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2003

Atmospheric Sciences

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Articles 1 - 30 of 33

Full-Text Articles in Physical Sciences and Mathematics

Breaking Of Thunderstorm-Generated Gravity Waves As A Source Of Short-Period Ducted Waves At Mesopause Altitudes, Jonathan B. Snively, Victor P. Pasko Dec 2003

Breaking Of Thunderstorm-Generated Gravity Waves As A Source Of Short-Period Ducted Waves At Mesopause Altitudes, Jonathan B. Snively, Victor P. Pasko

Publications

Numerical simulation results indicate that the breaking of atmospheric gravity waves generated by tropospheric convection can excite short-period secondary waves, which are trapped in the lower thermospheric duct and which closely resemble quasi-monochromatic structures commonly observed in airglow imaging experiments.


The Extratropical Transition Of Tropical Cyclones: Forecast Challenges, Current Understanding, And Future Directions, Sarah C. Jones, Patrick A. Harr, Jim Abraham, Lance F. Bosart, Peter J. Bowyer, Jenni L. Evans, Deborah E. Hanley, Barry N. Hanstrum, Robert E. Hart, Francois Lalaurette, Mark R. Sinclair, Roger K. Smith, Chris Thorncroft Dec 2003

The Extratropical Transition Of Tropical Cyclones: Forecast Challenges, Current Understanding, And Future Directions, Sarah C. Jones, Patrick A. Harr, Jim Abraham, Lance F. Bosart, Peter J. Bowyer, Jenni L. Evans, Deborah E. Hanley, Barry N. Hanstrum, Robert E. Hart, Francois Lalaurette, Mark R. Sinclair, Roger K. Smith, Chris Thorncroft

Applied Aviation Sciences - Prescott

A significant number of tropical cyclones move into the midlatitudes and transform into extratropical cyclones. This process is generally referred to as extratropical transition (ET). During ET a cyclone frequently produces intense rainfall and strong winds and has increased forward motion, so that such systems pose a serious threat to land and maritime activities. Changes in the structure of a system as it evolves from a tropical to an extratropical cyclone during ET necessitate changes in forecast strategies. In this paper a brief climatology of ET is given and the challenges associated with forecasting extratropical transition are described in terms …


Chemical And Physical Properties Of Bulk Aerosols Within Four Sectors Observed During Trace-P, C. Jordan, B E. Anderson, R. Talbot, Jack E. Dibb, H Fuelberg, Charlie Hudgins, C M. Kiley, R. S. Russo, Eric Scheuer, Garry Seid, K L. Thornhill, E L. Winstead Nov 2003

Chemical And Physical Properties Of Bulk Aerosols Within Four Sectors Observed During Trace-P, C. Jordan, B E. Anderson, R. Talbot, Jack E. Dibb, H Fuelberg, Charlie Hudgins, C M. Kiley, R. S. Russo, Eric Scheuer, Garry Seid, K L. Thornhill, E L. Winstead

Earth Sciences

Chemical and physical aerosol data collected on the DC-8 during TRACE-P were grouped into four sectors based on back trajectories. The four sectors represent long-range transport from the west (WSW), regional circulation over the western Pacific and Southeast Asia (SE Asia), polluted transport from northern Asia with substantial sea salt at low altitudes (NNW) and a substantial amount of dust (Channel). WSW has generally low mixing ratios at both middle and high altitudes, with the bulk of the aerosol mass due to non-sea-salt water-soluble inorganic species. Low altitude SE Asia also has low mean mixing ratios in general, with the …


Uptake Of Nitrate And Sulfate On Dust Aerosols During Trace-P, C. Jordan, Jack E. Dibb, B E. Anderson, H Fuelberg Nov 2003

Uptake Of Nitrate And Sulfate On Dust Aerosols During Trace-P, C. Jordan, Jack E. Dibb, B E. Anderson, H Fuelberg

Earth Sciences

Aerosol data collected near Asia on the DC-8 aircraft platform during TRACE-P has been examined for evidence of uptake of NO3 and SO4= on dust surfaces. Data is compared between a sector where dust was predominant and a sector where dust was less of an influence. Coincident with dust were higher mixing ratios of anthropogenic pollutants. HNO3, SO2, and CO were higher in the dust sector than the nondust sector by factors of 2.7, 6.2, and 1.5, respectively. The colocation of dust and pollution sources allowed for the uptake of NO3 …


Aerosol Chemical Composition In Asian Continental Outflow During The Trace-P Campaign: Comparison With Pem-West B, Jack E. Dibb, R. Talbot, Eric Scheuer, Garry Seid, Melody A. Avery, H B. Singh Nov 2003

Aerosol Chemical Composition In Asian Continental Outflow During The Trace-P Campaign: Comparison With Pem-West B, Jack E. Dibb, R. Talbot, Eric Scheuer, Garry Seid, Melody A. Avery, H B. Singh

