Physical Sciences and Mathematics Commons^™

Collision Spectroscopy Of Low Energy Capture By Multiply Charged Ions From Atomic Targets, Kadir Akgungor

Dissertations

State-selective differential cross sections for single-electron capture processes in very slow collisions of Ar^q+ (q = 4 - 6) ions with Ne, and Ar^6+ ions with He have been studied experimentally at laboratory collision energies between 15 and 100 qeV, and at scattering angles between 0° and 8° by means of translational energy-gain spectroscopy technique. The translational energy spectra show that only a few final states are populated depending on the charge state of the projectile, the projectile laboratory scattering angle, and the collision energy. These measurements also show that the dominant reaction channels are due to capture into excited …

An Integrated Environment For Problem Solving And Program Development, Fadi Pierre Deek

Dissertations

A framework for an integrated problem solving and program development environment that addresses the needs of students learning programming is proposed. Several objectives have been accomplished: defining the tasks required for program development and a literature review to determine the actual difficulties involved in learning those tasks. A comprehensive Study of environments and tools developed to support the learning of problem solving and programming was then performed, covering programming environments, debugging aids, intelligent tutoring systems, and intelligent programming environments. This was followed by a careful analysis and critique of these systems, which uncovered the limitations that have prevented them from …

Modeling Study On The Neopentyl+ O2 Reaction System And Experimental And Modeling Study On Mtbe Pyrolysis And Oxidation, Ru Wei

Dissertations

A modeling study on neopentyl radical + O₂ reaction system is conducted in this study. Thermodynamic parameters on all species and important transition states are calculated. A thermochemical kinetic analysis is performed.

Thermodynamic parameters are estimated using group additivity with HBI groups. Transition state energies are evaluated from experimental and theoretical data in the literature, combined with elementary reaction modeling to account for temperature effects. Transition state structures, vibration frequencies and entropies are determined from semi-empirical calculations, MOPAC PM3. Kinetics are analyzed with quantum RRK theory for k(E) coupled with modified strong collision analysis of Gilbert et al for …

Diffusive And Wavelike Phenomena In Thermal Processing Of Materials, John A. Pelesko

Dissertations

Contemporary materials science abounds with novel processing methods. Devices such as lasers, microwave sources, and electron beam guns, provide unprecedented control over the deposition of energy within a material. The modern materials scientist has the ability to deposit energy volumetrically, to precisely control the location of energy deposition within a material, and to deposit energy in extremely short intervals of time. While making possible numerous thermal processing methods, these devices also push the limits of our understanding of the response of materials to energy deposition. In order to optimize and control these processing methods, it becomes necessary to further our …

Systematics Of Stable Isotopes And Radionuclides In Precipitation At Kalamazoo, Michigan, Usa, Madhav V. Machavaram

Dissertations

Precipitation samples were collected at Kalamazoo from June 1992 to March 1995. The samples were analyzed for their 8D and 8lgO values. The 5D - 5I80 relationship is comparable to that of Meteoric Water Line (MWL). The monthly mean isotopic values in precipitation exhibited strong seasonality, being higher in summer and lower in winter months. This behavior is apparently a direct consequence of the temperature effect on isotope fractionation.

The summer precipitation at Kalamazoo is derived predominantly from the water vapor originated in the Gulf of Mexico. A box model calculation showed that a Rayleigh type distillation with Gulf moisture …

Domination In Digraphs, Lisa Hansen

Dissertations

No abstract provided.

Groundwater-Kalamazoo River Interaction Near The Parchment City Wellfield, Parchment, Michigan, W. Richard Laton

Dissertations

A detailed hydrogeologic study of the Kalamazoo River and its interaction with the groundwater was completed near Parchment, Michigan. The Kalamazoo River between Portage Creek and Allegan Dam is a Federal superfund site due to PCB contamination trapped in its sediments. The City of Parchment pumps all of its drinking water from a glacial aquifer 850 feet from the Kalamazoo River. This study focused on the hydrogeology and groundwater/surface interaction of the area through the use of surface and downhole geophysics, installation of monitoring wells and peizometers, seepage meters and chemical sampling. It was determined that the Kalamazoo River is …

Bandwidth, Edgesum And Profile Of Graphs, Yung-Ling Lai

Dissertations

No abstract provided.

A Robust Estimate For An Autoregressive Time Series, Jeffrey Terpstra

Dissertations

A weighted rank-based estimate for estimating the parameter of an auto-regressive time series is considered. When the weights are constant, the estimate is equivalent to using Jaeckel’s estimate and Wilcoxon scores. The estimate can be shown to be asymptotically normal at rate y/n. In a linear regression setting this estimate has the desired properties of a continuous totally bounded influence function and a positive breakdown point. It is shown via examples and Monte Carlo that these properties are preserved in an autoregressive time series setting.

