Physical Sciences and Mathematics Commons^™

Experiments In Aerobic And Anaerobic Biodegradation Of Trichloroethylene, Qiong Liao

Theses

The removal of trichloroethylene (TCE) from industrial waste has been intensively studied in recent years, Biodegradation has been determined to be an effective treatment for TCE in the environment. Many researchers have studied the biodegradation of TOE and obtained successful results based on the use of specific isolated bacteria. At the NJIT Biotechnology Laboratory, a new method is being developed in which immobilized activated sludge is used to degrade several toxic chemicals in various reactor configurations. The objective of this research is to determine if these methods can be extended to treat TCE.

Activated sludge from a wastewater treatment plant …

Paint Stripper Composition Having Reduced Volatility Containing Decanolactone, N-Methylpyrrolidone And Butyrolactone And Method Of Use, Harvest L. Collier, Gary L. Bertrand, Raymond L. Venable

Chemistry Faculty Research & Creative Works

An improved composition of matter and method of use for removing cured coatings of paint or varnish or other similar coatings from substrates. The composition comrpises chlorinated solvent paint strippers (especially methylene chloride (CH₂CI₂)), waxes and an additive selected from the group consisting of decanolactone (C₁₀H₁₈O₂), N-methylpyrrolidone (CH₃NCH₂CH₂CH₂CH₂) and butyrolactone (OCH₂CH₂CH₂CO). The additive retards the evaporation of the solvent resulting in a composition that is environmentally less hazardous to a user and also resulting …

Resolution Of Enantiomeric Hydrocarbon Biomarkers Of Geochemical Importance, Daniel W. Armstrong, Yubing Tang, Janusz Zukowski

Chemistry Faculty Research & Creative Works

Chlral isoprenoid and hydroaromatic compounds occur in all crude oils, coals, shales, and most sediments. Many of these compounds are referred to as biological markers since they are thought to be derived from biological sources and their presence, relative concentrations, or stereochemistry can provide information as to a geological deposit's age, maturity, diagenetic history, and so forth. Because of the previous lack of effective and efficient analytical methodologies for resolving hydrocarbon enantiomers, the stereochemical information encoded in these molecules is largely untouched. A series of derivatized α-, β-, and γ-cyclodextrin chiral stationary phases (CSPs) were used for the gas chromatographic …

Structural Characterization Of Mixed Alkali Metal Bis(Trimethylsilyl)Amide Bases., Paul Williard, Michael Nichols

Michael A Nichols

No abstract provided.

Polymer Research In Austria. I: Introduction And The Facilities, Otto Vogl, Josef Schurz, Bernd Thrattnigg, Klaus Hummel, Wolfgang Daimler, Klaus Lederer

Emeritus Faculty Author Gallery

No abstract provided.

Japan-U.S. Seminar On Polymer Synthesis, Otto Vogl, Hiroyuki Nishide

Emeritus Faculty Author Gallery

No abstract provided.

Consumption Rates, Evacuation Rates And Diets Of Pygmy Killifish, Leptolucania Ommata, And Mosquitofish, Gambusia Affinis In The Okefenokee Swamp, J. Douglas Oliver

Faculty Publications and Presentations

I studied feeding dynamics of Leptolucania ommata and Gambusia affinis in the Okefenokee Swamp. Both fishes mainly ate insect larvae (such as Chironomidae) and Cladocera. Evacuation rates ranged from 0.143 (L. ommala in winter) to 0.279/hour (L. ommala in summer). Daily food consumption (dry weight) ranged from 24.2 (L. ommata in winter) to 148.3 mg/g/day (G. affinis in summer). Maximum consumption by both species was estimated at 26.31 mg/t m2 / day, in summer. These values are consistent with other observations supporting a hypothesis that invertebrate prey production is substantial in these blackwater wetlands.

Polymer Research In Austria. I: Introduction And The Facilities, Otto Vogl, Josef Schurz, Bernd Thrattnigg, Klaus Hummel, Wolfgang Daimler, Klaus Lederer

Otto Vogl

No abstract provided.

Japan-U.S. Seminar On Polymer Synthesis, Otto Vogl, Hiroyuki Nishide

Otto Vogl

No abstract provided.

