Physical Sciences and Mathematics Commons^™

Understanding The Impact Of Microplastic Contamination On Soil Quality And Eco-Toxicological Risks In Horticulture: A Comprehensive Review, N. P. Gayathri, Geena Prasad, Vaishna Prabhakaran, Vishnu Priya

Research outputs 2022 to 2026

The horticulture sector, essential for global food production, confronts significant challenges with prevalent pollutants, mainly microplastics. The presence of microplastics in the food chain has induced physiological stress and a multifactorial food safety concern. The complexity of the problem, arising from intricate interactions among microplastics, organisms, and ecosystems, poses a substantial challenge to food safety, necessitating an immediate strategic perspective due to the associated risks to human health and eco-toxicology. Significant knowledge gaps persist regarding their impact on terrestrial ecosystems, especially in horticulture. This study addresses the urgent need to comprehend the implications of microplastics on soil health, eco-toxicological risks, …

Microplastics Fouling Mitigation In Forward Osmosis Membranes By The Molecular Assembly Of Sulfobetaine Zwitterion, Javad Farahbakhsh, Mitra Golgoli, Mehdi Khiadani, Amir Razmjou, Masoumeh Zargar

Research outputs 2022 to 2026

Forward osmosis (FO) membranes have potential for the efficient water and wastewater treatment applications. However, their development has faced significant challenges due to their fouling propensity. In this study, FO membranes modified with sulfobetaine zwitterions (i.e., [2-(Methacryloyloxy)ethyl]dimethyl-(3-sulfopropyl) ammonium hydroxide) were fabricated and used for the first time to address microplastic (MP) fouling issue. Water flux, reverse salt flux (RSF), fouling, and flux recovery were evaluated for the membranes loaded with different quantities of the zwitterions ranging from 0.25 % to 2 %. The developed membranes were tested over 49 h with feed solutions containing polyethylene MPs and bovine serum albumin …

Multi-Aspect Rule-Based Ai: Methods, Taxonomy, Challenges And Directions Towards Automation, Intelligence And Transparent Cybersecurity Modeling For Critical Infrastructures, Iqbal H. Sarker, Helge Janicke, Mohamed A. Ferrag, Alsharif Abuadbba

Research outputs 2022 to 2026

Critical infrastructure (CI) typically refers to the essential physical and virtual systems, assets, and services that are vital for the functioning and well-being of a society, economy, or nation. However, the rapid proliferation and dynamism of today's cyber threats in digital environments may disrupt CI functionalities, which would have a debilitating impact on public safety, economic stability, and national security. This has led to much interest in effective cybersecurity solutions regarding automation and intelligent decision-making, where AI-based modeling is potentially significant. In this paper, we take into account “Rule-based AI” rather than other black-box solutions since model transparency, i.e., human …

Simultaneous Extraction And Quantitative Analysis Of S-Methyl-L-Cysteine Sulfoxide, Sulforaphane And Glucosinolates In Cruciferous Vegetables By Liquid Chromatography Mass Spectrometry, Armaghan Shafaei, Caroline R. Hill, Jonathan M. Hodgson, Lauren C. Blekkenhorst, Mary C. Boyce

Research outputs 2022 to 2026

Sulfur containing compounds including glucosinolates (GLS), sulforaphane (SFN) and S-methyl-L-cysteine sulfoxide (SMCSO) have been proposed to be partly responsible for the beneficial health effects of cruciferous vegetables. As such, greater understanding of their measurements within foods is important to estimate intake in humans and to inform dietary intervention studies. Herein is described a simple and sensitive method for simultaneous analysis of 20 GLS, SFN and SMCSO by liquid chromatography mass spectrometry. Analytes were effectively retained and resolved on an Xbridge C18 column. Detection can be achieved using high resolution or unit resolution mass spectrometry; the latter making the method more …

Drought Legacy Interacts With Wildfire To Alter Soil Microbial Communities In A Mediterranean Climate-Type Forest, Anna J. M. Hopkins, Aaron J. Brace, Jess L. Bruce, J. Hyde, J. B. Fontaine, L. Walden, W. Veber, K. X. Ruthrof

Research outputs 2022 to 2026

Mediterranean forest ecosystems will be increasingly affected by hotter drought and more frequent and severe wildfire events in the future. However, little is known about the longer-term responses of these forests to multiple disturbances and the forests' capacity to maintain ecosystem function. This is particularly so for below-ground organisms, which have received less attention than those above-ground, despite their essential contributions to forest function. We investigated rhizosphere microbial communities in a resprouting Eucalyptus marginata forest, southwestern Australia, that had experienced a severe wildfire four years previously, and a hotter drought eight years previously. Our aim was to understand how microbial …