Localization And Transport Effects In The Disordered Materials, Vladislav Malyshkin

Dissertations

No abstract provided.

Efficient Parallel Processing With Optical Interconnections, Lili Hai

Dissertations

With the advances in VLSI technology, it is now possible to build chips which can each contain thousands of processors. The efficiency of such chips in executing parallel algorithms heavily depends on the interconnection topology of the processors. It is not possible to build a fully interconnected network of processors with constant fan-in/fan-out using electrical interconnections. Free space optics is a remedy to this limitation. Qualities exclusive to the optical medium are its ability to be directed for propagation in free space and the property that optical channels can cross in space without any interference. In this thesis, we present …

An Investigation Of The Oxygraphic Response Of Stressed Bovine Blood, Cristin Mckenna

Dissertations

Oxygraphic profiles of stressed bovine blood in a temperature controlled 2 ml reactor vessel provide the basis for an investigation of blood's response to various conditions. This response is broken down into an initial response (within 3 seconds), the response over 1 hour and the response over 24 hours. Fast-assay runs which investigate the initial response display a dose-response relationship when chemically stressed by phenol. Phenol concentrations in the 1,000 ppm range indicate a decrease in dissolved oxygen (DO) and higher phenol concentrations of over 20,000 an increase in DO. In addition to phenol concentration, other factors investigated with respect …

Multi-Wavelength Infrared Imaging Computer Systems And Applications, Jun Li

Dissertations

This dissertation presents the development of three computer systems for multi-wavelength thermal imaging.

Two computer systems were developed for the multi-wavelength imaging pyrometers (M-WIPs) that yield non-contact temperature measurements by remotely sensing the surface of objects with unknown wavelength-dependent emissivity. These M-WIP computer systems represent the state-of-art development in remote temperature measurement system based on the multi-wavelength approach. The dissertation research includes M-WIP computer system integration, software development, performance evaluation, and also applications in monitoring and control of temperature distribution of silicon wafers in a rapid thermal process system.

The two M-WIPs are capable of data acquisition, signal processing, system …

High Speed Protocols For Dual Bus And Dual Ring Network Architectures, Yaling Zhou

Dissertations

In this dissertation, two channel access mechanisms providing fair and bandwidth efficient transmission on dual bus and dual ring networks with high bandwidth-latency product are proposed. In addition, two effective priority mechanisms are introduced to meet the throughput and delay requirements of the diverse arrays of applications that future high speed networks must support.

For dual bus architectures, the Buffer Insertion Bandwidth Balancing (BI_BWB) mechanism and the Preemptive priority Bandwidth Balancing (P_BI_BWB) mechanism are proposed. BI_BWB can significantly improve the delay performance of remote stations. It achieves that by providing each station with a shift register into which the station …

Sampling And Analysis Of Trace Level Volatile Organic Compounds From Air Via Membrane Permeation, Naihong Zhu

Dissertations

The objective of this study is to develop air sampling techniques using membrane permeation. Two novel techniques for sampling and analysis of trace level VOCs from air via membrane permeation are presented:

1. selective concentration of VOCs into a canister using a membrane permeator;
2. on-line membrane extraction for direct introduction of VOCs from air emissions into a gas chromatograph.

In the membrane permeator-canister sampling system (MPCS), the air sample containing trace level VOCs as well as some interferences such as moisture are passed through the membrane module. Polydimethyl siloxane membrane used in this research is highly permeable to organic compounds, but …

On Document Filing Based Upon Predicates, Zhijian Zhu

Dissertations

This dissertation presents a formal approach to modeling documents in a personal office environment, proposes a heterogeneous algebraic query language to manipulating objects (folders) in the document model, and investigates a predicate-driven document filing system for automatically filing documents.

The document model was initially proposed in [38] which adopts a very natural view for describing the office documents using the relational and object-oriented paradigms. The model employs a dual approach to classifying and categorizing office documents by defining both a document type hierarchy and a folder organization. This dissertation extends and specifies formally the document model. Documents are partitioned into …

Reconstruction Of Wetland Hydrology Dynamics Using Tree Rings, Allan P. Hascall Iii

Dissertations

Increment core samples were collected and examined to test the hypothesis that the history of punctuated or intermediate-term changes in wetland soil-moisture conditions can be reconstructed from the annual growth-ring record of trees. The hypothesis is based on plant physiological principles that indicate a relationship between water surplus stress and impaired physiological activity that could lead to reduced growth.