Electron-Energy And –Angular Distributions In The Double Photoionization Of Helium, R. Wehlitz, Franz Heiser, Oliver Hemmers, B. Langer, A. Menzel, U. Becker

Environmental Studies Faculty Publications

Photoelectron spectra of helium have been measured at different angles and at various energies above the double-ionization threshold up to 120 eV to investigate the behavior of the energy and angular distributions, of shake-off electrons. Both energy and angular distributions clearly show a U-shaped profile which turns to a flat curve near threshold pointing to a uniform intensity distribution over the kinetic energy for all angles in this excitation energy regime. Our results for the angular-distribution asymmetry parameter indicate qualitative agreement with theoretical predictions but fail to provide them quantitatively.

Surface Structure Of √3x√3r 30 Cl/Ni(111) Determined Using Low-Temperature Angle-Resolved-Photoemission Extended Fine Structure, Li-Qiong Wang, Z. Hussain, Z. Q. Huang, A. E. Schach Von Wittenau, Dennis W. Lindle, D. A. Shirley

Chemistry and Biochemistry Faculty Research

A surface structural study of the √3 × √3 R30° Cl/Ni(111) adsorbate system was made using low-temperature angle-resolved photoemission extended fine structure. The experiments were performed along two emission directions, [111] and [110], and at two temperatures, 120 and 300 K. The multiple-scattering spherical-wave analysis determined that the Cl atom adsorbs in the fcc threefold hollow site, 1.837(8) Å above the first nickel layer, with a Cl-Ni bond length of 2.332(6) Å, and an approximate 5% contraction between the first and the second nickel layers (the errors in parentheses are statistical standard deviations only).

Reductive Cleavage Of Cyclopentadienylmanganese Tricarbonyl, Mani S. Iyer

Masters Theses

Since the isolation of ferrocene in 1951, it has been shown to behave like benzene and may be acylated, sulfonated, metalated, and arylated. Like benzene, it also resists hydrogenation.

Daniel Trifan and Louis Nicholas (1957) were the first to show that ferrocene can be smoothly degraded by lithium and ethylamine. The isolation of free cyclopentadienyl ion on hydrolysis of the reaction mixture indicates that the cleavage leads initially to cyclopentadienyl lithium salt. A similar procedure applied to cyclopentadienylmanganese tricarbonyl also resulted in the formation of cyclopentadienyl lithium salt. This, when added to ferrous chloride, gave ferrocene. This technique can be …

Selected Studies On Certain Iron Sandwich Complexes, Mashitah M. Yusoff

Masters Theses

In these studies, the synthesis of [2.3](1,3)cyclopentadiendoparacyclophane was attempted. Like ferrocene and [2.2]paracyclophane, it is expected to exhibit transannular π-electronic interaction throughout its molecular structure and therefore, one dimensional semiconductivity.

The preparation of dialkylferrocenes had resulted in complex inseparable mixtures. Due to the fluxional nature of its intermediates, their conversion to stable Diels-Alder adducts would facilitate analysis. In this project, certain Diels-Alder adducts of bis-cyclopentadienyliron dicarbonyl intermediates were prepared for analysis.

Very few transition metal complexes of pyrrole are currently known. [2.2](2,5)Pyrroloparacyclophane was perceived to be stable especially as a part of an iron sandwich complex. The final phase …

Electrochemical And Spectroscopic Investigations Of The Properties Of Electrified Interfaces, Mark Anderson

Mark R. Anderson

No abstract is available at this time.

The Influence Of Cation Size Upon The Infrared Spectrum Of Carbon Monoxide Adsorbed On Platinum Electrodes, Mark Anderson, Jimin Huang

Mark R. Anderson

The infrared spectrum of carbon monoxide adsorbed on polycrystalline platinum electrodes in the presence of acetonitrile solutions is examined. Acetonitrile solutions provide a wide double layer region (approximately 4 V) in which to investigate the observed potential dependence of the infrared peak position. The wider window allows for better comparisons of experimental data with theoretical predictions than those which are available from measurements conducted in aqueous solutions. It is found that (i) near-monolayer surface coverage can be obtained from solutions saturated with CO, (ii) the coverage stays constant over roughly the entire double layer region, (iii) the CO adsorbs to …

Mass Asymmetric Fission Barriers For 75br, D. N. Delis, Y. Blumenfeld, D. R. Bowman, N. Colonna, K. Hanold, K. Jing, M. Justice, J. C. Meng, Graham F. Peaslee, G. J. Wozniak, L. G. Moretto