Earth Sciences

Aerosol associated soluble ions and the radionuclide tracers 7Be and 210Pb were quantified in 414 filter samples collected in spring 2001 from the DC-8 during the Transport and Chemical Evolution over the Pacific (TRACE-P) campaign. Binning the data into near Asia (flights from Hong Kong and Japan) and remote Pacific (all other flights) revealed large enhancements of NO3, SO4=, C2O4=, NH4+, K+, Mg2+, and Ca2+ near Asia. The boundary layer and lower troposphere were most strongly influenced by continental …


Intercontinental Transport Of Pollution Manifested In The Variability And Seasonal Trend Of Springtime O3 At Northern Middle And High Latitudes, Yuhang Wang, Changsub Shim, Nicola J. Blake, D R. Blake, Yunsoo Choi, Brian Ridley, Jack E. Dibb, Anthony Wimmers, Jennie Moody, F Flocke, Andrew Weinheimer, R. Talbot, Elliot Atlas Nov 2003

Intercontinental Transport Of Pollution Manifested In The Variability And Seasonal Trend Of Springtime O3 At Northern Middle And High Latitudes, Yuhang Wang, Changsub Shim, Nicola J. Blake, D R. Blake, Yunsoo Choi, Brian Ridley, Jack E. Dibb, Anthony Wimmers, Jennie Moody, F Flocke, Andrew Weinheimer, R. Talbot, Elliot Atlas

Earth Sciences

Observations (0–8 km) from the Tropospheric Ozone Production about the Spring Equinox (TOPSE) experiment are analyzed to examine air masses contributing to the observed variability of springtime O3 and its seasonal increase at 40°–85°N over North America. Factor analysis using the positive matrix factorization and principal component analysis methods is applied to the data set with 14 chemical tracers (O3, NOy, PAN, CO, CH4, C2H2, C3H8, CH3Cl, CH3Br, C2Cl4, CFC-11, HCFC-141B, Halon-1211, and 7Be) and one …


Chemical Composition Of Asian Continental Outflow Over The Western Pacific: Results From Transport And Chemical Evolution Over The Pacific (Trace-P), R. S. Russo, R. Talbot, Jack E. Dibb, Eric Scheuer, Garry Seid, C. Jordan, H Fuelberg, G W. Sachse, M A. Avery, S Vay, D R. Blake, N J. Blake, E L. Atlas, A Fried, S T. Sandholm, D Tan, H B. Singh, J Snow, B J. Heikes Oct 2003

Chemical Composition Of Asian Continental Outflow Over The Western Pacific: Results From Transport And Chemical Evolution Over The Pacific (Trace-P), R. S. Russo, R. Talbot, Jack E. Dibb, Eric Scheuer, Garry Seid, C. Jordan, H Fuelberg, G W. Sachse, M A. Avery, S Vay, D R. Blake, N J. Blake, E L. Atlas, A Fried, S T. Sandholm, D Tan, H B. Singh, J Snow, B J. Heikes

Earth Sciences

We characterize the chemical composition of Asian continental outflow observed during the NASA Transport and Chemical Evolution over the Pacific (TRACE-P) mission during February–April 2001 in the western Pacific using data collected on the NASA DC-8 aircraft. A significant anthropogenic impact was present in the free troposphere and as far east as 150°E longitude reflecting rapid uplift and transport of continental emissions. Five-day backward trajectories were utilized to identify five principal Asian source regions of outflow: central, coastal, north-northwest (NNW), southeast (SE), and west-southwest (WSW). The maximum mixing ratios for several species, such as CO, C2Cl4, …


Large-Scale Ozone And Aerosol Distributions, Air Mass Characteristics, And Ozone Fluxes Over The Western Pacific Ocean In Late Winter/Early Spring, Edward V. Browell, Marta Fenn, Carolyn Butler, William B. Grant, Vincent G. Brackett, Jonathan Hair, Melody A. Avery, Yuanlong Hu, Reginald E. Newell, H Fuelberg, Daniel J. Jacob, Bruce E. Anderson, Elliot Atlas, D R. Blake, William H. Brune, Jack E. Dibb, A Fried, B J. Heikes, G W. Sachse, S T. Sandholm, Hanwant B. Singh, R. Talbot, S Vay, Rodney J. Weber, Karen B. Bartlett Oct 2003

Large-Scale Ozone And Aerosol Distributions, Air Mass Characteristics, And Ozone Fluxes Over The Western Pacific Ocean In Late Winter/Early Spring, Edward V. Browell, Marta Fenn, Carolyn Butler, William B. Grant, Vincent G. Brackett, Jonathan Hair, Melody A. Avery, Yuanlong Hu, Reginald E. Newell, H Fuelberg, Daniel J. Jacob, Bruce E. Anderson, Elliot Atlas, D R. Blake, William H. Brune, Jack E. Dibb, A Fried, B J. Heikes, G W. Sachse, S T. Sandholm, Hanwant B. Singh, R. Talbot, S Vay, Rodney J. Weber, Karen B. Bartlett

Earth Sciences

Large-scale measurements of ozone (O3) and aerosol distributions were made from the NASA DC-8 aircraft during the Transport and Chemical Evolution over the Pacific (TRACE-P) field experiment conducted in February–April 2001. Remote measurements were made with an airborne lidar to provide O3 and multiple-wavelength aerosol backscatter profiles from near the surface to above the tropopause along the flight track. In situ measurements of O3, aerosols, and a wide range of trace gases were made onboard the DC-8. Five-day backward trajectories were used in conjunction with the O3 and aerosol distributions on each flight to …