Investigating Communication Of Findings In Environmental Impact Assessment And Developing A Research Agenda For Improvement, Alan Bond, Francois Retief, Angus Morrison-Saunders, Jenny Pope, Reece C. Alberts, Claudine Roos, Dirk Cilliers

Research outputs 2022 to 2026

Environmental Impact Assessment (EIA) aims to embed consideration of the significance of predicted environmental consequences (the findings) of proposed developments into approval decision making. Achieving this aim relies on adequate communication of the findings of the EIA to the stakeholders, especially the decision makers responsible for the approval decision. However, the naïve assumption that this communication of findings can be effectively achieved through the publication of a written report pervades legislation worldwide, despite decades of evidence to the contrary. As a first step towards improving such communication, this research identifies the contingent conditions associated with effectively transferring EIA findings from …

Maximizing Charge Dynamics In Znin2s4/Cn Van Der Waals Heterojunction For Optimal Hydrogen Production From Photoreforming Of Glucose, Jinqiang Zhang, Xinyuan Xu, Lei Shi, Huayang Zhang, Shaobin Wang, Hongqi Sun

Research outputs 2022 to 2026

Biomass photoreforming stands out as a promising avenue for green hydrogen, leveraging solar energy for the generation and transformation of clean and renewable energy resources. The pursuit of efficient photocatalysts is motivated by the unsatisfied hydrogen evolution performance arising from the complex and stubborn structure of biomass. Herein, we loaded 2-dimensional (2D) ZnIn2S4 onto 2D carbon nitride nanosheets, resulting in the formation of Van der Waals (VDW) heterojunctions (ZIS/CN). Band structure and morphology of CN were rationally tailored through precursor engineering to effectively magnify interfacial internal electric field and minimize diffusion pathway within the VDW heterostructure, realizing optimal charge dynamics …

Examination Of Traditional Botnet Detection On Iot-Based Bots, Ashley Woodiss-Field, Michael N. Johnstone, Paul Haskell-Dowland

Research outputs 2022 to 2026

A botnet is a collection of Internet-connected computers that have been suborned and are controlled externally for malicious purposes. Concomitant with the growth of the Internet of Things (IoT), botnets have been expanding to use IoT devices as their attack vectors. IoT devices utilise specific protocols and network topologies distinct from conventional computers that may render detection techniques ineffective on compromised IoT devices. This paper describes experiments involving the acquisition of several traditional botnet detection techniques, BotMiner, BotProbe, and BotHunter, to evaluate their capabilities when applied to IoT-based botnets. Multiple simulation environments, using internally developed network traffic generation software, were …

Analysis Of The Outer Retinal Bands In Abca4 And Prph2-Associated Retinopathy Using Oct, Rachael C. Heath Jeffery, Johnny Lo, Jennifer A. Thompson, Tina M. Lamey, Terri L. Mclaren, John N. De Roach, Lauren N. Ayton, Andrea L. Vincent, Abhishek Sharma, Fred K. Chen

Research outputs 2022 to 2026

Purpose: To evaluate the outer retinal bands using OCT in ABCA4- and PRPH2-associated retinopathy and develop a novel imaging biomarker to differentiate between these 2 genotypes. Design: Multicenter case-control study. Participants: Patients with a clinical and genetic diagnosis of ABCA4- or PRPH2-associated retinopathy and an age-matched control group. Methods: Macular OCT was used to measure the thickness of the outer retinal bands 2 and 4 by 2 independent examiners at 4 retinal loci. Main Outcome Measures: Outcome measures included the thicknesses of band 2, band 4, and the band 2/band 4 ratio. Linear mixed modeling was used to make comparisons …

Machine Learning-Enhanced All-Photovoltaic Blended Systems For Energy-Efficient Sustainable Buildings, Mohammad Nur-E-Alam, Kazi Z. Mostofa, Boon K. Yap, Mohammad K. Basher, Mohammad A. Islam, Mikhail Vasiliev, Manzoore E. M. Soudagar, Narottam Das, Tiong S. Kiong