Faculty Publications

Fragments with atomic numbers covering nearly the entire range of the mass-asymmetry coordinate (4 < Z < 27) were observed from the 5.0, 6.2, 6.9, 8.0, 10.2 and 12.7 MeV/A 63Cu + 12C reactions. Energy spectra and angular distributions show the presence of projectile-like and target-like components along with an isotropic component. The isotropic component appears as a Coulomb ring in the invariant cross-section plots indicating the presence of a binary compound nucleus decay which is confirmed by the coincidence data. Excitation functions were constructed for each Z value and a nearly complete set of mass-asymmetric barriers has been extracted for 75Br. There is excellent agreement between the experimentally determined barriers and the finite-range model predictions.

Spectroelectrochemical Analysis Of Spontaneously Adsorbed Monolayers, Marilyn O'Grady, Mark Anderson

Mark R. Anderson

No abstract is currently available.

An Analytical Representation Of The Lowest Potential Energy Surface For The Reaction O(3 P)+Hcl (X  1Σ+)→Oh(X  2Π)+Cl(2 P), H. Koizumi, George C. Schatz, Mark S. Gordon

Mark S. Gordon

We present a new analytical representation of the lowest 3 A‘ energy surface for the reaction O(3 P)+HCl(X  1Σ+)→OH(X  2Π)+Cl(2 P). This surface is derived by fitting a b i n i t i o calculations, and adjustments are made to the barrier height so that rate constants derived from accurate quantum scattering calculations match the room temperature thermal rate constants. Contributions to thermal and state resolved rate constants arising from reaction on the lowest 3 A’surface are also considered. Comparisons of thermal and state resolved rate constants with experiment are good except at high temperature where the 3 A’ …

Change Of Magnetic Properties Of Th₂Fe₁₇ Due To Interstitial Solution Of C And N, T. H. Jacobs, Gary J. Long, Oran Allan Pringle, Fernande Grandjean, K. H. Buschow

Chemistry Faculty Research & Creative Works

The changes in magnetic and crystallographic properties in the series Th₂Fe₁₇C_x and Th₂Fe ₁₇N_x have been studied. The changes in the latter series were also studied by ⁵⁷Fe Mössbauer spectroscopy. The ultimate enhancements of the saturation moments in these series are 13% and 24%, respectively. This is much larger than observed previously in the corresponding rare-earth compounds, although the Curie temperature enhancements are of comparable magnitude. In the Th-Fe-C system a novel compound of the BaCd ₁₁ type was found, having a Curie temperature around 370 K.

A Collaborative Summer Research Program For Community College Students, Chris Craney, Franklin Dehaan

Chris L. Craney

While the benefits of undergraduate research are well established, little attention has been paid toward involving community college students in such research. This paper describes a five-year-experience with a summer research program that includes Los Angeles area community college students working side-by-side with Occidental College students and faculty.

Multifragment Emission In The Reaction 36ar + 197au At E/A = 35, 50, 80, And 110 Mev, R. T. De Souza, L. Phair, D. R. Bowman, N. Carlin, C. K. Gelbke, W. G. Gong, Y. D. Yim, M. A. Lisa, W. G. Lynch, Graham F. Peaslee, M. B. Tsang, H. M. Tsang, H. M. Xu, F. Zhu, W. A. Friedman

Faculty Publications

Multifragment emission in the reaction at has been measured with a low-threshold 4π detector array. Over this broad range of incident energies, the mean values and variances of the intermediate mass fragment (IMF: 3 ⩽ Z ⩽ 20) multiplicity distributions exhibit an approximate scaling with the total charged particle multiplicity. The measured multiplicities of light charged particles and intermediate mass fragments are compared with both a model involving statistical decay of an expanding compound nucleus, and with a model involving microscopic quasi-particle dynamics. The statistical decay model predictions are sensitive to the low-density nuclear equation of state.

The Conformational Potential Energy Surface Of Glycine: A Theoretical Study, Jan H. Jensen, Mark S. Gordon

Mark S. Gordon

The conformational potential energy surface of nonionized glycine has been studied by using ab initio (6-310*, ST0-20) and semiempirical (AM1, PM3) methods. The MP2/6-31G*/ /RHF/6-310* potential energy surface was then used to calculate the Boltzmann equilibrium distribution and kinetics of conformational interconversion at various temperatures. The results of this study are compared to previous computational and experimental investigations of gas-phase glycine.

