Physical Sciences and Mathematics Commons^™

Nickel Subsulfide Can Protect Human Fibroblasts From The Mutagenic Effect Of Benzo[A]Pyrene Diolepoxide, Samir M. Hamdan

Masters Theses

Cancer researchers are interested in identifying the environmental causes and synergistic influences of different carcinogens. It is important to examine the combined effect of multiple carcinogens since this is a more realistic representation of the true environmental situation in which we are exposed daily. Our study has reported that pretreating human fibroblasts with nickel subsulfide followed by the simultaneous treatment with both nickel subsulfide and benzo[a]pyrene diolepoxide (BPDE) can protect human fibroblasts from the mutagenic effects of BPDE. These results correlate well with our previous chromium-BPDE co-treatment work, suggesting a transition metal dependent protective effect. This protective effect was dependent …

Synthesis, Characterization And Photophysical Behavior Of A Cr(Iii) Bimetallic System, Yan Chen

Masters Theses

Many binuclear transition metal complexes have been studied to understand the nature of interactions between the metal centers. People have found Simultaneous Pair Excitation phenomenon in some bimetallic system that can serve as a potential source of Non-Linear Optical behavior.

Thus a series of Cr₂ -([14]aneN₄)₂-X₄ⁿ⁺ complexes were synthesized and characterized. Only the cis,cis configuration was found. The results were compared with those of their monomer analogs. The electronic structures are very similar in both monomer and dimer complexes. The quantum yield, UV-Vis absorption and lifetime studies suggested a possible coupling between the …

Separation And Determination Of Monochlorophenols By Capillary Zones Electrophoresis, Zarina Yasmin Banu

Masters Theses

Chlorine has been widely used in industry. One of the most common uses of chlorine is in municipal water treatment plants. Chlorine reacts with a variety of organic compounds, among these are phenol and its derivatives which are commonly found in natural waters. When these compounds react with chlorine, a variety of chlorine substituted and oxidized products result depending on concentrations, pH, and temperature. In order to study these reactions it is necessary to separate and determine the various products produced.

Earlier studies have shown 3-chloro and 4-chlorophenol cannot be separated by commercial GLC columns. GC/MS (electron impact) measurements cannot …

A Portable, Object-Oriented Library For Neural Network Simulation, Martin P. Franz

Masters Theses

A portable, object-oriented library for simulation of general Multi-layer Feedforward Neural Networks (MLFNs) is described. Unlike all-encompassing neural network simulation environments, the library was designed to allow convenient use in existing programs and in applications where training and testing data are generated using separate, often complex simulations.

The library' s design goals include modularity, portability, efficiency, correctness, compactness, and type-safety. To demonstrate how these objectives are met, competing architectural choices are presented, along with the criteria used for determining the strategy actually implemented. Sample applications using the library are presented, showing how the library' s class files are used in …

Application Of The Paleomagnetic Fold Test To Determine The Relative Timing Of Sill Intrusion And Deformation In The Southwest Helena Salient, Montana, Stephen Christopher Whisner

Masters Theses

The Doherty Mountain fold complex is a highly folded and faulted region along the southern boundary of the Helena Salient in southwestern Montana. This region has a complex deformation history that is a key to deformation within the Helena Salient as a whole. A structural interpretation of the deformed rocks of this area was conducted using field mapping and cross section construction at 1:24,000 scale providing insight to the internal deformation processes involved. Fourteen folds and three major faults were mapped and analyzed showing the influence of the Southwest Montana Transverse Zone and late stage detachment faulting on fold orientation. …

Geosciences Newsletter- 1998, Department Of Geosciences

Geological and Environmental Sciences News

Vol. 1, No. 23

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Angle-Resolved Studies Of Inner Shell Excitations For Argon, Krypton And Xenon Using Third Generation Synchrotron Sources, Ahmad H. Farhat

Dissertations

This dissertation, which is in the area of atomic physics, concentrates on the study of the interaction between VUV-soft X-ray radiation and atoms in the gas phase. The main area of interest is the study of Auger decay in atoms utilizing the process known as the resonance Auger effect, where an inner shell electron is excited to an unfilled orbital followed by the ejection of an Auger electron. The measurements in this thesis were performed by using the high resolution Atomic, Molecular and Optical Physics undulator beam line, which utilizes a spherical grating monochromator at the Advanced Light Source at …

Improvement Of Epa Method 8330: Complete Separation Of Explosives Using A Two Phase Approach, Michael J. Lang

Masters Theses

A wide range of primary and secondary contaminants is found in environmental matrices containing explosive residues. HPLC methodology for the detection of explosive is now standardized in EPA Method 8330, and represents the most common method currently used for explosive analysis. However, co-elution of some of the analytes occurs even using method 8330. As a result, explosive analysis using HPLC have required the use of a confirmation column in an additional analysis step.