Research outputs 2022 to 2026

The focus of this work is on the optimization of an all-photovoltaic hybrid power generation systems for energy-efficient and sustainable buildings, aiming for net-zero emissions. This research proposes a hybrid approach combining conventional solar panels with advanced solar window systems and building integrated photovoltaic (BIPV) systems. By analyzing the meteorological data and using the simulation models, we predict energy outputs for different cities such as Kuala Lumpur, Sydney, Toronto, Auckland, Cape Town, Riyadh, and Kuwait City. Although there are long payback times, our simulations demonstrate that the proposed all-PV blended system can meet the energy needs of modern buildings (up …

Scene Graph Generation: A Comprehensive Survey, Hongsheng Li, Guangming Zhu, Liang Zhang, Youliang Jiang, Yixuan Dang, Haoran Hou, Peiyi Shen, Xia Zhao, Syed A. A. Shah, Mohammed Bennamoun

Research outputs 2022 to 2026

Deep learning techniques have led to remarkable breakthroughs in the field of object detection and have spawned a lot of scene-understanding tasks in recent years. Scene graph has been the focus of research because of its powerful semantic representation and applications to scene understanding. Scene Graph Generation (SGG) refers to the task of automatically mapping an image or a video into a semantic structural scene graph, which requires the correct labeling of detected objects and their relationships. In this paper, a comprehensive survey of recent achievements is provided. This survey attempts to connect and systematize the existing visual relationship detection …

From Grain To Malt: Tracking Changes Of Ultra-Low-Gluten Barley Storage Proteins After Malting, Mahya Bahmani, Angéla Juhász, Utpal Bos, Mitchell G. Nye-Wood, Malcolm Blundell, Crispin A. Howitt, Michelle L. Colgrave

Research outputs 2022 to 2026

Barley (Hordeum vulgare L.) is a major cereal crop produced globally. Hordeins, the major storage proteins in barley, can trigger immune responses leading to celiac disease or symptoms associated with food allergy. Here, proteomics approaches were employed to investigate the proteome level changes of grain and malt from the malting barley cultivar, Sloop, and single-, double- and triple hordein-reduced lines. The triple hordein-reduced line is an ultra-low gluten barley cultivar, Kebari®. Using discovery proteomics, 2,688 and 3,034 proteins in the barley and malt samples were detected respectively. Through the application of targeted proteomics, a significant reduction in the quantity …

Analysis Of Element Yield, Bacterial Community Structure And The Impact Of Carbon Sources For Bioleaching Rare Earth Elements From High Grade Monazite, Melissa K. Corbett, April Gifford, Nick Fimognari, Elizabeth L. J. Watkin

Research outputs 2022 to 2026

Rare earth element (REE) recovery from waste streams, mine tailings or recyclable components using bioleaching is gaining traction due to the shortage and security of REE supply as well as the environmental problems that occur from processing and refining. Four heterotrophic microbial species with known phosphate solubilizing capabilities were evaluated for their ability to leach REE from a high-grade monazite when provided with either galactose, fructose or maltose. Supplying fructose resulted in the greatest amount of REE leached from the ore due to the largest amount of organic acid produced. Gluconic acid was the dominant organic acid identified produced by …

Performance Evaluation Of A Dual-Chamber Plant Microbial Fuel Cell Developed For Electricity Generation And Wastewater Treatment, Mahmood Golzarian, M. Ghiasvand, S. Shokri, M. Bahreini, Fatemeh Kazemi

Research outputs 2022 to 2026

Plant microbial fuel cells (PMFC) have attracted great scholarly attention as a renewable energy source. These cells have three main components: anode, cathode chambers, and a proton exchange membrane. In this study, a dual-chamber plant microbial fuel cell system was designed using Cyperus papyrus and Shewanella oneidensis. The effects of various factors, including the size of the electrodes, the distance between the electrodes, and the inoculation volume of Shewanella oneidensis, on the ability of electricity generation, were scrutinized. The results indicated that increasing the size area of the electrodes from 2 × 2 to 4 × 4 and 6 × …

Simulating Compatible Solute Biosynthesis Using A Metabolic Flux Model Of The Biomining Acidophile, Acidithiobacillus Ferrooxidans Atcc 23270, Himel N. Khaleque, Hadi Nazem-Bokaee, Yosephine Gumulya, Ross P. Carlson, Anna H. Kaksonen