Reactive Nitrogen In Asian Continental Outflow Over The Western Pacific: Results From The Nasa Transport And Chemical Evolution Over The Pacific (Trace-P) Airborne Mission, R. Talbot, Jack E. Dibb, Eric Scheuer, Garry Seid, R. S. Russo, S T. Sandholm, D Tan, H B. Singh, D R. Blake, N J. Blake, Elliot Atlas, G W. Sachse, C. Jordan, Melody A. Avery Oct 2003

Reactive Nitrogen In Asian Continental Outflow Over The Western Pacific: Results From The Nasa Transport And Chemical Evolution Over The Pacific (Trace-P) Airborne Mission, R. Talbot, Jack E. Dibb, Eric Scheuer, Garry Seid, R. S. Russo, S T. Sandholm, D Tan, H B. Singh, D R. Blake, N J. Blake, Elliot Atlas, G W. Sachse, C. Jordan, Melody A. Avery

Earth Sciences

We present here results for reactive nitrogen species measured aboard the NASA DC-8 aircraft during the Transport and Chemical Evolution over the Pacific (TRACE-P) mission. The large-scale distributions total reactive nitrogen (NOy,sum = NO + NO2 + HNO3 + PAN + C1–C5alkyl nitrates) and O3 and CO were better defined in the boundary layer with significant degradation of the relationships as altitude increased. Typically, NOy,sum was enhanced over background levels of ∼260 pptv by 20-to-30-fold. The ratio C2H2/CO had values of 1–4 at altitudes up to 10 …


Summary Of Measurement Intercomparisons During Trace-P, Fred Eisele, Lee Mauldin, C A. Cantrell, M Zondlo, E C. Apel, A Fried, J Walega, R E. Shetter, Barry Lefer, F Flocke, Andrew Weinheimer, M A. Avery, S Vay, G W. Sachse, J Podolske, G S. Diskin, J D. Barrick, H B. Singh, William H. Brune, H Harder, M Martinez, A R. Bandy, D C. Thornton, B J. Heikes, Y Kondo, D Riemer, S T. Sandholm, R. Talbot, Jack E. Dibb Oct 2003

Summary Of Measurement Intercomparisons During Trace-P, Fred Eisele, Lee Mauldin, C A. Cantrell, M Zondlo, E C. Apel, A Fried, J Walega, R E. Shetter, Barry Lefer, F Flocke, Andrew Weinheimer, M A. Avery, S Vay, G W. Sachse, J Podolske, G S. Diskin, J D. Barrick, H B. Singh, William H. Brune, H Harder, M Martinez, A R. Bandy, D C. Thornton, B J. Heikes, Y Kondo, D Riemer, S T. Sandholm, R. Talbot, Jack E. Dibb

Earth Sciences

The NASA DC-8 and P-3B aircraft flew within about a kilometer or less of each other on three occasions during the Transport and Chemical Evolution Over the Pacific (TRACE-P) campaign in order to intercompare similar measurements on the two aircraft. The first and last intercomparisons were in relatively remote marine environments during transits to and from Asia. The first began with a boundary layer measurement followed by an ascent to 3 km. The second set of intercomparisons was at a fixed altitude of about 5.2 km off the coast of Japan, also in relatively clean air. Finally, the third measurement …


Comparison Between Analytical Probabilistic And Computer Simulation Models, Using Current Design Examples, Barry A. Palynchuk Phd Sep 2003

Comparison Between Analytical Probabilistic And Computer Simulation Models, Using Current Design Examples, Barry A. Palynchuk Phd

Barry A. Palynchuk PhD

Closed form analytical expressions have been developed to solve several basic problems related to the hydrologic design of storm water management facilities. The collection of these analytical expressions is referred to as the Analytical Probabilistic Storm Water Models (APSWM). APSWM can be used as an alternative to the design storm simulation models in the design and analysis of storm water management facilities. In this paper, a comparison is made between APSWM and design storm simulation models as applied to an actual design case. Conventional outputs such as runoff volume, peak discharge, and peak discharge from detention ponds are reviewed and …


Chemical Characterization Of Ambient Aerosol Collected During The Northeast Monsoon Season Over The Arabian Sea: Labile-Fe(Ii) And Other Trace Metals, Anne M. Johansen, Michael R. Hoffmann Jul 2003

Chemical Characterization Of Ambient Aerosol Collected During The Northeast Monsoon Season Over The Arabian Sea: Labile-Fe(Ii) And Other Trace Metals, Anne M. Johansen, Michael R. Hoffmann

All Faculty Scholarship for the College of the Sciences

Ambient aerosol samples were collected over the Arabian Sea during the month of March of 1997, aboard the German R/V Sonne, as part of the German Joint Global Ocean Flux Study (JGOFS) project. This is the third study in a series of analogous measurements taken over the Arabian Sea during different seasons of the monsoon. Dichotomous high‐volume collector samples were analyzed for ferrous iron immediately after collection, while trace metals, anions, and cations were determined upon return to the laboratory. The main crustal component was geochemically well represented by the average crustal composition and amounted to 5.94 ± 3.08 …