Structures And Bonding Of Group Iv Sulfur And Oxygen Propellane Derivatives, Kiet A. Nguyen, Marhsall T. Carroll, Mark S. Gordon

Mark S. Gordon

The RHF, ROHF, and GVB structures and energetics of group IV 2,4,5-trioxa[l.l.l]metallapropellanes, 2,4,5- trithia [ l.l.l]metallapropellanes, and their bicyclopentane analogues have been determined from ab initio molecular orbital theory by using both the 6-31G(d) basis set for all-electron calculations and the valence basis set with effective core potentials (ECP) developed by Stevens, Basch, and Krauss. Although they have extremely short bridgehead distances, these species possess fairly large natural orbital occupation numbers in the lowest unoccupied molecular orbitals, indicating significant diradical character. Structures and other properties determined by ECP calculations are in good agreement with the 6-31 G(d) all-electron calculations.

Reactions Of Aqueous Chlorine With Valine In Model Solutions And In Wastewater, Erika Forrer Mccormick

Chemistry & Biochemistry Theses & Dissertations

Solutions of the amino acid valine were chlorinated to seven chlorine-to-nitrogen mole (Cl/N) ratios and analyzed by high performance liquid chromatography, gas chromatography/mass spectroscopy, infrared spectroscopy, and nuclear magnetic resonance spectroscopy. The chlorination products found were N-chlorovaline, isobutyraldehyde, isobutyronitrile, and N-chloroisobutyraldimine. Their product distribution depends on the level of chlorination and pH. The main products identified at the lower CI/N mole ratios were N-chlorovaline and isobutyraldehyde, whereas at the higher CI/N mole ratios isobutyronitrile and N-chloroisobutyraldimine were identified as the main products. The concentration and the chlorination products of valine in municipal wastewater were also determined. The chlorination products of …

Ua66/7/2 Hilltopper News, Wku Chemistry

WKU Archives Records

Newsletter created by and about the WKU Chemistry department.

Thermal Characterization Of Carbon Monoxide Oxidation Catalysts Using Thermogravimetric Analysts And Differential Scanning Calorimetry, Rene A. Bartgis

Chemistry & Biochemistry Theses & Dissertations

Catalysts composed of platinum and/or palladium on tin (IV) oxide supports, with and without silica gel, as well as catalysts composed of gold on manganese oxide, have been developed for the recombination of carbon monoxide and oxygen to form carbon dioxide for use in carbon dioxide lasers. A thermogravimetric method and a differential scanning calorimetric method have been developed for the thermal characterization of these catalysts. The mass loss data and the enthalpy changes determined as the catalysts lost water were then related to existing activity data for these catalysts. No relationship was found between the thermal data and the …

Spectroelectrochemical Analysis Of Metal Surfaces Modified With Thin Organic Films, Marilyn O'Grady, Mark Anderson

Mark R. Anderson

No abstract is currently available.

Determination Of The Vertical Ionization Potentials Of Small Sodium Clusters Using Path Integral Monte Carlo Calculations, Sean E. Hays, Randall W. Hall

Randall W. Hall

Reply To "Comment On 'Kinetic-Energy Density Functional For A Special Shape-Invariant Potential Of A One-Dimensional Two-Level System'", Jiushu Shao, John J. Stezowski

John J. Stezowski Publications

For a harmonic potential, which is the special shape-invariant potential discussed in our paper [1], the relation between the ground state and the first-excited-state wave functions [Eq. (2)] should be . . .

Therefore, we have shown that one cannot find a closed form of the kinetic-energy density for the harmonic oscillator.

Structural Changes And Enhancements In Dnase I Footprinting Experiments?, Jerry Goodisman, James C. Dabrowiak

Chemistry - All Scholarship

In footprinting experiments, an increase in DNA cleavage with addition of ligand to a system may be due to a ligand-induced structural change. Ligand binding also enhances cleavage by displacing the cleavage agent from ligand-binding sites, thus increasing its concentration elsewhere. The theory and characteristics of this mass-action enhancement are given, and it is shown how it may be recognized. Results of DNase I footprinting of small oligomers, with actinomycin D as ligand, are analyzed to reveal which enhancements are due to mass action, and which can reasonably be ascribed to structural changes. Patterns in the footprinting plots from our …