Research outputs 2022 to 2026

Halotolerant, acidophilic, bioleaching microorganisms are crucial to biomining operations that utilize saline water. Compatible solutes play an important role in the adaptation of these microorganisms to saline environments. Acidithiobacillus ferrooxidans ATCC 23270, an iron- and sulfur-oxidizing acidophilic bacterium, synthesizes trehalose as its native compatible solute but is still sensitive to salinity. Recently, halotolerant bioleaching bacteria were found to use ectoine as their key compatible solute. Previously, bioleaching bacteria were recalcitrant to genetic manipulation; however, recent advancements in genetic tools and techniques allow successful genetic modification of A. ferrooxidans ATCC 23270. Therefore, this study aimed to test, in silico, the effect …

The Impact Of Environmental Policy On Renewable Energy Innovation: A Systematic Literature Review And Research Directions, Hiva Rastegar, Gabriel Eweje, Aymen Sajjad

Research outputs 2022 to 2026

Renewable energy innovations are imperative to tackle the climate change crisis. However, there is a gap in the literature regarding the effectiveness of environmental policies in promoting renewable energy innovations. To bridge this gap, we have adopted a systematic literature review process covering the period from 2005 to 2023. We identified and analysed 29 articles in our final sample. Further, we employ two levels of analysis (individual-policy and policy-mix levels) for analysing the extant research. Our findings show that fiscal incentives and emissions trading policies such as the European Union (EU) Emissions Trading System (ETS) consistently promote renewable energy innovations. …

Unleashing The Power Of Internet Of Things And Blockchain: A Comprehensive Analysis And Future Directions, Abderahman Rejeb, Karim Rejeb, Andrea Appolloni, Sandeep Jagtap, Mohammad Iranmanesh, Salem Alghamdi, Yaser Alhasawi, Yasanur Kayikci

Research outputs 2022 to 2026

As the fusion of the Internet of Things (IoT) and blockchain technology advances, it is increasingly shaping diverse fields. The potential of this convergence to fortify security, enhance privacy, and streamline operations has ignited considerable academic interest, resulting in an impressive body of literature. However, there is a noticeable scarcity of studies employing Latent Dirichlet Allocation (LDA) to dissect and categorize this field. This review paper endeavours to bridge this gap by meticulously analysing a dataset of 4455 journal articles drawn solely from the Scopus database, cantered around IoT and blockchain applications. Utilizing LDA, we have extracted 14 distinct topics …

Region-Specific Drivers Cause Low Organic Carbon Stocks And Sequestration Rates In The Saltmarsh Soils Of Southern Scandinavia, Carmen Leiva-Dueñas, Anna E. L. Graversen, Gary T. Banta, Jeppe N. Hansen, Marie L. K. Schrøter, Pere Masqué, Marianne Holmer, Dorte Krause-Jensen

Research outputs 2022 to 2026

Saltmarshes are known for their ability to act as effective sinks of organic carbon (OC) and their protection and restoration could potentially slow down the pace of global warming. However, regional estimates of saltmarsh OC storage are often missing, including for the Nordic region. To address this knowledge gap, we assessed OC storage and accumulation rates in 17 saltmarshes distributed along the Danish coasts and investigated the main drivers of soil OC storage. Danish saltmarshes store a median of 10 kg OC m−2 (interquartile range, IQR: 13.5–7.6) in the top meter and sequester 31.5 g OC m−2 yr−1 (IQR: 41.6–15.7). …

Understanding The Impact Of Environmental Impact Assessment Research On Policy And Practice, Angus Morrison-Saunders, Annette Nykiel, Nicole Atkins

Research outputs 2022 to 2026

There is an enormous and ever-growing body of environmental impact assessment (EIA) research, much of which is grounded in practice or seeks to advance it. In this paper we show how the impact of EIA research on policy and practice might be conceptualised and how to set about evidencing it. A framework is developed through literature review to account for impact in four areas pertaining to instrumental impact, conceptual impact, capacity building and knowledge brokerage and co-production. Methods for implementing the framework include citations within policy documents along with content analysis to determine influence and interviews or surveys with policy …

Development Of A Regional Climate Change Model For Aedes Vigilax And Aedes Camptorhynchus (Diptera: Culicidae) In Perth, Western Australia, Kerry Staples, Peter J. Neville, Steven Richardson, Jacques Oosthuizen

Research outputs 2022 to 2026

Mosquito-borne disease is a significant public health issue and within Australia Ross River virus (RRV) is the most reported. This study combines a mechanistic model of mosquito development for two mosquito vectors; Aedes vigilax and Aedes camptorhynchus, with climate projections from three climate models for two Representative Concentration Pathways (RCPs), to examine the possible effects of climate change and sea-level rise on a temperate tidal saltmarsh habitat in Perth, Western Australia. The projections were run under no accretion and accretion scenarios using a known mosquito habitat as a case study. This improves our understanding of the possible implications of sea-level …