Antarctic Oversnow Traverse-Based Southern Hemisphere Climate Reconstruction, Paul Andrew Mayewski Jun 2003

Antarctic Oversnow Traverse-Based Southern Hemisphere Climate Reconstruction, Paul Andrew Mayewski

Earth Science Faculty Scholarship

On 2 January 2003, the U.S. component of the International Trans Antarctic Scientific Expedition (U.S. ITASE) (Figure 1) arrived at the South Pole after completing more than 5000 km of oversnow traverses that included much of west Antarctica and a portion of east Antarctica (Figure 2). During the traverses, which were performed from 1999 through 2003, U.S. ITASE focused on collecting data that will allow the reconstruction of sub-annual scale climate variability and changes in the chemistry of the atmosphere over the last 200+ years.

ITASE is a multi-disciplinary research program supported by 19 nations and endorsed by the Scientific …


Be-10/Be-7 Tracer Of Atmospheric Transport And Stratosphere-Troposphere Exchange, C. Jordan, Jack E. Dibb, R C. Finkel Apr 2003

Be-10/Be-7 Tracer Of Atmospheric Transport And Stratosphere-Troposphere Exchange, C. Jordan, Jack E. Dibb, R C. Finkel

Earth Sciences

The 10Be/7Be ratio is a sensitive tracer of atmospheric transport and stratosphere-troposphere exchange (STE). Data from five NASA aircraft field missions (PEM: West A and B, Tropics A; SONEX; and SUCCESS) have been assembled to produce the largest data set of 10Be,7Be, and their ratio collected to date (>300 samples). Ratios near 0.60 are indicative of tropospheric air with little stratospheric influence, while higher ratios are found in stratospheric air. Samples from the lower stratosphere were all collected within 2.5 km of the tropopause and had ratios >1.27. Of these lower stratosphere samples …


Measurement Of Proton Transfer Reaction Rates In A Microwave Cavity Discharge Flowing Afterglow, George M. Brooke Iv Apr 2003

Measurement Of Proton Transfer Reaction Rates In A Microwave Cavity Discharge Flowing Afterglow, George M. Brooke Iv

Physics Theses & Dissertations

The reaction rate coefficients between the hydronium ion and the molecules ethene (C2H4), propene (C3H6), 1-butene (C4H8) and hydrogen sulfide (H2S) were measured at 296 K. The measured reaction rates were compared to collision rates calculated using average dipole orientation (ADO) theory. Reaction efficiency depends primarily upon the proton affinity of the molecules. All the measurements were obtained using the newly developed microwave cavity discharge flowing afterglow (MCD-FA) apparatus. This device uses an Asmussen-type microwave cavity discharge ion source that is …


Data Mining Atmospheric/Oceanic Parameters In The Design Of A Long-Range Nephelometric Forecast Tool, Richard F. Benz Mar 2003

Data Mining Atmospheric/Oceanic Parameters In The Design Of A Long-Range Nephelometric Forecast Tool, Richard F. Benz

Theses and Dissertations

The Department of Defense calls for long-range forecasts to aid in the planning of operations. The goal of this research was to explore the feasibility of predicting, one month in advance, the total monthly cloud cover over the country of Afghanistan. In an attempt to reach this goal, the following objectives were achieved: (1) climatological synoptic study of Afghanistan; (2) survey of Real Time Nephanalysis, outgoing longwave radiation (OLR), and surface observational data; (3) examination of teleconnection indices and sea surface temperatures; (4) standard statistical analysis for prediction; and (5) classification tree analysis (CART), In addition, due to current world …


Stratospheric Influence On The Northern North American Free Troposphere During Topse: 7be As A Stratospheric Tracer, Jack E. Dibb, R. Talbot, Eric Scheuer, Garry Seid, Linsey J. Debell, Barry Lefer, Brian Ridley Feb 2003

Stratospheric Influence On The Northern North American Free Troposphere During Topse: 7be As A Stratospheric Tracer, Jack E. Dibb, R. Talbot, Eric Scheuer, Garry Seid, Linsey J. Debell, Barry Lefer, Brian Ridley

Earth Sciences

We use 7Be, with HNO3 and O3, to identify air masses sampled from the NCAR C-130 during TOPSE that retained clear evidence of stratospheric influence. A total of 43 such air masses, spread fairly evenly across the February to May sampling period, and 40°N–86°N latitude range, were encountered. South of 55°N, nearly all clear stratospheric influence was restricted to altitudes above 6 km. At higher latitudes stratospherically influenced air masses were encountered as low as 2 km. Approximately 12% of all TOPSE sampling time at altitudes above 2 km was spent in stratospherically impacted air, above …


Effect Of Sulfate Aerosol On Tropospheric Nox And Ozone Budgets: Model Simulations And Topse Evidence, Xuexi Tie, L K. Emmons, Larry Horowitz, Guy Brasseur, Brian Ridley, Elliot Atlas, Craig Stround, Peter Hess, Andrzej Klonecki, Sasha Madronich, R. Talbot, Jack E. Dibb Feb 2003