Sampling sites were selected for their ostensible historic hydrologic variability and the availability of documentation of hydrologic disturbances. A conceptual model was developed by which trees were sampled along a hydrotopographic gradient for comparison of radial stem growth in uplands versus …

Study Of Impurity Modes In Photonic Crystals And Study Of Power Gaas Mesfets, Michael G. Khazhinsky

Dissertations

The dissertation consists of two projects. In the first project, impurity modes in Photonic Crystals are studied in one- and two-dimensional Photonic Crystals. Onedimensional systems are formed from an infinite layered array of dielectric slabs and are studied for linearly polarized electromagnetic waves propagating perpendicular to the plane of slabs. Two-dimensional systems consist either of parallel cylindrical dielectric rods in vacuum or cylindrical holes containing vacuum in dielectric medium. These rods/holes are arranged in a square lattice array. The electromagnetic waves in these system propagate perpendicular to the axes of the rods and are of E or H polarization. Green’s …

Least Space-Time First Scheduling Algorithm : Scheduling Complex Tasks With Hard Deadline On Parallel Machines, Bo-Chao Cheng

Dissertations

Both time constraints and logical correctness are essential to real-time systems and failure to specify and observe a time constraint may result in disaster. Two orthogonal issues arise in the design and analysis of real-time systems: one is the specification of the system, and the semantic model describing the properties of real-time programs; the other is the scheduling and allocation of resources that may be shared by real-time program modules.

The problem of scheduling tasks with precedence and timing constraints onto a set of processors in a way that minimizes maximum tardiness is here considered. A new scheduling heuristic, Least …

Massively Parallel Reasoning In Transitive Relationship Hierarchies, Yugyung Lee

Dissertations

This research focuses on building a parallel knowledge representation and reasoning system for the purpose of making progress in realizing human-like intelligence. To achieve human-like intelligence, it is necessary to model human reasoning processes by programs. Knowledge in the real world is huge in size, complex in structure, and is also constantly changing even in limited domains. Unfortunately, reasoning algorithms are very often intractable, which means that they are too slow for any practical applications. One technique to deal with this problem is to design special-purpose reasoners. Many past Al systems have worked rather nicely for limited problem sizes, but …

Safe Code Transfromations For Speculative Execution In Real-Time Systems, Mohamed Mohamed Younis

Dissertations

Although compiler optimization techniques are standard and successful in non-real-time systems, if naively applied, they can destroy safety guarantees and deadlines in hard real-time systems. For this reason, real-time systems developers have tended to avoid automatic compiler optimization of their code. However, real-time applications in several areas have been growing substantially in size and complexity in recent years. This size and complexity makes it impossible for real-time programmers to write optimal code, and consequently indicates a need for compiler optimization. Recently researchers have developed or modified analyses and transformations to improve performance without degrading worst-case execution times. Moreover, these optimization …

Development Of Crosslinking Reagents, And Intra- And Intermolecular Multi-Linking Hemoglobin Molecules As Potential Blood Substitutes, Yaguo Zheng

Dissertations

No abstract provided.

Asymmetric Synthesis By Palladium (Ii) Catalysis: Chirality Transfer And New A Symmetric Catalytic System, Othman Hamed

Dissertations

No abstract provided.

Multinuclear Magnetic Resonance Studies Of Anion Binding To Copper, Zinc-Superoxide Dismutase, And Of Lithium Transport And Binding In Cultured Neuroblastoma Cells, Cherian Zachariah

Dissertations

No abstract provided.

Ionic Interaction Studies Of Bovine Copper, Zinc-Superoxide Dismutase, Hanan A. Hasan

Dissertations

No abstract provided.

The Computational Study Of "Model" Pollutants In Clay Montmorillonite, Sung-Ho Park

Dissertations

No abstract provided.

Ph And Osmolality Effects On Lipid-Enhanced Sickle And Normahemoglobin Oxidation, Sharron Kay Jenkins

Dissertations

No abstract provided.

A Multinuclear Magnetic Resonance Study Of Cesium And Chloride Distribution In Human Erythrocyte Suspensions, Wanrong Lin

Dissertations

No abstract provided.

Novel Palladium (Ii) Catalysts For Asymmetric Synthesis, Arab El-Qisairi

Dissertations

No abstract provided.

Competition Between Li+ And Mg2+ For Human Rbcmembrane Phospholipids And Guanine Nucleotide Binding Proteins, Chandra Srinivasan

Dissertations

No abstract provided.