Enhancing Water Safety: Exploring Recent Technological Approaches For Drowning Detection, Salman Jalalifar, Andrew Belford, Eila Erfani, Amir Razmjou, Rouzbeh Abbassi, Masoud Mohseni-Dargah, Mohsen Asadnia

Research outputs 2022 to 2026

Drowning poses a significant threat, resulting in unexpected injuries and fatalities. To promote water sports activities, it is crucial to develop surveillance systems that enhance safety around pools and waterways. This paper presents an overview of recent advancements in drowning detection, with a specific focus on image processing and sensor-based methods. Furthermore, the potential of artificial intelligence (AI), machine learning algorithms (MLAs), and robotics technology in this field is explored. The review examines the technological challenges, benefits, and drawbacks associated with these approaches. The findings reveal that image processing and sensor-based technologies are the most effective approaches for drowning detection …

Malware Detection With Artificial Intelligence: A Systematic Literature Review, Matthew G. Gaber, Mohiuddin Ahmed, Helge Janicke

Research outputs 2022 to 2026

In this survey, we review the key developments in the field of malware detection using AI and analyze core challenges. We systematically survey state-of-the-art methods across five critical aspects of building an accurate and robust AI-powered malware-detection model: malware sophistication, analysis techniques, malware repositories, feature selection, and machine learning vs. deep learning. The effectiveness of an AI model is dependent on the quality of the features it is trained with. In turn, the quality and authenticity of these features is dependent on the quality of the dataset and the suitability of the analysis tool. Static analysis is fast but is …

Pdf Malware Detection: Toward Machine Learning Modeling With Explainability Analysis, G. M.Sakhawat Hossain, Kaushik Deb, Helge Janicke, Iqbal H. Sarker

Research outputs 2022 to 2026

The Portable Document Format (PDF) is one of the most widely used file types, thus fraudsters insert harmful code into victims' PDF documents to compromise their equipment. Conventional solutions and identification techniques are often insufficient and may only partially prevent PDF malware because of their versatile character and excessive dependence on a certain typical feature set. The primary goal of this work is to detect PDF malware efficiently in order to alleviate the current difficulties. To accomplish the goal, we first develop a comprehensive dataset of 15958 PDF samples taking into account the non-malevolent, malicious, and evasive behaviors of the …

Trends In Monitoring Of Australia’S Threatened Birds (1990–2020): Much Improved But Still Inadequate, Simon J. Verdon, Robert A. Davis, Ayesha Tulloch, Sarah M. Legge, David M. Watson, John C. Z. Woinarski, G. Barry Baker, Joris Driessen, Hayley M. Geyle, Hugh Possingham, Stephen T. Garnett

Research outputs 2022 to 2026

Monitoring is vital to conservation, enabling conservation scientists to detect population declines, identify threats and measure the effectiveness of interventions. However, not all threatened taxa are monitored, monitoring quality is variable, and the various components of monitoring are likely to differ in their rates of improvement over time. We assessed the presence of monitoring and monitoring quality, using a range of metrics, for all Australia’s threatened bird taxa from 1990 to 2020 (four assessments spanning 30 years). We used our assessments to understand decadal trends in the number of taxa monitored; monitoring quality; and the groups that conduct monitoring. The …

Opportunities And Challenges Posed By Disruptive And Converging Information Technologies For Australia's Future Defence Capabilities: A Horizon Scan, Pi-Shen Seet, Anton Klarin, Janice Jones, Mike Johnstone, Helen Cripps, Jalleh Sharafizad, Violetta Wilk, David Suter, Tony Marceddo

Research outputs 2022 to 2026

Introduction: The research project's objective was to conduct a comprehensive horizon scan of Network Centric Warfare (NCW) technologies—specifically, Cyber, IoT/IoBT, AI, and Autonomous Systems. Recognised as pivotal force multipliers, these technologies are critical to reshaping the mission, design, structure, and operations of the Australian Defence Force (ADF), aligning with the Department of Defence (Defence)’s offset strategies and ensuring technological advantage, especially in the Indo-Pacific's competitive landscape.