Effect Of Sulfate Aerosol On Tropospheric Nox And Ozone Budgets: Model Simulations And Topse Evidence, Xuexi Tie, L K. Emmons, Larry Horowitz, Guy Brasseur, Brian Ridley, Elliot Atlas, Craig Stround, Peter Hess, Andrzej Klonecki, Sasha Madronich, R. Talbot, Jack E. Dibb

Earth Sciences

The distributions of NOx and O3 are analyzed during TOPSE (Tropospheric Ozone Production about the Spring Equinox). In this study these data are compared with the calculations of a global chemical/transport model (Model for OZone And Related chemical Tracers (MOZART)). Specifically, the effect that hydrolysis of N2O5 on sulfate aerosols has on tropospheric NOx and O3 budgets is studied. The results show that without this heterogeneous reaction, the model significantly overestimates NOx concentrations at high latitudes of the Northern Hemisphere (NH) in winter and spring in comparison to the observations during TOPSE; …


Tunable Diode Laser Measurements Of Formaldehyde During The Topse 2000 Study: Distributions, Trends, And Model Comparisons, A Fried, Yuhang Wang, C A. Cantrell, B Wert, J Walega, Brian Ridley, Elliot Atlas, R E. Shetter, Barry Lefer, Michael T. Coffey, James W. Hannigan, D R. Blake, N J. Blake, Simone Meinardi, R. Talbot, Jack E. Dibb, Eric Scheuer, Oliver Wingenter, J Snow, B J. Heikes, Dieter Ehhalt Feb 2003

Tunable Diode Laser Measurements Of Formaldehyde During The Topse 2000 Study: Distributions, Trends, And Model Comparisons, A Fried, Yuhang Wang, C A. Cantrell, B Wert, J Walega, Brian Ridley, Elliot Atlas, R E. Shetter, Barry Lefer, Michael T. Coffey, James W. Hannigan, D R. Blake, N J. Blake, Simone Meinardi, R. Talbot, Jack E. Dibb, Eric Scheuer, Oliver Wingenter, J Snow, B J. Heikes, Dieter Ehhalt

Earth Sciences

Airborne measurements of formaldehyde (CH2O) were acquired employing tunable diode laser absorption spectroscopy (TDLAS) during the 2000 Tropospheric Ozone Production About the Spring Equinox (TOPSE) study. This study consisted of seven deployments spanning the time period from 4 February to 23 May 2000 and covered a wide latitudinal band from 40°N to 85°N. The median measured CH2O concentrations, with a few exceptions, did not show any clear temporal trends from February to May in each of five altitude and three latitude bins examined. Detailed measurement–model comparisons were carried out using a variety of approaches employing two …


An Estimate Of The Stratospheric Contribution To Springtime Tropospheric Ozone Maxima Using Topse Measurements And Beryllium-7 Simulations, Dale J. Allen, Jack E. Dibb, Brian Ridley, Kenneth E. Pickering, R. Talbot Feb 2003

An Estimate Of The Stratospheric Contribution To Springtime Tropospheric Ozone Maxima Using Topse Measurements And Beryllium-7 Simulations, Dale J. Allen, Jack E. Dibb, Brian Ridley, Kenneth E. Pickering, R. Talbot

Earth Sciences

Measurements of tropospheric ozone (O3) between 30°N and 70°N show springtime maxima at remote locations. The contribution of seasonal changes in stratosphere–troposphere exchange (STE) to these maxima was investigated using measurements from the Tropospheric Ozone Production about the Spring Equinox Experiment (TOPSE) campaign and the beryllium-7 (7Be) distribution from a calculation driven by fields from the Goddard Earth Observing System Data Assimilation System (GEOS DAS). Comparison with TOPSE measurements revealed that upper tropospheric model-calculated 7Be mixing ratios were reasonable (a change from previous calculations) but that lower tropospheric mixing ratios were too low most likely …


Coupled Evolution Of Brox-Clox-Hox-Nox Chemistry During Bromine-Catalyzed Ozone Depletion Events In The Arctic Boundary Layer, M J. Evans, D J. Jacob, E L. Atlas, C A. Cantrell, Fred Eisele, F Flocke, A Fried, R L. Mauldin, Brian Ridley, B Wert, R. Talbot, D R. Blake, B J. Heikes, J Snow, J Walega, Andrew Weinheimer, Jack E. Dibb Feb 2003

Coupled Evolution Of Brox-Clox-Hox-Nox Chemistry During Bromine-Catalyzed Ozone Depletion Events In The Arctic Boundary Layer, M J. Evans, D J. Jacob, E L. Atlas, C A. Cantrell, Fred Eisele, F Flocke, A Fried, R L. Mauldin, Brian Ridley, B Wert, R. Talbot, D R. Blake, B J. Heikes, J Snow, J Walega, Andrew Weinheimer, Jack E. Dibb

