copper(Ⅱ) complex 2biPy(ClO4)4 on the glassy carbon electrode through the method of cyclic voltammetry(CV).It was found that the modified electrode exhibited high electrocatalytic activity toward L-Cysteine oxidation with good reproducibility and high sensitivity.The peak current of semi-derivative linear scan was proportional to the concentration of L-cys in the range of 1×10-6~3×10-4 mol·L-1.The detection limit was 5×10-7 mol·L-1.