Research process: Employing a two-pronged research approach, the study first leveraged scientometric analysis, utilising informetric mapping software (VOSviewer) to evaluate emerging trends and their implications on defence capabilities. This approach facilitated a broader understanding …

Unifying Context With Labeled Property Graph: A Pipeline-Based System For Comprehensive Text Representation In Nlp, Ali Hur, Naeem Janjua, Mohiuddin Ahmed

Research outputs 2022 to 2026

Extracting valuable insights from vast amounts of unstructured digital text presents significant challenges across diverse domains. This research addresses this challenge by proposing a novel pipeline-based system that generates domain-agnostic and task-agnostic text representations. The proposed approach leverages labeled property graphs (LPG) to encode contextual information, facilitating the integration of diverse linguistic elements into a unified representation. The proposed system enables efficient graph-based querying and manipulation by addressing the crucial aspect of comprehensive context modeling and fine-grained semantics. The effectiveness of the proposed system is demonstrated through the implementation of NLP components that operate on LPG-based representations. Additionally, the proposed …

Mhair: A Dataset Of Audio-Image Representations For Multimodal Human Actions, Muhammad Bilal Shaikh, Douglas Chai, Syed M. S. Islam, Naveed Akhtar

Research outputs 2022 to 2026

Audio-image representations for a multimodal human action (MHAiR) dataset contains six different image representations of the audio signals that capture the temporal dynamics of the actions in a very compact and informative way. The dataset was extracted from the audio recordings which were captured from an existing video dataset, i.e., UCF101. Each data sample captured a duration of approximately 10 s long, and the overall dataset was split into 4893 training samples and 1944 testing samples. The resulting feature sequences were then converted into images, which can be used for human action recognition and other related tasks. These images can …

Multimodal Fusion For Audio-Image And Video Action Recognition, Muhammad B. Shaikh, Douglas Chai, Syed M. S. Islam, Naveed Akhtar

Research outputs 2022 to 2026

Multimodal Human Action Recognition (MHAR) is an important research topic in computer vision and event recognition fields. In this work, we address the problem of MHAR by developing a novel audio-image and video fusion-based deep learning framework that we call Multimodal Audio-Image and Video Action Recognizer (MAiVAR). We extract temporal information using image representations of audio signals and spatial information from video modality with the help of Convolutional Neutral Networks (CNN)-based feature extractors and fuse these features to recognize respective action classes. We apply a high-level weights assignment algorithm for improving audio-visual interaction and convergence. This proposed fusion-based framework utilizes …

Economic Material For Large-Scale H2 Storage And H2-Co2 Separation, Hussein R. Abid, Alireza Keshavarz, Header Jaffer, Basim K. Nile, Stefan Iglauer

Research outputs 2022 to 2026

Hydrogen is a clean fuel that can potentially completely decarbonize the energy supply chain and mitigate global warming. Hydrogen – a highly volatile gas – however, needs to be separated from CO2 during H2 production, and also from cushion gas in H2 geo-storage projects; in addition, large-scale H2 storage is a key obstacle. We thus tested and chemically upgraded common sub-bituminous coal as a material for H2-CO2 separation and H2 storage. The coal adsorbed significant amounts of H2 and CO2 and demonstrated an excellent H2-CO2 separation efficiency if chemically modified. The work presented here thus provides fundamental data required for …

Confined Feni Alloy Nanoparticles In Carbon Nanotubes For Photothermal Oxidative Dehydrogenation Of Ethane By Carbon Dioxide, Jinqiang Zhang, Meng Li, Xiaojie Tan, Lei Shi, Kun Xie, Xiaoli Zhao, Shuaijun Wang, Shiyong Zhao, Huayang Zhang, Xiaoguang Duan, Haijun Chen, Yuezhao Zhu, Mingbo Wu, Hongqi Sun, Shaobin Wang

Research outputs 2022 to 2026

Oxidative dehydrogenation of ethane with CO2 (ODEC) is an attractive reaction for reduction of carbon footprints and ethene production. In this work, we present photothermal catalysis on confined bimetal catalysts for ODEC. Carbon nanotubes confined non-noble bimetal alloy (i.e., CoNi@CNTs and FeNi@CNTs) catalysts were prepared and FeNi@CNTs showed effective performance in photothermal catalytic ODEC to ethene. Experiments and simulations reveal that UV and visible lights (420 – 490 nm) are responsible for ODEC and non-oxidative dehydrogenation of ethane, respectively, to ethene. Additionally, ODEC to ethene is preferred to C-C cracking to methane on FeNi@CNTs in light ( > 490 nm)-induced thermocatalysis. …