Earth Sciences

Extensive chemical characterization of ozone (O3) depletion events in the Arctic boundary layer during the TOPSE aircraft mission in March–May 2000 enables analysis of the coupled chemical evolution of bromine (BrOx), chlorine (ClOx), hydrogen oxide (HOx) and nitrogen oxide (NOx) radicals during these events. We project the TOPSE observations onto an O3 chemical coordinate to construct a chronology of radical chemistry during O3 depletion events, and we compare this chronology to results from a photochemical model simulation. Comparison of observed trends in ethyne (oxidized by Br) and ethane …


Investigations Into Free Tropospheric New Particle Formation In The Central Canadian Arctic During The Winter/Spring Transition As Part Of Topse, R J. Weber, D A. Orsini, B Wang, Eric Scheuer, R. Talbot, Jack E. Dibb, Garry Seid, Linsey J. Debell, R L. Mauldin, E Kosciuch, C A. Cantrell, Fred Eisele Feb 2003

Investigations Into Free Tropospheric New Particle Formation In The Central Canadian Arctic During The Winter/Spring Transition As Part Of Topse, R J. Weber, D A. Orsini, B Wang, Eric Scheuer, R. Talbot, Jack E. Dibb, Garry Seid, Linsey J. Debell, R L. Mauldin, E Kosciuch, C A. Cantrell, Fred Eisele

Earth Sciences

In this paper, we investigate the role of in situ new particle production in the central Canadian sub-Arctic and Arctic as part of the TOPSE experiment. Airborne measurements conducted primarily in the free troposphere were made from 50° to 90°W longitude and 60° to 85°N latitude during the period from February to May 2000. Data pertinent to this paper include 3–4 nm diameter (Dp) particles, ultrafine condensation nuclei (Dp > 3 nm), fine particles (0.2 < Dp < 3 μm), and the possible nucleation precursor, sulfuric acid, and its precursor, sulfur dioxide. For data averaged over this period, most species showed little evidence for a latitudinal trend. Fine aerosol number concentrations, however, showed a slight increase with latitude. The evolution of various species concentrations over the period of the study show that fine particles also had a consistent temporal trend, increasing at all altitudes from February to May, whereas sulfur dioxide at the surface tended to peak in late March. Ultrafine condensation nuclei and 3–4 nm particles showed no temporal trends. Little evidence for in situ new particle production was observed during the study, except for one atypical event where SO2concentrations were 3.5 ppbv, 2 orders of magnitude higher than typical levels. This paper cannot address the question of whether the observed condensation nuclei were …


Ozone Depletion Events Observed In The High Latitude Surface Layer During The Topse Aircraft Program, Brian Ridley, Elliot Atlas, D Montzka, Edward V. Browell, C A. Cantrell, D R. Blake, N J. Blake, L Cinquini, Michael T. Coffey, L K. Emmons, Ronald C. Cohen, Russell J. Deyoung, Jack E. Dibb, Fred Eisele, F Flocke, A Fried, F E. Grahek, William B. Grant, Jonathan Hair, James W. Hannigan, B J. Heikes, Barry Lefer, R L. Mauldin, Jennie Moody, R E. Shetter, J Snow, R. Talbot, J A. Thornton, J Walega, Andrew Weinheimer, B Wert, Anthony Wimmers Feb 2003

Ozone Depletion Events Observed In The High Latitude Surface Layer During The Topse Aircraft Program, Brian Ridley, Elliot Atlas, D Montzka, Edward V. Browell, C A. Cantrell, D R. Blake, N J. Blake, L Cinquini, Michael T. Coffey, L K. Emmons, Ronald C. Cohen, Russell J. Deyoung, Jack E. Dibb, Fred Eisele, F Flocke, A Fried, F E. Grahek, William B. Grant, Jonathan Hair, James W. Hannigan, B J. Heikes, Barry Lefer, R L. Mauldin, Jennie Moody, R E. Shetter, J Snow, R. Talbot, J A. Thornton, J Walega, Andrew Weinheimer, B Wert, Anthony Wimmers

Earth Sciences

During the Tropospheric Ozone Production about the Spring Equinox (TOPSE) aircraft program, ozone depletion events (ODEs) in the high latitude surface layer were investigated using lidar and in situ instruments. Flight legs of 100 km or longer distance were flown 32 times at 30 m altitude over a variety of regions north of 58° between early February and late May 2000. ODEs were found on each flight over the Arctic Ocean but their occurrence was rare at more southern latitudes. However, large area events with depletion to over 2 km altitude in one case were found as far south as …


Seasonal Distributions Of Fine Aerosol Sulfate In The North American Arctic Basin During Topse, Eric Scheuer, R. Talbot, Jack E. Dibb, Garry Seid, Linsey J. Debell, Barry Lefer Feb 2003

Seasonal Distributions Of Fine Aerosol Sulfate In The North American Arctic Basin During Topse, Eric Scheuer, R. Talbot, Jack E. Dibb, Garry Seid, Linsey J. Debell, Barry Lefer