In the current work, all of the compounds in the EPA 8330 explosives list were resolved using a single HPLC separation. While the EPA 8330 HPLC conditions …

A Generalization Of Cayley Graphs For Finite Fields, Dawn M. Jones

Dissertations

A central question in the area of topological graph theory is to find the genus of a given graph. In particular, the genus parameter has been studied for Cayley graphs. A Cayley graph is a representation of a group and a fixed generating set for that group. A group is said to be planar if there is a generating set which produces a planar Cayley graph. We say that a group is toroidal if there is a generating set that produces a toroidal Cayley graph and if there are no generating sets which produce a planar Cayley graph. Characterizations for …

Perturbed Hamiltonian System Of Two Parameters With Several Turning Points, Myeong Joon Ann

Dissertations

No abstract provided.

Units In Integral Group Rings For Direct Products, Richard M. Low

Dissertations

Given a finite group G and the ring of integers, one can form the integral group ring ZG . A natural problem to investigate is to find a description of the group of units for this ring ZG. Since the unit problem for integral group rings arises in the contexts of algebraic topology, number theory, and algebra, it is an important question to try to answer. For this reason, it has drawn the attention of researchers from diverse areas of mathematics.

Graham Higman (circa 1940) made substantial contributions to the solution of this problem, in the case where G was …

A Study Of The Knowledge Structure Of Expert, Intermediate, And Novice Subjects In The Domain Of Physics, Jennifer L. Discenna

Dissertations

The objective of this research was to investigate the knowledge structure in physics by describing the knowledge of experts, intermediates, and novices. A review of the literature on expertise, physics knowledge, and conceptual structure provided two competing representations of physics knowledge: one defined as a hierarchy of models arranged from general to specific models, the second defined by theories which link knowledge together.

In order to investigate the two representations described above, a reiterative categorization task was employed. This task resulted in a hierarchical sort with larger piles at the top of the hierarchy and smaller piles at the bottom …

Surface Models Of Finite Geometries, Ramon Manuel Figueroa-Centeno

Dissertations

The standard non-Euclidean geometries, hyperbolic geometry and elliptical geometry, both arise by negating the parallel postulate of Euclid. Both these geometries share with Euclidean geometries an infinitude of points and lines. But also possible are many finite geometries. Among these are the class of projective geometries PG(m,q) of projective dimension m (m > 2) and the k-configurations. These mathematical objects, although primarily geometric in nature, provide related structures of combinatorial interest: block designs. These have applications in scheduling problems and the design of experiments for statistical analysis. Recently, A. T. White has added a topological flavor to the study …

Electron Emission Following The Interaction Of Slow Highly Charged Ions With Solids, Joseph W. Mcdonald

Dissertations

The interaction of highly-charged ions with surfaces involves many excitation processes of the surface atoms and the bulk material. One such process, the emission of electrons from surfaces due to the potential energy of the incident ions has been studied. The experimental results presented here confirm that the majority of electrons emitted as a result of highly-charged ions interacting with a solid surface have energies of about 20 eV. Auger processes contribute a smaller fraction of the total emitted electrons with increasing Z o f the projectile. This contribution to the total electron emission yield is found to be less …

A Method For The Determination Of Purity Of Pnu-10483 Bulk Drug By Capillary Zone Electrophoresis, Gavin Gibson

Honors Theses

In this investigation, a method was developed for the determination of purity of the drug PNU-10483 using the technique of capillary zone electrophoresis (CZE). CZE was seen as a potential alternative to the formerly used procedure of ion-pair reversed phase highperformance liquid chromatography (HPLC). Nearly five years earlier, a similar study was performed, in which an attempt was made to develop a method that used CZE to determine the purity of bulk drug and the potency of drug tablets. While this development was mostly successful, sporadically unpredictable results reduced the method's overall viability. These outliers were thought to be caused …

A Paleoclimatic Study Of The Midwestern United States From The Stahle Isotope Records In Lake Sediments, Norman Alan Lovan

Dissertations

No abstract provided.