Earth Sciences

We used the mist chamber/ion chromatography technique to quantify fine aerosol SO4=(<2.7 μm) in the Arctic during the Tropospheric Ozone Production about the Spring Equinox Experiment (TOPSE) with about 2.5 min time resolution. Our effective sample area ranged from 50° to 86°N and 53° to 100°W. The seasonal evolution of fine aerosol sulfate in the Arctic troposphere during TOPSE was consistent with the phenomenon of Arctic haze. Arctic haze has been attributed to pollution from sources in the Arctic and pollution transported meridionally along stable isentropes into the Arctic in geographically broad but vertically narrow bands. These layers became more prevalent at higher altitudes as the season progressed toward summer, and the relevant isentropes are not held so close to the surface. Mean fine particle SO4= mixing ratios during TOPSE in February below 1000 m were elevated (112 pptv) and highly variable (between 28 and 290 pptv) but were significantly lower at higher altitudes (about 40 pptv). As the season progressed, elevated mixing ratios and higher variability were observed at higher altitudes, up to 7 km. In May, mixing ratios at the lowest altitudes declined but still remained higher than in February at all altitudes. The high variability in our measurements likely reflects the vertical heterogeneity of the wintertime …


Steady State Free Radical Budgets And Ozone Photochemistry During Topse, C A. Cantrell, Lee Mauldin, M Zondlo, Fred Eisele, E Kosciuch, R E. Shetter, Barry Lefer, S R. Hall, T L. Campos, Brian Ridley, J Walega, A Fried, B Wert, F Flocke, Andrew Weinheimer, James W. Hannigan, Michael T. Coffey, Elliot Atlas, S Stephens, B J. Heikes, J Snow, D R. Blake, N J. Blake, A Katzenstein, J Lopez, Edward V. Browell, Jack E. Dibb, Eric Scheuer, Garry Seid, R. Talbot Feb 2003

Steady State Free Radical Budgets And Ozone Photochemistry During Topse, C A. Cantrell, Lee Mauldin, M Zondlo, Fred Eisele, E Kosciuch, R E. Shetter, Barry Lefer, S R. Hall, T L. Campos, Brian Ridley, J Walega, A Fried, B Wert, F Flocke, Andrew Weinheimer, James W. Hannigan, Michael T. Coffey, Elliot Atlas, S Stephens, B J. Heikes, J Snow, D R. Blake, N J. Blake, A Katzenstein, J Lopez, Edward V. Browell, Jack E. Dibb, Eric Scheuer, Garry Seid, R. Talbot

Earth Sciences

A steady state model, constrained by a number of measured quantities, was used to derive peroxy radical levels for the conditions of the Tropospheric Ozone Production about the Spring Equinox (TOPSE) campaign. The analysis is made using data collected aboard the NCAR/NSF C-130 aircraft from February through May 2000 at latitudes from 40° to 85°N, and at altitudes from the surface to 7.6 km. HO2 + RO2 radical concentrations were measured during the experiment, which are compared with model results over the domain of the study showing good agreement on the average. Average measurement/model ratios are 1.04 (σ …


Springtime Photochemistry At Northern Mid And High Latitudes, Yuhang Wang, Brian Ridley, A Fried, C A. Cantrell, D D. Davis, Gao Chen, J Snow, B J. Heikes, R. Talbot, Jack E. Dibb, F Flocke, Andrew Weinheimer, N J. Blake, D R. Blake, R E. Shetter, Barry Lefer, Elliot Atlas, Michael T. Coffey, J Walega, B Wert Feb 2003

Springtime Photochemistry At Northern Mid And High Latitudes, Yuhang Wang, Brian Ridley, A Fried, C A. Cantrell, D D. Davis, Gao Chen, J Snow, B J. Heikes, R. Talbot, Jack E. Dibb, F Flocke, Andrew Weinheimer, N J. Blake, D R. Blake, R E. Shetter, Barry Lefer, Elliot Atlas, Michael T. Coffey, J Walega, B Wert

Earth Sciences

Physical and chemical properties of the atmosphere at 0–8 km were measured during the Tropospheric Ozone Production about the Spring Equinox (TOPSE) experiments from February to May 2000 at mid (40°–60°N) and high latitudes (60°–80°N). The observations were analyzed using a diel steady state box model to examine HOx and O3 photochemistry during the spring transition period. The radical chemistry is driven primarily by photolysis of O3 and the subsequent reaction of O(1D) and H2O, the rate of which increases rapidly during spring. Unlike in other tropospheric experiments, observed H2O2 …


Near-Surface Currents In Desoto Canyon (1997–99): Comparison Of Current Meters, Satellite Observation, And Model Simulation, Dong-Ping Wang, Lie-Yauw Oey, Tal Ezer, Peter Hamilton Jan 2003

Near-Surface Currents In Desoto Canyon (1997–99): Comparison Of Current Meters, Satellite Observation, And Model Simulation, Dong-Ping Wang, Lie-Yauw Oey, Tal Ezer, Peter Hamilton