Groundwater Hydraulics And Slope Stability Analysis: Elements For Prediction Of Shoreline Recession, William W. Montgomery

Dissertations

Studies documenting the roles that geologic materials and groundwater play in Great Lakes bluff recession are rare. This study reports findings concerning relationships between bluff lithology, bluff hydrology, and bluff recession along a 10-mile stretch of eastern Lake Michigan shoreline in heterogeneous Pleistocene deposes. According to a newly-developed, field-tested, GIS-based methodology, bluffs in the study area can be characterized lithologically as sand, clay, or mixed sand/clay, and can be characterized hydrologically as exhibiting either high head or low head.

Geotechnical analysis indicates that Atterberg limits, index properties, consolidation state, and drainage conditions affect the shear strength of bluff materials. Silty …

A Generic Multi-Electrode Automated/Semi-Automated Field Resistivity System, Douglas D. Werkema

Masters Theses

Geophysical field exploration using electrical resistivity typically employs the use of four electrodes which are progressively relocated to positions that differ from a few meters to hundreds of meters. Consequently, field operations are tiresome and often lead to imprecise locations of electrodes and poor data quality. This project develops an automated field resistivity system.

This automation of resistivity measurements is accomplished by using multiple sets of field electrodes, a programmable switch box, remotely controlling the acquisition instrument and digitally storing the results. Controlling the process is the Acquisition Control^©software, for Windows 95^© .The prototype switch box has …

Implementation Of The Graphical User Interface Of The Parint Package In Java, Gwowen Fu

Masters Theses

The graphical user interface (GUI) of the ParInt interface package provides a convenient and efficient way for users to integrate multivariate functions on a parallel system or a network.

This thesis introduces basic structure of the GUI and gives a detailed description of each class of how the classes communicate with each other and how the connection with the parallel program is made.

Vertical Resistivity Electrode Arrays For Detecting Hydrocarbon Movement And Content In Sands, Kirt Elliott

Masters Theses

In many contamination sites where hydrocarbon is involved an accurate thickness of the contaminant can not be achieved through the most commonly used methods. The purpose of this study is to find an alternate method of determining a precise thickness and monitor the contaminant movement in conjunction with the current methods. Vertical resistivity electrode arrays were tested in a lab environment on singular probes and between probes. The arrays tested were the Wenner, dipole dipole, gradient, parallel and down-hole 3-arrays. Electrode pipes were constructed and placed into a sand tank where the hydrocarbon thickness and the water level could be …

Factors Governing The Rate Of Appearance Of Fuels In Monitoring Wells, Bradley A. Green

Masters Theses

Delays in the appearance of free product (e.g. fuels) in groundwater monitoring wells often cause costly delays in site evaluation. Little is known about how monitoring well design and installation affect this rate of appearance. This study examined the effects of well screen open area, filter pack grain size and wettability, and well development methods on the rate of appearance and subsequent thickness of free product in wells.

Laboratory and field results indicate that free product appears faster in hydrophilic filter packs than in hydrophobic filter packs. Hydrophobic filter packs with a finer grain size than the "industry standard", seem …

Sm-Nd Systematics As Indicators Of Displaced Plutons: A Test In The Idaho Batholith-Boulder Batholith Region, Christine J. Brand

Masters Theses

In east-central Idaho and western Montana a 400km-long Cretaceous and Tertiary magmatic corridor extends from the Wallowa-Seven Devils terrane to the Helena Salient. Three basement provinces underlie this area: Archean basement to the east, Permo-Triassic basement to the west, and Proterozoic basement in-between. Ideally, if Cretaceous plutons were decapitated and translated eastward along thrusts over a different basement province, then the Cretaceous pluton and the in-place Tertiary pluton would show different isotopic signatures. Pluton samples from locations evenly spaced throughout the magmatic corridor were analyzed for ε⁰_Nd, ε^t_Nd, and ¹⁴⁷Sm/¹⁴³Nd model ages …