CCPO Publications

This study evaluates a data-assimilated model simulation of near-surface circulation in DeSoto Canyon (DSC), Gulf of Mexico, with emphasis on analyzing moored current-meter observations and comparing them with satellite data and model results. The study period is for two years from April 1997 to April 1999. The model results are from a high-resolution Gulf of Mexico model forced by analyzed wind and surface heat flux. Two types of data are used to deduce near-surface circulation: moored current meters at 13 locations in the DSC, and satellite sea level anomaly. The moored currents are mapped through multivariate objective analysis to produce …


Ozone, Aerosol, Potential Vorticity, And Trace Gas Trends Observed At High-Latitudes Over North America From February To May 2000, Edward V. Browell, Jonathan Hair, Carolyn Butler, William B. Grant, Russell J. Deyoung, Marta Fenn, Vincent G. Brackett, Marian B. Clayton, Lorraine A. Brasseur, David B. Harper, Brian Ridley, Andrzej Klonecki, Peter Hess, L K. Emmons, Xuexi Tie, Elliot Atlas, C A. Cantrell, Anthony Wimmers, D R. Blake, Michael T. Coffey, James W. Hannigan, Jack E. Dibb, R. Talbot, F Flocke, Andrew Weinheimer, A Fried, B Wert, J Snow, Barry Lefer Jan 2003

Ozone, Aerosol, Potential Vorticity, And Trace Gas Trends Observed At High-Latitudes Over North America From February To May 2000, Edward V. Browell, Jonathan Hair, Carolyn Butler, William B. Grant, Russell J. Deyoung, Marta Fenn, Vincent G. Brackett, Marian B. Clayton, Lorraine A. Brasseur, David B. Harper, Brian Ridley, Andrzej Klonecki, Peter Hess, L K. Emmons, Xuexi Tie, Elliot Atlas, C A. Cantrell, Anthony Wimmers, D R. Blake, Michael T. Coffey, James W. Hannigan, Jack E. Dibb, R. Talbot, F Flocke, Andrew Weinheimer, A Fried, B Wert, J Snow, Barry Lefer

Earth Sciences

Ozone (O3) and aerosol scattering ratio profiles were obtained from airborne lidar measurements on thirty-eight flights over seven deployments covering the latitudes of 40°–85°N between 4 February and 23 May 2000 as part of the Tropospheric Ozone Production about the Spring Equinox (TOPSE) field experiment. Each deployment started from Broomfield, Colorado, with bases in Churchill, Canada, and on most deployments, Thule Air Base, Greenland. Nadir and zenith lidar O3 measurements were combined with in situ O3measurements to produce vertically continuous O3 profiles from near the surface to above the tropopause. Potential vorticity (PV) distributions …


New Evidence For Enhanced Ocean Primary Production Triggered By Tropical Cyclone, I. Lin, W. Timothy Liu, Chun-Chieh Wu, George T. F. Wong, Chuanmin Hu, Zhiqiang Chen, Wen-Der Liang, Yih Yang, Kon-Kee Liu Jan 2003

New Evidence For Enhanced Ocean Primary Production Triggered By Tropical Cyclone, I. Lin, W. Timothy Liu, Chun-Chieh Wu, George T. F. Wong, Chuanmin Hu, Zhiqiang Chen, Wen-Der Liang, Yih Yang, Kon-Kee Liu

OES Faculty Publications

[1] New evidence based on recent satellite data is presented to provide a rare opportunity in quantifying the long-speculated contribution of tropical cyclones to enhance ocean primary production. In July 2000, moderate cyclone Kai-Tak passed over the South China Sea (SCS). During its short 3-day stay, Kai-Tak triggered an average 30-fold increase in surface chlorophyll-a concentration. The estimated carbon fixation resulting from this event alone is 0.8 Mt, or 2-4% of SCS's annual new production. Given an average of 14 cyclones passing over the SCS annually, we suggest the long-neglected contribution of tropical cyclones to SCS's annual new production may …


Near-Real-Time Measurement Of Sea-Salt Aerosol During The Seas Campaign: Comparison Of Emission-Based Sodium Detection With An Aerosol Volatility Technique, P. Campuzano-Jost, Catherine D. Clark, H. Maring, D. S. Covert, S. Howell, V. Kapustin, K. A. Clarke, E. S. Saltzman, A. J. Hynes Jan 2003

Near-Real-Time Measurement Of Sea-Salt Aerosol During The Seas Campaign: Comparison Of Emission-Based Sodium Detection With An Aerosol Volatility Technique, P. Campuzano-Jost, Catherine D. Clark, H. Maring, D. S. Covert, S. Howell, V. Kapustin, K. A. Clarke, E. S. Saltzman, A. J. Hynes

Biology, Chemistry, and Environmental Sciences Faculty Articles and Research

The first deployment of an emission-based aerosol sodium detector (ASD), designed to chemically characterize marine aerosols on a near-real-time basis, is reported. Deployment occurred as part of the Shoreline Environment Aerosol Study ( SEAS) from 16 April to 1 May 2000 at Bellows Air Force Base on the east side of Oahu, where the University of Hawaii's Department of Oceanography maintains a tower for aerosol measurements. The instrument was operated in size-unsegregated mode and measurements were made that included two extended continuous sampling periods, each of which lasted for 24 h. During this time, the ASD was compared with measurements …